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    • 2. 发明授权
    • Solvent extraction of synfuel liquids
    • 溶剂萃取Synfuel液体
    • US4297206A
    • 1981-10-27
    • US117591
    • 1980-02-01
    • Edward G. Scheibel
    • Edward G. Scheibel
    • C10G21/16C10G21/20C10G67/04C10G45/02
    • C10G21/16C10G21/20C10G67/0418
    • An improvement in the solvent extraction of nonhydrocarbons from a synfuel liquid, e.g., shale oil, involves that the extract from the extractor, rather than being recycled directly back to the extractor, is first hydrotreated. A further improvement involves that a portion of the hydrotreated extract is fractionated and a light fraction is returned to the extractor. Use of the hydrotreated extract as recycle increases the efficiency of the extractor. A still further improvement involves the use as a selective solvent of one of the following: dialkylformamide, aldehydomorpholine, keto-morpholine, morpholine or an aliphatic aromatic ketone. These preferred solvents have the advantage of providing a clear interface between the extract and raffinate in the extractor. Removal of the nonhydrocarbons permits production of more hydrocarbons having enhanced utility as a jet fuel from a synfuel liquid than otherwise would be possible.
    • 来自合成油液体例如页岩油的非烃溶剂萃取的改进涉及将来自萃取器的提取物而不是直接再循环回萃取器的提取物首先进行加氢处理。 进一步的改进涉及加氢处理的提取物的一部分被分馏,轻馏分返回到提取器。 使用加氢处理的提取物作为回收提高了萃取器的效率。 还有一个进一步的改进涉及作为以下之一的选择性溶剂的用途:二烷基甲酰胺,醛,吗啉,吗啉或脂族芳族酮。 这些优选的溶剂具有在提取器中提取萃取物和萃余液之间提供清晰界面的优点。 去除非烃允许生产更多的碳氢化合物,其作为来自合成燃料液体的喷气燃料具有更高的效用,否则将是可能的。
    • 3. 发明授权
    • Fractionation of gases at low pressure
    • 低压气体分馏
    • US3996030A
    • 1976-12-07
    • US660217
    • 1976-02-23
    • Edward G. Scheibel
    • Edward G. Scheibel
    • C07C7/04F25J3/02
    • F25J3/0242C07C7/04F25J3/0219F25J3/0233F25J3/0238F25J2200/04F25J2200/74F25J2200/78F25J2210/12F25J2215/62F25J2215/64F25J2240/02F25J2270/04F25J2270/88
    • A process to separate hydrocarbon gases into different fractions by condensing in the high pressure condenser of a staged dual pressure rectification system only that amount of vapor necessary for the reboiler duty of the low pressure column and expanding the excess vapor to provide the low temperature refrigeration duty. The process of the invention lends itself particularly to refinery gases, particularly to an absorber tail gas which comprises a mixture of low molecular weight hydrocarbon gases (e.g. methane, ethane, ethylene, propane, etc.).This disclosure also describes a process for the low pressure fractional distillation of gaseous mixtures with relative volatilities of less than 2 by compressing part of the overhead gas product, removing the heat of compression with cooling water, cooling it by heat exchange with the overhead vapor stream from the low pressure column, condensing it in the high pressure condenser to supply additional reboiler duty to the low pressure column and adding the liquid to the reflux stream to the low pressure column.
    • 通过在分级双压精馏系统的高压冷凝器中冷凝仅将低浓度塔的再沸器负荷所需的蒸汽量和扩大过量蒸气以提供低温制冷功能的气体分离成不同馏分的方法 。 本发明的方法特别适用于炼油气体,特别是涉及包含低分子量烃气体(例如甲烷,乙烷,乙烯,丙烷等)的混合物的吸收剂尾气。
    • 4. 发明授权
    • Separation of ammonia from ammonia containing gases
    • 从含氨气体中分离氨
    • US4287162A
    • 1981-09-01
    • US58695
    • 1979-07-18
    • Edward G. Scheibel
    • Edward G. Scheibel
    • B01D53/58B01D53/14C01C1/12C01C3/00
    • C01C1/12B01D53/14
    • A process for the separation and recovery of substantially pure ammonia from its admixture with gases, particularly with gases containing carbon dioxide and gases obtained from the catalytic ammoxidation of hydrocarbons to the corresponding nitriles, by scrubbing the ammonia containing gases with an aqueous solution containing a mixture of salts having different cations and the anions of one or more inorganic acids capable of absorbing and liberating ammonia; e.g., mixtures of different alkali metal salts of phosphoric, telluric, boric, vanadic, chromic, selenic, germanic, silicic and similar acids. Preferably the anion component will be at least one of phosphoric, chromic, or boric acids.
    • 一种从与其气体混合物中分离和回收基本上纯氨的方法,特别是将含有二氧化碳和气体的气体从通过烃催化氨氧化成相应的腈得到的气体,通过用含有混合物的水溶液洗涤含氨气体 的具有不同阳离子的盐和能够吸收和释放氨的一种或多种无机酸的阴离子; 例如磷酸,碲,硼,钒,铬,硒,锗,硅和类似酸的不同碱金属盐的混合物。 优选地,阴离子组分将是磷酸,铬酸或硼酸中的至少一种。
    • 5. 发明授权
    • Cascade refrigeration system
    • 级联制冷系统
    • US4028079A
    • 1977-06-07
    • US660218
    • 1976-02-23
    • Edward G. Scheibel
    • Edward G. Scheibel
    • F25B7/00F25B9/00F25J1/02
    • F25J1/0265F25B7/00F25B9/00F25J1/0007F25J1/001F25J1/0052F25J1/0062F25J1/0072F25J1/0204F25J1/0268
    • In a cascade refrigeration system where low pressure vapor from an evaporator stage is compressed and then recycled for condensation to the evaporator of a previous stage, the improvement of passing the low pressure vapor from an evaporator stage through a heat exchanger to heat said vapor to ambient temperature, compressing said heated vapor, removing the compressor work by passing said compressed vapor through a cooler, cooling said compressed vapor by passing it through said heat exchanger in heat exchange relationship with said low pressure vapor, condensing it in the evaporator of the next higher temperature cycle of the cascade system and recycling the liquid to the low pressure evaporator stage.
    • 在级联制冷系统中,来自蒸发器级的低压蒸汽被压缩,然后被再循环以冷凝到前一级的蒸发器,改进了将来自蒸发器级的低压蒸气通过热交换器以将所述蒸气加热至环境 温度,压缩所述加热的蒸汽,通过使所述压缩蒸汽通过冷却器来移除压缩机工作,通过使所述压缩蒸汽通过所述热交换器与所述低压蒸汽以热交换关系冷却所述压缩蒸气,将其冷凝在下一个较高的蒸汽 级联系统的温度循环,并将液体再循环到低压蒸发器阶段。