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    • 1. 发明授权
    • Non-chrome tanning method
    • 非铬鞣制方法
    • US4784664A
    • 1988-11-15
    • US877743
    • 1986-06-24
    • Marcel SieglerErnest DiamontJoseph L. SuarezColin D. Quinn
    • Marcel SieglerErnest DiamontJoseph L. SuarezColin D. Quinn
    • C14C3/28C14C3/02C14C3/08C14C3/10
    • C14C3/02
    • The present process yields superior leather materials from limed hides, without the use of chromium salts, by combining a series of essential method steps in a sequence which yields leather having a "chrome" character. The present chromium-free tanning process includes the method steps of pretanning a hide with a chromium-free tan until its shrinkage temperature is about 170.degree. to 185.degree. F., submerging the hide in an acidic brine, having a pH between 2.5 and 3.5, and adding (in sequence, and in amounts sufficient to yield specified concentrations of each) pretanning agents, syntans, vegetable extracts, neutralizing agents and retanning and finishing agents, all of which are free from chromium. This method of pretanning, tanning and retanning a hide with a specified sequence of particular concentrations of chromium-free reagents yields a leather product having the characteristics of chrome-tanned leather and which demonstrates superior shrink resistance, resilience and flexural strength. The resultant leather product has particular utility when incorporated into durable, weather-resistant footwear such as military shoes and boots, but is likewise suitable for use in other applications which require durable, attractive leather goods such as handbags and attaches.
    • 本发明方法通过在产生具有“铬”特性的皮革的序列中组合一系列必需的方法步骤,从而不使用铬盐,从有色皮革产生优良的皮革材料。 本发明的无铬鞣制方法包括以无铬棕褐色预鞣皮的方法步骤,直到其收缩温度为约170至185°F,将皮革浸入酸性盐水中,pH在2.5至3.5之间 ,并且加入(按顺序,并且以足以产生每种的指定浓度的量)预处理剂,合成鞣剂,植物提取物,中和剂和复鞣整理剂,所有这些都不含铬。 这种用特定浓度的无铬试剂预定鞣制和复鞣皮革的方法产生具有铬鞣皮革特征的皮革制品,并且具有优异的抗收缩性,弹性和弯曲强度。 所得到的皮革产品在结合到耐用的耐候性鞋类如军用鞋和靴子中时具有特别的用途,但同样适用于需要耐用,有吸引力的皮革制品如手袋和附件的其它应用。
    • 3. 发明授权
    • Process for preparing macromolecular biologically active collagen
    • 制备大分子生物活性胶原蛋白的方法
    • US4279812A
    • 1981-07-21
    • US74738
    • 1979-09-12
    • Gheorghe Cioca
    • Gheorghe Cioca
    • A61K9/00A61K9/22A61K9/70A61K47/42A61L15/32A61L15/44A61L26/00C07K14/78C08L89/06C14C1/00C07G7/00
    • C08L89/06A61K9/70A61L15/325A61L15/44A61L26/0033A61L2300/404A61L2300/43Y10S128/08
    • Macromolecular reconstituted collagen is prepared by treating natural insoluble collagen with an aqueous solution comprised of an alkali sulfate salt and an alkali metal hydroxide for at least 48 hours to saponify fats suspended within the natural insoluble collagen. The fat free collagen is then treated with an aqueous solution comprised of an alkali metal sulfate for at least four hours to stabilize the interfibular bonds between individual polypeptide chains. The collagen is then dissolved in an aqueous acid solution and frozen at a rate of -20.degree. C./hour. The frozen collagen is vacuum dried at 10.sup.-3 to 10.sup.-5 torr for at least 16 hours to produce a biologically active collagen article. Various biologically active materials may be added to the aqueous acid solution prior to freezing. The collagen product may then be implanted into an animal or the like and the medication slowly released. The article can remain within the biological system and it will slowly dissolve due to enzymatic digestion and through other biological processes.
    • 通过用含有碱金属硫酸盐和碱金属氢氧化物的水溶液处理天然不溶性胶原蛋白至少48小时以皂化悬浮在天然不溶性胶原蛋白中的脂肪来制备大分子复原胶原蛋白。 然后用含有碱金属硫酸盐的水溶液处理不含脂肪的胶原蛋白至少4小时以稳定各个多肽链之间的界面结合。 然后将胶原溶解在酸性水溶液中,并以-20℃/小时的速度冷冻。 将冷冻的胶原蛋白在10-3至10-5乇真空干燥至少16小时以产生生物活性胶原物品。 在冷冻之前,可以向酸性水溶液中加入各种生物活性物质。 然后将胶原产品植入动物等中,药物缓慢释放。 该物品可以保留在生物系统内,并且由于酶消化和通过其他生物过程而将缓慢溶解。
    • 6. 发明申请
    • Natural grain leather
    • 天然谷物皮革
    • US20040071895A1
    • 2004-04-15
    • US10682689
    • 2003-10-09
    • Seton Company
    • Hermann Winkler
    • B05D001/18B05D003/12
    • C14C11/006B05D7/12C08G18/0823C08L75/04C09D133/08C14B3/00Y10T428/25Y10T428/31551Y10T428/31558Y10T428/4935C08L2666/20
    • A leather finishing process in which, in pertinent part, a warm water milling step is added after the base coat is applied to nullcrustnull leather and cured. The warm water contains at least one dye fixation agent including but not limited to about 0.1-2.0% by weight of formic acid. Moreover, the base coat itself is an aqueous base coat containing at least two polymers such as an acrylic salt or a polyurethane salt. Between the polymeric constituents of the base coat, the acid fixation agent, and the use of the warm water milling step after the base coat has been applied and dried, a surprisingly natural feel to the leather is attained without loss of excellent adhesion, wear-resistance and other properties when the leather is completely finished.
