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    • 5. 发明授权
    • Separation of ammonia from ammonia containing gases
    • 从含氨气体中分离氨
    • US4287162A
    • 1981-09-01
    • US58695
    • 1979-07-18
    • Edward G. Scheibel
    • Edward G. Scheibel
    • B01D53/58B01D53/14C01C1/12C01C3/00
    • C01C1/12B01D53/14
    • A process for the separation and recovery of substantially pure ammonia from its admixture with gases, particularly with gases containing carbon dioxide and gases obtained from the catalytic ammoxidation of hydrocarbons to the corresponding nitriles, by scrubbing the ammonia containing gases with an aqueous solution containing a mixture of salts having different cations and the anions of one or more inorganic acids capable of absorbing and liberating ammonia; e.g., mixtures of different alkali metal salts of phosphoric, telluric, boric, vanadic, chromic, selenic, germanic, silicic and similar acids. Preferably the anion component will be at least one of phosphoric, chromic, or boric acids.
    • 一种从与其气体混合物中分离和回收基本上纯氨的方法,特别是将含有二氧化碳和气体的气体从通过烃催化氨氧化成相应的腈得到的气体,通过用含有混合物的水溶液洗涤含氨气体 的具有不同阳离子的盐和能够吸收和释放氨的一种或多种无机酸的阴离子; 例如磷酸,碲,硼,钒,铬,硒,锗,硅和类似酸的不同碱金属盐的混合物。 优选地,阴离子组分将是磷酸,铬酸或硼酸中的至少一种。