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1. 发明授权

US07064226B2 Organopolysiloxanes containing phosphonic groups, method for the production and use thereof 有权
公开(公告)号：US07064226B2
公开(公告)日：2006-06-20
申请号：US10250732
申请日：2002-01-09
申请人： Alice Caroline Sullivan , John Robert Howe Wilson
发明人： Alice Caroline Sullivan , John Robert Howe Wilson
IPC分类号： C07F9/02
CPC分类号： C07F9/4012 , B01J39/19 , C07C41/56 , C07C45/515 , C07C45/52 , C07C45/72 , C07C45/74 , C07C51/29 , C07C67/03 , C07C67/08 , C07D301/12 , C07D303/04 , C08G77/30 , C07C49/78 , C07C49/04 , C07C49/796 , C07C63/06 , C07C63/10 , C07C69/58 , C07C43/307
摘要： The invention relates to new compounds of the formula, wherein R and R1 are each independently hydrogen, a linear or branched C1-40 alkyl, C2-40 alkenyl or C2-40 alkynyl group, an aryl or C1-40 alkylaryl group or an optionally complex metal ion Mn+/n wherein n is an integer from 1 to 8; the free valences of the silicate oxygen atoms are saturated by one or more of: silicon atoms of other groups of the formula, hydrogen, a linear or branched C1-12 alkyl group or by cross-linking bridge members R3qM1(OR2)mOk/2 or Al(OR2)3-pOp/2 or R3Al(OR2)2-rOr/2; where M1 is Si or Ti; R2 is linear or branched C1-12 alkyl group; and R3 is a linear or branched C1-6 alkyl group; k is an integer from 1 to 4 and q and m are integers from 0 to 2; such that m+k+q=4; and p is an integer from 1 to 3; and r is an integer from 1 to 2; or other known oxo metal bridging systems; x, y and z are integers such that the radio of x:y+z, varies from 0.00001 to 100,000 with the fragments [O3/2SiCH(CH2PO(OR)(OR1))CH2CH2SiO3/2]X and [O3/2SiCH2CH2PO(OR)(OR1)]Y always present whilst the integer z varies from 0 to 200y. The compounds are useful as catalysts for a wide variety of reactions and have the advantages that they can be prepared in a one-pot reaction and have functional group losding can be tailored to be at a required level. In addition, the compounds have high chemical and thermal stability, fixed and rigid structures, are insoluble in organic solvents, high resistance to ageing, and can easily be purified and reused.

2. 发明申请

US20060241314A1 Organopolysiloxanes containing phosphonic groups, method for the production and use thereof 有权
公开(公告)号：US20060241314A1
公开(公告)日：2006-10-26
申请号：US11455545
申请日：2006-06-19
申请人： Alice Sullivan , John Wilson
发明人： Alice Sullivan , John Wilson
IPC分类号： C07F9/02
CPC分类号： C07F9/4012 , B01J39/19 , C07C41/56 , C07C45/515 , C07C45/52 , C07C45/72 , C07C45/74 , C07C51/29 , C07C67/03 , C07C67/08 , C07D301/12 , C07D303/04 , C08G77/30 , C07C49/78 , C07C49/04 , C07C49/796 , C07C63/06 , C07C63/10 , C07C69/58 , C07C43/307
摘要： The invention relates to new compounds of the formula, wherein R and R1 are each independently hydrogen, a linear or branched C1-40 alkyl, C2-40 alkenyl or C2-40 alkynyl group, an aryl or C1-40 alkylaryl group or an optionally complex metal ion Mn+/n wherein n is an integer from 1 to 8; the free valences of the silicate oxygen atoms are saturated by one or more of: silicon atoms of other groups of the formula, hydrogen, a linear or branched C1-12 alkyl qroup or by cross-linking bridge members R3qM1(OR2)mOk/2 or Al(OR2)3·pOp/2 or R3Al(OR2)2·rOr/2; where M1 is Si or Ti; R2 is linear or branched C1-12 alkyl group; and R3 is a linear or branched C1-6 alkyl group; k is an integer from 1 to 4 and q and m are integers from 0 to 2; such that m+k+q=4; and p is an integer from 1 to 3; and r is an integer from 1 to 2; or other known oxo metal bridging systems; x, y and z are integers such that the radio of x:y+z, varies from 0.00001 to 100,000 with the fragments [O3/2SiCH(CH2PO(OR)(OR1))CH2CH2SiO3/2]X and [O3/2SiCH2CH2PO(OR)(OR1)]Y always present whilst the integer z varies from 0 to 200y. The compounds are useful as catalysts for a wide variety of reactions and have the advantages that they can be prepared in a one-pot reaction and have functional group losding can be tailored to be at a required level. In addition, the compounds have high chemical and thermal stability, fixed and rigid structures, are insoluble in organic solvents, high resistance to ageing, and can easily be purified and reused.

