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    • 1. 发明授权
    • Inorganic mesoporous materials with chiral nematic structures and preparation method thereof
    • 具有手性向列结构的无机介孔材料及其制备方法
    • US08623237B2
    • 2014-01-07
    • US13076469
    • 2011-03-31
    • Mark John MacLachlanKevin Eric ShopsowitzWadood Yasser HamadHao Qi
    • Mark John MacLachlanKevin Eric ShopsowitzWadood Yasser HamadHao Qi
    • C09K19/02C09K19/52B01D67/00B01D71/02C01B33/12B82Y40/00C08K3/36C01G17/02C01G19/02
    • C09K19/02B01D67/0048B01D67/0058B01D71/027B01D2325/025B01D2325/44C01B33/12C01B37/00C01G17/02C01G19/02C09K19/52
    • The present invention describes a composition and a method for producing mesoporous silica materials with a chiral organization. In the method, a polymerizable inorganic monomer is reacted in the presence of nanocrystalline cellulose (NCC) to give a material of inorganic solid with cellulose nanocrystallites embedded in a chiral nematic organization. The NCC can be removed to give a stable porous structure that retains the chiral organization of the NCC template. The new materials may be obtained as iridescent free-standing films with high surface area. Through control of the reaction conditions, the color of the films can be varied across the entire visible spectrum. These are the first materials to combine mesoporosity with long-range chiral ordering that leads to photonic properties. Examples of possible applications of the materials are: lightweight reinforcement materials, low k dielectric materials, tunable reflective filters, adsorbents, stationary phases for chromatography of chiral or achiral substances, supports for catalysts (e.g., for asymmetric synthetic transformations), and as a template to generate other new porous materials (e.g., porous carbon or porous metals), preferably with chiral nematic structures.
    • 本发明描述了一种具有手性组织的制备介孔二氧化硅材料的组合物和方法。 在该方法中,可聚合的无机单体在纳米晶体纤维素(NCC)的存在下反应,得到嵌入手性向列组织中的纤维素纳米晶的无机固体材料。 可以除去NCC以产生保持NCC模板的手性组织的稳定的多孔结构。 新材料可以获得具有高表面积的彩虹色自立膜。 通过控制反应条件,可以在整个可见光谱范围内改变膜的颜色。 这些是将介孔度与长距离手性排序结合起来产生光子性质的第一种材料。 材料的可能应用的例子有:轻质增强材料,低k电介质材料,可调谐反射滤光片,吸附剂,手性或非手性物质层析固定相,催化剂载体(如用于不对称合成转化),以及模板 以产生其它新的多孔材料(例如,多孔碳或多孔金属),优选具有手性向列结构。