    • 皮革整理过程中,在相关部分中,在将基底涂层施用于“皮革”皮革并固化之后,加入温水碾磨步骤。 温水含有至少一种染料固着剂,其包括但不限于约0.1-2.0重量%的甲酸。 此外,底涂层本身是含有至少两种聚合物如丙烯酸盐或聚氨酯盐的水性底涂层。 在底涂层的聚合物组分,酸固定剂和基底涂层施加和干燥后的温水研磨步骤的使用之间,获得了皮革的令人惊奇的天然感觉,而没有优异的粘附性, 皮革完全完成时的阻力等特性。
    • 7. 发明授权
    • Making of trilaminates and quadlaminates for automotive vehicle seats
    • 制造汽车座椅的三层板和四层板
    • US5169469A
    • 1992-12-08
    • US547961
    • 1990-07-05
    • George F. Feeley
    • George F. Feeley
    • A47C31/02B32B27/12
    • B32B37/12B32B27/12B29L2031/3082Y10S156/927Y10T156/1168
    • A laminated composite in the form of a trilaminate and quadlaminate for use in the manufacture of a seat, particularly a vehicle seat, such as an automobile seat and a vehicle interior member. The laminated composite includes a seat cover material having a first adhesive applied to a first surface of the seat cover material. A sew pad is bonded to the seat cover material by the first adhesive. A second adhesive can be applied to the sew pad so that the sew pad can be bonded to a cushion by the second adhesive. The first adhesive can be a thermoplastic releasable polyolefin or polyester, and the second adhesive can be a polyurethane film so that the first adhesive forms a temporary releasable bond and the second adhesive forms a permanent bond. A method of manufacturing laminated composites is also disclosed.
    • 一种用于制造座椅,特别是诸如汽车座椅和车辆内部构件的车辆座椅的三层和四层板形式的层压复合材料。 层压复合材料包括具有施加到座椅护罩材料的第一表面的第一粘合剂的座椅覆盖材料。 缝合垫通过第一粘合剂粘合到座椅护罩材料上。 可以将第二粘合剂施加到缝合垫上,使得缝合垫可以通过第二粘合剂粘合到衬垫上。 第一粘合剂可以是热塑性可释放的聚烯烃或聚酯,并且第二粘合剂可以是聚氨酯膜,使得第一粘合剂形成临时的可释放粘合,并且第二粘合剂形成永久粘合。 还公开了制备叠层复合材料的方法。
    • 10. 发明授权
    • Manufacture of leather
    • 皮革制造
    • US4060384A
    • 1977-11-29
    • US721706
    • 1976-09-09
    • Marcel Siegler
    • Marcel Siegler
    • C14C3/02C14C3/06C14C3/28
    • C14C3/28
    • Manufacture of grain and split leather is simplified by pre-tanning hide with a chromium-free tan until its shrinkage temperature is about 170.degree. to about 185.degree. F, splitting the pre-tanned hide to provide a grain intermediate and a split intermediate, shaving at least one of these intermediates, and chrome-tanning the shaved intermediate. Shavings contain no chromium and can be disposed of by dumping, without significant environmental impact. Before splitting, the hide can also be pickled to improve the splitting and shaving and make the unfinished hide better suited for shipping to remote geographical areas. Entire hide treatment sequence can be effected with two stages in which batches of hides are loaded in a container such as tumbling drum; unhairing, bating and pre-tanning with or without a pickle, all in one stage, and final tanning, coloring and fat-liquoring in another stage. Final chrome-tanned product has very good physical characteristics including unusually high slot tear and is recovered in higher yield.
    • 通过无铬鞣制的皮革制成谷物和分裂皮革,直到其收缩温度为约170度至约185°F,将预鞣皮分割成提供谷物中间体和分割中间体,剃须 这些中间体中的至少一种,并且将鞣制的中间体进行铬鞣制。 刨花不含铬,可以通过倾倒处理,没有显着的环境影响。 在分裂之前,皮革也可以酸洗,以改善分裂和剃须,并使未完成的皮革更适合运送到偏远的地理区域。 可以通过两个阶段实现整个隐藏处理顺序,其中批量的皮革装载在诸如滚筒的容器中; 腌制,鞣制和预鞣制,有或没有腌制,一个阶段,最后的鞣制,着色和油炸在另一个阶段。 最终的铬鞣制品具有非常好的物理特性,包括异常高的槽裂,并以更高的产率回收。