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    • 3. 发明授权
    • Adhesive
    • 胶粘剂
    • US07410694B2
    • 2008-08-12
    • US11103285
    • 2005-04-11
    • Marc HusemannStephan Zollner
    • Marc HusemannStephan Zollner
    • B32B7/12
    • C09J4/00C08L63/00C08L2666/02C09J133/14Y10S526/931Y10S526/935Y10T428/287Y10T428/2891
    • The invention relates to an adhesive. Provision is made for the adhesive to comprise (a) 50 to 95% by weight of a heat-activable or pressure-sensitively adhesive polymer formed from a comonomer mixture comprising, based on the polymer, (a1) 40 to 95% by weight of acrylic and/or methacrylic esters of the formula CH2═CH(R1)(COOR2), where R1 is H and/or CH3 and R2 is H and/or alkyl chains having 1 to 30 carbon atoms; (a2) 5 to 30% by weight of a first copolymerizable vinyl monomer containing at least one carboxylic and/or sulphonic and/or phosphonic acid group; (a3) 1 to 10% by weight of a second copolymerizable vinyl monomer containing at least one epoxy group or one acid anhydride function; and (a4) 0 to 20% by weight of a third copolymerizable vinyl monomer containing at least one functional group which differs from the functional group of the first copolymerizable vinyl monomer and from the functional group of the second copolymerizable vinyl monomer; and also (b) 5 to 50% by weight of an epoxy resin or a mixture of two or more epoxy resins.
    • 本发明涉及粘合剂。 制备粘合剂包括(a)50至95重量%的由共聚单体混合物形成的可热激活或压敏敏感性聚合物,其基于聚合物,(a1)40至95重量% 丙烯酸和/或甲基丙烯酸酯,其分子式为CH 2 -CH(R 1 H 2)(COOR 2),其中R 1, / SUB>是H和/或CH 3,R 2是H和/或具有1至30个碳原子的烷基链; (a2)5-30重量%的含有至少一个羧酸和/或磺酸和/或膦酸基团的第一可共聚乙烯基单体; (a3)1〜10重量%的含有至少一个环氧基或一个酸酐官能团的第二可共聚乙烯基单体; 和(a4)0〜20重量%的含有至少一个与第一可共聚乙烯基单体的官能团和第二可共聚乙烯基单体的官能团不同的官能团的可共聚乙烯基单体; 和(b)5〜50重量%的环氧树脂或两种以上环氧树脂的混合物。
    • 7. 发明授权
    • UV-transparent pressure sensitive adhesive
    • 紫外线透明压敏胶
    • US07144928B2
    • 2006-12-05
    • US10745305
    • 2003-12-22
    • Marc HusemannStephan Zöllner
    • Marc HusemannStephan Zöllner
    • C09J7/02C09J133/08
    • C09J133/02C08K3/36Y10S526/905Y10T428/2813Y10T428/2857Y10T428/2896
    • A UV-transparent pressure sensitive adhesive comprising (a) a copolymer of (a1) from 75 to 99.8% by weight of acrylic esters and/or methacrylic esters of the formula CH2═CH(R1)(COOR2), where R1 is H or CH3 and R2 is an alkyl chain having 1 to 20 carbon atoms; (a2) from 0 to 10% by weight of acrylic acid and/or methacrylic acid of the formula CH2═CH(R1)(COOH), where R1 is H or CH3; (a3) from 0.2 to 5% by weight of olefinically unsaturated monomers which contain at least one UV-crosslinking functional group per monomer; and (a4) from 0 to 20% by weight of olefinically unsaturated monomers which contain at least one functional group per monomer; the copolymer having a weight average molecular weight of less than 300,000 g/mol and (b) from 2 to 20% by weight, based on the weight of copolymer, of a silicate filler, the silicate filler having a maximum particle diameter of 50 nm; and having a residual solvent fraction of less than 1%, based on the pressure sensitive adhesive.
    • 一种UV透明压敏粘合剂,其包含(a)75重量%至99.8重量%的(a1)共聚物,其具有式CH 2 -CH(R SUB)的丙烯酸酯和/或甲基丙烯酸酯 (COOR 2),其中R 1是H或CH 3,R 2和/或< >是具有1至20个碳原子的烷基链; (a2)0至10重量%的丙烯酸和/或式CH 2 -CH(R 1)(COOH)的甲基丙烯酸,其中R 1, SUB> 1是H或CH 3 N; (a3)0.2至5重量%的每单体含有至少一个UV交联官能团的烯属不饱和单体; 和(a4)0至20重量%的每单体含有至少一个官能团的烯属不饱和单体; 所述共聚物的重均分子量小于300,000g / mol,(b)基于共聚物重量的2至20重量%硅酸盐填料,最大粒径为50nm的硅酸盐填料 ; 并且基于压敏粘合剂具有小于1%的残留溶剂分数。