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1. 发明授权

US10458011B2 Ternary ceramic thermal spraying powder and method of manufacturing thermal sprayed coating using said powder 有权
公开(公告)号：US10458011B2
公开(公告)日：2019-10-29
申请号：US15853798
申请日：2017-12-24
申请人： MesoCoat, Inc.
发明人： Evelina Vogli , Andrew J. Sherman , Curtis P. Glasgow
IPC分类号： C04B35/58 , C23C4/10 , B22F1/00 , C22C29/14 , C23C4/12 , C23C24/04 , C04B35/622
摘要： The invention describes a method for producing ternary and binary ceramic powders and their thermal spraying capable of manufacturing thermal sprayed coatings with superior properties. Powder contain at least 30% by weight ternary ceramic, at least 20% by weight binary molybdenum borides, at least one of the binary borides of Cr, Fe, Ni, W and Co and a maximum of 10% by weight of nano and submicro-sized boron nitride. The primary crystal phase of the manufactured thermal sprayed coatings from these powders is a ternary ceramic, while the secondary phases are binary ceramics. The coatings have extremely high resistance against corrosion of molten metal, extremely thermal shock resistance and superior tribological properties at low and at high temperatures.

2. 发明申请

US20170021445A1 METHOD AND APPARATUS FOR FORMING CLAD METAL PRODUCTS 审中-公开
标题翻译：用于形成金属制品的方法和装置
公开(公告)号：US20170021445A1
公开(公告)日：2017-01-26
申请号：US15287754
申请日：2016-10-07
申请人： MESOCOAT, INC.
发明人： Andrew J. Sherman , P. Greg Engleman , Mario Medanic , Kurt E. Gilbert
IPC分类号： B23K10/02 , B23K28/00 , B23K31/02 , F16L58/08 , B23K37/02 , C23C24/08 , H05H1/48 , H05B6/80 , B23K37/053
CPC分类号： B23K10/027 , B05D3/0254 , B23K28/00 , B23K31/027 , B23K37/0217 , B23K37/0531 , B23K37/0538 , B23K2101/06 , B23K2101/10 , C23C24/08 , F16L58/08 , H05B6/80 , H05H1/48
摘要： The present invention concerns methods and apparatus for forming a clad product, such as a clad pipe or tube. Particular embodiments include a method for metallurgically bonding cladding material onto a metal substrate, the method including a step of providing a metal substrate comprising a pipe or a tube having a cladding composition arranged along an interior surface of the substrate to form a coated substrate, the interior surface arranged within an interior cavity of the substrate. A further step includes inserting a heat source into an interior cavity of the substrate, the heat source comprising an infrared, microwave, or radio frequency heat source, the heat source being mounted on a heat source-retaining housing, the housing comprising a cantilevered structure. An additional step includes applying heat discharged from the heat source to the coated substrate along the coated interior surface until the cladding composition metallurgically bonds to the substrate.
摘要翻译：本发明涉及用于形成包覆产品的方法和装置，例如复合管或管。具体实施方案包括用于将包覆材料冶金结合到金属基底上的方法，所述方法包括提供包括管或管的金属基底的步骤，所述管或管具有沿着所述基底的内表面布置的覆层组合物以形成涂覆的基底，内表面布置在基底的内腔内。进一步的步骤包括将热源插入衬底的内腔中，该热源包括红外线，微波或射频热源，该热源安装在热源保持壳体上，该壳体包括悬臂结构。附加步骤包括沿着涂覆的内表面将从热源排出的热量施加到涂覆的基底上，直到包层组合物冶金地结合到基底上。

