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    • 9. 发明申请
    • Process for making glycol ether compositions useful for metal recovery
    • 制备用于金属回收的二醇醚组合物的方法
    • US20110011210A1
    • 2011-01-20
    • US12460225
    • 2009-07-15
    • Farhad FadakarAdam Chan
    • Farhad FadakarAdam Chan
    • C22B11/10B03D1/008C22B15/00
    • B03D1/008B03D1/0043B03D2201/04B03D2203/02C22B11/00C22B15/00
    • Glycol ether compositions useful for metal recovery by froth flotation and processes for making the compositions are disclosed. In one process, dipropylene glycol methyl ether (DPM) is propoxylated to give a composition comprising 4 to 15 wt. % of DPM and at least 20 wt. % of tripropylene glycol methyl ether (TPM). In another process, the glycol ether composition is made from a distillation residue which comprises DPM, TPM, and a basic catalyst. Extraction of the residue with water to remove some of the basic catalyst is followed by propoxylated to give a composition which comprises less than 15 wt. % of DPM, at least 20 wt. % of TPM, and one or more PO-based glycols. In comparative froth tests, glycol ether compositions of the invention meet or exceed the performance of commercial frothers.
    • 公开了通过泡沫浮选用于金属回收的二醇醚组合物和用于制备组合物的方法。 在一个方法中,将丙二醇甲基醚(DPM)进行丙氧基化,得到包含4至15wt。 %的DPM和至少20wt。 %的三丙二醇甲基醚(TPM)。 在另一方法中,二醇醚组合物由包含DPM,TPM和碱性催化剂的蒸馏残渣制成。 用水萃取残余物以除去一些碱性催化剂,然后丙氧基化得到包含小于15wt。 %的DPM,至少20wt。 %的TPM和一种或多种基于PO的二醇。 在比较泡沫试验中,本发明的二醇醚组合物达到或超过商业起泡剂的性能。