3. 发明授权

US11866520B2 Functionalised compounds 有权
公开(公告)号：US11866520B2
公开(公告)日：2024-01-09
申请号：US16766219
申请日：2018-11-22
申请人： PHOSPHONICS LIMITED
发明人： Nicholas P. Taylor , Laura C. Forfar , Paul M. Murray , Christopher North , Alexander Watson
IPC分类号： C08B3/10 , B01J20/24 , B01J20/28 , C01G7/00 , C01G55/00 , C02F1/28 , C08B31/04 , C02F101/20 , C02F103/10
CPC分类号： C08B3/10 , B01J20/24 , B01J20/28019 , B01J20/28023 , B01J20/28033 , C01G7/00 , C01G55/002 , C02F1/286 , C08B31/04 , B01J2220/4825 , C02F2101/20 , C02F2103/10
摘要： A substantially insoluble compound having a polysaccharide backbone which is derivatised at one or more of its hydroxyl groups with a ligand (L) bound to the sugar moiety by a sulphur atom which may be tailored according to a wide range of applications. The compound is useful as a catalyst and in removal of contaminants from a feed containing particularly metal ions.

4. 发明申请

US20210147578A1 Functionalised Compounds 有权
公开(公告)号：US20210147578A1
公开(公告)日：2021-05-20
申请号：US16766219
申请日：2018-11-22
申请人： PHOSPHONICS LIMITED
发明人： Nicholas P. Taylor , Laura C. Forfar , Paul M. Murray , Christopher North , Alexander Watson
IPC分类号： C08B3/10 , C08B31/04 , C01G55/00 , C01G7/00 , B01J20/24 , B01J20/28 , C02F1/28
摘要： A substantially insoluble compound having a polysaccharide backbone which is derivatised at one or more of its hydroxyl groups with a ligand (L) bound to the sugar moiety by a sulphur atom which may be tailored according to a wide range of applications. The compound is useful as a catalyst and in removal of contaminants from a feed containing particularly metal ions.

5. 发明授权

US07728159B2 Organopolysiloxanes containing phosphonic groups, method for the production and use thereof 有权
标题翻译：含有膦酸基的有机聚硅氧烷，其制备方法及其应用
公开(公告)号：US07728159B2
公开(公告)日：2010-06-01
申请号：US11455545
申请日：2006-06-19
申请人： Alice Caroline Sullivan , John Robert Howe Wilson
发明人： Alice Caroline Sullivan , John Robert Howe Wilson
IPC分类号： C07F7/26
CPC分类号： C07F9/4012 , B01J39/19 , C07C41/56 , C07C45/515 , C07C45/52 , C07C45/72 , C07C45/74 , C07C51/29 , C07C67/03 , C07C67/08 , C07D301/12 , C07D303/04 , C08G77/30 , C07C49/78 , C07C49/04 , C07C49/796 , C07C63/06 , C07C63/10 , C07C69/58 , C07C43/307
摘要： The invention relates to new compounds of the formula, wherein R and R1 are each independently hydrogen, a linear or branched C1-40 alkyl, C2-40 alkenyl or C2-40 alkynyl group, an aryl or C1-40 alkylaryl group or an optionally complex metal ion Mn+/n wherein n is an integer from 1 to 8; the free valences of the silicate oxygen atoms are saturated by one or more of: silicon atoms of other groups of the formula, hydrogen, a linear or branched C1-12 alkyl group or by cross-linking bridge members R3qM1(OR2)mOk/2 or Al(OR2)3-pOp/2 or R3 Al(OR−)2-1 O1/2; wherein M1 is Si or Ti; R2 is linear or branched C1-12 alkyl group; and R3 is alinear or branched C1-6 alkyl group; k is an integer from 1 to 4 and q and m are integers from 0 to 2; such that M+k+q=4; and p is an integer from 1 to 3; and r is an integer from 1 to 2; or other known oxo metal bridging systems; x, y and z are integers such that the radio of x:y+z, varies from 0.00001 to 100,000 with the fragments [O3/2SiCH(CH2PO(OR)(OR1))CH2CH2SiO3/2]x and [O3/2SiCH2CH2PO(OR)(OR1)]y always present whilst the integer z varies from 0 to 200y. The compounds are useful as catalysts for a wide variety of reactions and have the advantages that they can be prepared in a one-pot reaction and functional group losding can be tailored to be at a required level. In addition, the compounds have high chemical and thermal stability, fixed and rigid structures, are insoluble in organic solvents, high resistance to ageing, and can easily be purified and reused.
摘要翻译：本发明涉及新的下式化合物，其中R 1和R 2各自独立地为氢，直链或支链C 1-20烷基，C 2-40链烯基或C 2-40炔基，芳基或C 1-4烷基芳基或任选地复合金属离子Mn + / n，其中n为1至8的整数; 硅酸盐氧原子的自由价饱和的一个或多个：下式的其他基团的硅原子：氢，直链或支链的C 1-12烷基，或通过桥连构件R3qM1（OR2）mOk / 2 或Al（OR2）3-pOp / 2或R3Al（OR-）2-1O1 / 2; 其中M1是Si或Ti; R2是直链或支链C1-12烷基; 并且R 3是亚胺基或支链C 1-6烷基; k是1至4的整数，q和m是0至2的整数; 使得M + k + q = 4; 并且p是1至3的整数; 并且r是1至2的整数; 或其它已知的氧代金属桥接体系; 片段[O3 / 2SiCH（CH2PO（OR）（OR1））CH2CH2SiO3 / 2] x和[O3 / 2SiCH2CH2PO（...）的x：y + z的放射线从0.00001到100,000变化， OR）（OR1）] y总是存在，而整数z从0到200y变化。该化合物可用作多种反应的催化剂，并且具有可以在一锅反应中制备的优点，并且官能团可以定制为所需的水平。此外，化合物具有高的化学和热稳定性，固定和刚性结构，不溶于有机溶剂，耐老化，易于纯化和再利用。

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