3. 发明申请

US20140272171A1 TERNARY CERAMIC THERMAL SPRAYING POWDER AND METHOD OF MANUFACTURING THERMAL SPRAYED COATING USING SAID POWDER 有权
标题翻译：第三代陶瓷热喷涂粉末及使用该粉末制造热喷涂涂层的方法
公开(公告)号：US20140272171A1
公开(公告)日：2014-09-18
申请号：US14216725
申请日：2014-03-17
申请人： MESOCOAT, INC.
发明人： Evelina VOGLI , Andrew J. SHERMAN , Curtis P. GLASGOW
IPC分类号： C23C4/10 , C22C29/14 , C04B35/58
CPC分类号： C23C4/10 , B22F1/007 , C04B35/58 , C04B35/5805 , C04B35/58064 , C04B35/62222 , C04B2235/3804 , C04B2235/3813 , C04B2235/386 , C04B2235/446 , C04B2235/80 , C22C29/14 , C23C4/12 , C23C24/04 , Y10T428/12181
摘要： The invention describes a method for producing ternary and binary ceramic powders and their thermal spraying capable of manufacturing thermal sprayed coatings with superior properties. Powder contain at least 30% by weight ternary ceramic, at least 20% by weight binary molybdenum borides, at least one of the binary borides of Cr, Fe, Ni, W and Co and a maximum of 10% by weight of nano and submicro-sized boron nitride. The primary crystal phase of the manufactured thermal sprayed coatings from these powders is a ternary ceramic, while the secondary phases are binary ceramics. The coatings have extremely high resistance against corrosion of molten metal, extremely thermal shock resistance and superior tribological properties at low and at high temperatures.
摘要翻译：本发明描述了一种用于制造三元和二元陶瓷粉末的方法及其热喷涂，其能够制造具有优异性能的热喷涂层。粉末含有至少30重量％的三元陶瓷，至少20重量％的二元硼化钼，Cr，Fe，Ni，W和Co的二元硼化物中的至少一种和最多10重量％的纳米和亚微米尺寸的氮化硼。由这些粉末制造的热喷涂层的主晶相是三元陶瓷，而次相是二元陶瓷。涂层在低温和高温下具有极高的熔融金属腐蚀性，极高的耐热冲击性和优异的摩擦学性能。

4. 发明申请

US20140004270A1 METHOD AND APPARATUS FOR FORMING CLAD METAL PRODUCTS 有权
标题翻译：用于形成金属制品的方法和装置
公开(公告)号：US20140004270A1
公开(公告)日：2014-01-02
申请号：US14004372
申请日：2012-03-09
申请人： Andrew J. Sherman , P. Greg Engleman , Mario Medanic , Kurt E. Gilbert
发明人： Andrew J. Sherman , P. Greg Engleman , Mario Medanic , Kurt E. Gilbert
IPC分类号： B05D3/02
CPC分类号： B23K10/027 , B05D3/0254 , B23K28/00 , B23K31/027 , B23K37/0217 , B23K37/0531 , B23K37/0538 , B23K2101/06 , B23K2101/10 , C23C24/08 , F16L58/08 , H05B6/80 , H05H1/48
摘要： The present invention concerns methods and apparatus for forming a clad product, such as a clad pipe or tube. Particular embodiments include a method for metallurgically bonding cladding material onto a metal substrate, the method including a step of providing a metal substrate comprising a pipe or a tube having a cladding composition arranged along an interior surface of the substrate to form a coated substrate, the interior surface arranged within an interior cavity of the substrate. A further step includes inserting a heat source into an interior cavity of the substrate, the heat source comprising an infrared, microwave, or radio frequency heat source, the heat source being mounted on a heat source-retaining housing, the housing comprising a cantilevered structure. An additional step includes applying heat discharged from the heat source to the coated substrate along the coated interior surface until the cladding composition metallurgically bonds to the substrate.
摘要翻译：本发明涉及用于形成包覆产品的方法和装置，例如复合管或管。具体实施方案包括用于将包覆材料冶金结合到金属基底上的方法，所述方法包括提供包括管或管的金属基底的步骤，所述管或管具有沿着所述基底的内表面布置的覆层组合物以形成涂覆的基底，内表面布置在基底的内腔内。进一步的步骤包括将热源插入衬底的内腔中，该热源包括红外线，微波或射频热源，该热源安装在热源保持壳体上，该壳体包括悬臂结构。附加步骤包括沿着涂覆的内表面将从热源排出的热量施加到涂覆的基底上，直到包层组合物冶金地结合到基底上。

