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    • 5. 发明授权
    • Superacid catalyzed preparation of resorcinol from meta-isopropylphenol
    • 超临界催化从间 - 异丙基苯酚制备间苯二酚
    • US4423254A
    • 1983-12-27
    • US383941
    • 1982-06-01
    • George A. Olah
    • George A. Olah
    • C07C37/00C07C37/055C07C37/08C07C37/14C07C37/16C07C37/18C07C37/48C07C39/06
    • C07C37/08C07C37/055C07C37/0555C07C37/14C07C37/16C07C37/18C07C37/48
    • Resorcinol is prepared by an improved process through superacid (such as perfluorinated alkanesulfonic superacids of one to eighteen carbon atoms or polymeric perfluorinated resinsulfonic acids, such as Nafion-H catalyzed cleavage-rearrangement reaction of meta-isopropylphenol hydroperoxide in the form of its protected ether or ester derivatives, including readily cleavable and reusable trimethylsilyl and trifluoromethanesulfonyl derivates. Part of the process is the preparation of needed meta-isopropylphenol in high purity free of other isomers by treating any mixture of isopropylphenol isomers in an excess of anhydrous hydrogen fluoride or a perfluorinated alkanesulfonic superacid of one to eighteen carbon atoms and a Lewis acid fluoride or by alkylating (transalkylating) phenol with a propyl alkylating agent in the presence of the aforementioned superacid systems.
    • 间苯二酚通过超强酸(例如1至18个碳原子的全氟化烷烃磺酸超强酸或聚合全氟磺酸磺酸)的改进方法制备,例如Nafion-H催化的经受保护的醚形式的间异丙基苯酚氢过氧化物的裂解重排反应,或 酯衍生物,包括易裂解和可重复使用的三甲基甲硅烷基和三氟甲磺酰基衍生物。该方法的一部分是通过将过量无水氟化氢或全氟化烷烃磺酸的异丙基苯酚异构体的任何混合物处理,制备所需的高纯度的不含异构体的间异丙基苯酚 通过在上述超酸体系的存在下,使用丙烷基化剂将烷基化(烷基转移)苯酚与1至18个碳原子的超酸和路易斯酸氟化物反应。
    • 6. 发明授权
    • Composition and process for the protection of materials against spots or
stains
    • 保护材料免受斑点或污渍的组成和过程
    • US4366300A
    • 1982-12-28
    • US265941
    • 1981-05-21
    • Charles L. L. Delescluse
    • Charles L. L. Delescluse
    • C09D5/00C08L33/14C09D133/04D06M15/295C09D3/81C09D5/14
    • D06M15/295C08L33/14
    • The invention relates to a composition for the protection of materials against contaminations, spots and stains.This liquid composition comprises by weight 0.1 to 1% of at least one fluorinated resin based on acrylic or methacrylic esters of fluorinated sulfonamido-alcohol, associated or not with non-fluorinated monomers, 0.4 to 10% of at least one adjuvant selected from aminoplast resins based on melamine, thermoplastic resins and waxes, and 89 to 99.5% of at least one organic solvent.Applied on materials such as walls, facades, monuments or sculptures in cement, bricks, concrete or stones and other construction elements, the composition according to the invention confers on the materials an excellent protection against natural or artificial contaminations.
    • 本发明涉及一种用于保护材料免受污染,斑点和污渍的组合物。 该液体组合物包含0.1至1%的至少一种氟化树脂,其基于氟化亚磺酰氨基醇的丙烯酸或甲基丙烯酸酯,与非氟化单体缔合或不相结合,0.4-10%的至少一种佐剂,其选自氨基塑料树脂 基于三聚氰胺,热塑性树脂和蜡,以及89至99.5%的至少一种有机溶剂。 用于水泥,砖,混凝土或石头等建筑构件的墙体,立面,古迹或雕塑等材料,根据本发明的组合物赋予材料优良的防止天然或人造污染的保护。