5. 发明申请

US20180119265A1 TERNARY CERAMIC THERMAL SPRAYING POWDER AND METHOD OF MANUFACTURING THERMAL SPRAYED COATING USING SAID POWDER 审中-公开
公开(公告)号：US20180119265A1
公开(公告)日：2018-05-03
申请号：US15853798
申请日：2017-12-24
申请人： MesoCoat, Inc.
发明人： Evelina Vogli , Andrew J. Sherman , Curtis P. Glasgow
IPC分类号： C23C4/10 , C23C24/04 , C23C4/12 , B22F1/00 , C22C29/14 , C04B35/58
CPC分类号： C23C4/10 , B22F1/007 , C04B35/58 , C04B35/5805 , C04B35/58064 , C04B35/62222 , C04B2235/3804 , C04B2235/3813 , C04B2235/386 , C04B2235/446 , C04B2235/80 , C22C29/14 , C23C4/12 , C23C24/04 , Y10T428/12181
摘要： The invention describes a method for producing ternary and binary ceramic powders and their thermal spraying capable of manufacturing thermal sprayed coatings with superior properties. Powder contain at least 30% by weight ternary ceramic, at least 20% by weight binary molybdenum borides, at least one of the binary borides of Cr, Fe, Ni, W and Co and a maximum of 10% by weight of nano and submicro-sized boron nitride. The primary crystal phase of the manufactured thermal sprayed coatings from these powders is a ternary ceramic, while the secondary phases are binary ceramics. The coatings have extremely high resistance against corrosion of molten metal, extremely thermal shock resistance and superior tribological properties at low and at high temperatures.

6. 发明授权

US09486832B2 Method and apparatus for forming clad metal products 有权
标题翻译：用于形成复合金属制品的方法和装置
公开(公告)号：US09486832B2
公开(公告)日：2016-11-08
申请号：US14004372
申请日：2012-03-09
申请人： Andrew J. Sherman , P. Greg Engleman , Mario Medanic , Kurt E. Gilbert
发明人： Andrew J. Sherman , P. Greg Engleman , Mario Medanic , Kurt E. Gilbert
IPC分类号： B05D3/00 , C08J7/18 , G21H5/00 , B05D3/02 , C23C24/08 , F16L58/08 , B23K28/00 , B23K31/02
CPC分类号： B23K10/027 , B05D3/0254 , B23K28/00 , B23K31/027 , B23K37/0217 , B23K37/0531 , B23K37/0538 , B23K2101/06 , B23K2101/10 , C23C24/08 , F16L58/08 , H05B6/80 , H05H1/48
摘要： The present invention concerns methods and apparatus for forming a clad product, such as a clad pipe or tube. Particular embodiments include a method for metallurgically bonding cladding material onto a metal substrate, the method including a step of providing a metal substrate comprising a pipe or a tube having a cladding composition arranged along an interior surface of the substrate to form a coated substrate, the interior surface arranged within an interior cavity of the substrate. A further step includes inserting a heat source into an interior cavity of the substrate, the heat source comprising an infrared, microwave, or radio frequency heat source, the heat source being mounted on a heat source-retaining housing, the housing comprising a cantilevered structure. An additional step includes applying heat discharged from the heat source to the coated substrate along the coated interior surface until the cladding composition metallurgically bonds to the substrate.
摘要翻译：本发明涉及用于形成包覆产品的方法和装置，例如复合管或管。具体实施方案包括用于将包覆材料冶金结合到金属基底上的方法，所述方法包括提供包括管或管的金属基底的步骤，所述管或管具有沿着所述基底的内表面布置的覆层组合物以形成涂覆的基底，内表面布置在基底的内腔内。进一步的步骤包括将热源插入衬底的内腔中，该热源包括红外线，微波或射频热源，该热源安装在热源保持壳体上，该壳体包括悬臂结构。附加步骤包括沿着涂覆的内表面将从热源排出的热量施加到涂覆的基底上，直到包层组合物冶金地结合到基底上。

7. 发明申请

US20140134452A1 COATINGS, COMPOSITION AND METHOD RELATED TO NON-SPALLING LOW DENSITY HARDFACE COATINGS 有权
标题翻译：涂料，组合物和方法相关的非膨胀低密度硬质涂料
公开(公告)号：US20140134452A1
公开(公告)日：2014-05-15
申请号：US13799648
申请日：2013-03-13
申请人： Mesocoat, Inc.
发明人： Andrew Sherman , Curt Glasgow
IPC分类号： C09D1/00
CPC分类号： C09D1/00 , B22F7/08 , C22C29/00 , C22C29/02 , C23C4/067 , C23C14/223 , Y10T428/12486
摘要： A heterogeneous composite body that is spall resistant and comprises a substantially discontinuous cermet phase in a substantially continuous metal rich matrix phase. The heterogeneous composite body is typically bonded to a substrate to form a hardfacing on the substrate. The heterogeneous composite body exhibits ductile phase toughening with a strain to failure of at least about 2 percent, a modulus of elasticity of less than about 35 million pounds per square inch, and a density of less than about 7 grams per cubic centimeter. The metal rich matrix phase between the ceramic rich regions in the heterogeneous composite body has an average minimum span of about 0.5 to 8 microns to allow ductility in the heterogeneous composite body. The heterogeneous composite body has a Vicker's hardness number of greater than approximately 500. The ceramic rich regions exhibit high hardness as compared with the matrix phase.
摘要翻译：一种异质复合体，其具有抗剥落性，并且在基本连续的富金属基质相中包含基本上不连续的金属陶瓷相。非均相复合体通常结合到基底上以在基底上形成硬化面。非均相复合体表现出韧性相增韧，破坏应变至少约为2％，弹性模量小于约3500万磅/平方英寸，密度小于约7克/立方厘米。非均相复合体中陶瓷富集区之间的富金属基质相的平均最小跨度为约0.5至8微米，以允许非均相复合体中的延展性。非均相复合体具有大于约500的维氏硬度值。与基体相相比，富陶瓷区显示出高的硬度。

8. 发明授权

US09885100B2 Ternary ceramic thermal spraying powder and method of manufacturing thermal sprayed coating using said powder 有权
公开(公告)号：US09885100B2
公开(公告)日：2018-02-06
申请号：US14216725
申请日：2014-03-17
申请人： MESOCOAT, INC.
发明人： Evelina Vogli , Andrew J. Sherman , Curtis P. Glasgow
IPC分类号： C04B35/58 , C23C4/10 , C22C29/14 , C23C4/12 , C23C24/04 , B22F1/00
CPC分类号： C23C4/10 , B22F1/007 , C04B35/58 , C04B35/5805 , C04B35/58064 , C04B35/62222 , C04B2235/3804 , C04B2235/3813 , C04B2235/386 , C04B2235/446 , C04B2235/80 , C22C29/14 , C23C4/12 , C23C24/04 , Y10T428/12181
摘要： The invention describes a method for producing ternary and binary ceramic powders and their thermal spraying capable of manufacturing thermal sprayed coatings with superior properties. Powder contain at least 30% by weight ternary ceramic, at least 20% by weight binary molybdenum borides, at least one of the binary borides of Cr, Fe, Ni, W and Co and a maximum of 10% by weight of nano and submicro-sized boron nitride. The primary crystal phase of the manufactured thermal sprayed coatings from these powders is a ternary ceramic, while the secondary phases are binary ceramics. The coatings have extremely high resistance against corrosion of molten metal, extremely thermal shock resistance and superior tribological properties at low and at high temperatures.

9. 发明授权

US09376573B2 Coatings, composition and method related to non-spalling low density hardface coatings 有权
标题翻译：与非剥落低密度硬质涂料相关的涂料，组成和方法
公开(公告)号：US09376573B2
公开(公告)日：2016-06-28
申请号：US13799648
申请日：2013-03-13
申请人： Mesocoat, Inc.
发明人： Andrew Sherman , Curt Glasgow
IPC分类号： C09D1/00 , C23C14/22 , B22F7/08 , C22C29/00 , C22C29/02
CPC分类号： C09D1/00 , B22F7/08 , C22C29/00 , C22C29/02 , C23C4/067 , C23C14/223 , Y10T428/12486
摘要： A heterogeneous composite body that is spall resistant and comprises a substantially discontinuous cermet phase in a substantially continuous metal rich matrix phase. The heterogeneous composite body is typically bonded to a substrate to form a hardfacing on the substrate. The heterogeneous composite body exhibits ductile phase toughening with a strain to failure of at least about 2 percent, a modulus of elasticity of less than about 35 million pounds per square inch, and a density of less than about 7 grams per cubic centimeter. The metal rich matrix phase between the ceramic rich regions in the heterogeneous composite body has an average minimum span of about 0.5 to 8 microns to allow ductility in the heterogeneous composite body. The heterogeneous composite body has a Vicker's hardness number of greater than approximately 500. The ceramic rich regions exhibit high hardness as compared with the matrix phase.
摘要翻译：一种异质复合体，其具有抗剥落性，并且在基本连续的富金属基质相中包含基本上不连续的金属陶瓷相。非均相复合体通常结合到基底上以在基底上形成硬化面。非均相复合体表现出韧性相增韧，破坏应变至少约为2％，弹性模量小于约3500万磅/平方英寸，密度小于约7克/立方厘米。非均相复合体中陶瓷富集区之间的富金属基质相的平均最小跨度为约0.5至8微米，以允许非均相复合体中的延展性。非均相复合体具有大于约500的维氏硬度值。与基体相相比，富陶瓷区显示出高的硬度。

10. 发明授权

US08460796B2 Coatings, composition, and method related to non-spalling low density hardface coatings 有权
标题翻译：与非剥落低密度硬质涂层相关的涂料，组合物和方法
公开(公告)号：US08460796B2
公开(公告)日：2013-06-11
申请号：US12699779
申请日：2010-02-03
申请人： Andrew J. Sherman
发明人： Andrew J. Sherman
IPC分类号： B32B3/00 , B32B5/16 , B32B7/00 , B32B9/00 , B32B13/04 , B32B15/04 , B32B19/00 , B05D1/08 , C23C4/00 , H05H1/26 , C23C4/04 , C23C4/08
CPC分类号： C23C4/06 , Y10T428/12097 , Y10T428/24893
摘要： A composite body that is spall resistant and comprises a substantially discontinuous cermet phase in a substantially continuous metal rich matrix phase. The composite body is typically bonded to a substrate to form a hardfacing on the substrate. The composite body exhibits ductile phase toughening with a strain to failure of at least about 2 percent, a modulus of elasticity of less than about 46 million pounds per square inch, and a density of less than about 7 grams per cubic centimeter. The metal rich matrix phase between the ceramic rich regions in the composite body has an average minimum span of about 0.5 to 8 microns to allow ductility in the composite body. The composite body has a Vicker's hardness number of greater than approximately 650. The discontinuous cermet phase is in the form of ceramic rich regions embedded within the composite body, and it includes ceramic particles and a cermet binder. The ceramic particles having a Moh's hardness of at least approximately 7.5, a modulus of elasticity of less than approximately 46 million pounds per square inch, and an average particle size of from about 0.1 to 10 microns. The ceramic rich regions exhibit high hardness as compared with the matrix phase.
摘要翻译：一种复合体，其具有抗剥落性并且在基本上连续的富金属基质相中包含基本上不连续的金属陶瓷相。复合体通常结合到基底以在基底上形成表面硬化。复合体表现出韧性相增韧，应变至少为约2％，弹性模量小于约4600万磅/平方英寸，密度小于约7克/立方厘米。复合体中富陶瓷区域之间富含金属的基体相的平均最小跨度为约0.5至8微米，以允许复合体中的延展性。复合体具有大于约650的维氏硬度值。不连续的金属陶瓷相是嵌入复合体内的富陶瓷区的形式，其包括陶瓷颗粒和金属陶瓷粘合剂。陶瓷颗粒的莫氏硬度至少为7.5，弹性模量小于约4600万磅/平方英寸，平均粒度为约0.1至10微米。与基体相相比，富陶瓷区表现出高的硬度。

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