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    • 5. 发明授权
    • Separation of copper from cobalt
    • 铜与钴的分离
    • US3887679A
    • 1975-06-03
    • US25839672
    • 1972-05-31
    • FALCONBRIDGE NICKEL MINES LTD
    • WIGSTOL EIVINDFROYLAND KJELL ELNAR
    • C22B23/00C01G3/00C22B3/00C22B3/20C22B3/28C22B15/00C01G51/00
    • C22B3/0012C01G3/00C01G3/003C22B3/001Y02P10/234
    • A solvent extraction process for the improved separation of copper from cobalt in chloride solutions in which an organic solution containing an amine solvent, such as tri-iso-octylamine, is cycled around a closed organic circuit comprising in turn co-extraction of cobalt and copper from the chloride solution, preferential stripping of cobalt from the organic solution into water or dilute chloride solution thereby forming a cobalt eluate, stripping of copper from the organic, and return of the regenerated organic to the co-extraction step. The invention comprises dividing the organic into two streams, coextracting cobalt and copper from the chloride solution into one stream, preferentially extracting copper from the cobalt eluate into the other stream, and combining the two streams for preferential cobalt stripping therefrom, thereby forming a closed preferential cobalt stripping, preferential copper extracting circuit and producing a purified cobalt eluate.
    • 用于在氯化物溶液中改善铜与钴的分离的溶剂萃取方法,其中将含有胺溶剂的有机溶液(例如三异辛基胺)围绕封闭的有机回路循环,所述闭合有机回路包括依次共萃取钴 和来自氯化物溶液的铜,优先将钴从有机溶液中汽提到水或稀氯化物溶液中,由此形成钴洗脱液,从有机物中剥离铜,并将再生有机物返回共萃取步骤。 本发明包括将有机物分成两股,将氯化物溶液中的钴和铜共萃取成一股料流,优先将铜从钴洗脱液中提取到另一股料流中,并将两股料流合并,从而形成优质的钴 封闭的优选钴剥离,优选铜提取回路和生产纯化的钴洗脱液。
    • 10. 发明授权
    • Treatment of metal chlorides in fluidized beds
    • 流化床中金属氯化物的处理
    • US3642441A
    • 1972-02-15
    • US3642441D
    • 1967-09-14
    • FALCONBRIDGE NICKEL MINES LTD
    • WEERT GEZINUS VAN
    • C01B13/26C22B1/10C22B23/02C01B13/14C01G49/02C01G53/04
    • C01B13/26C01P2004/50C01P2004/61C01P2006/10C01P2006/80C22B1/10C22B23/02Y02P10/234
    • A method and apparatus for thermal treatment of solid particles in fluidized beds and carrying out of heat treatments and other reactions therein at elevated temperatures such as formation of metal oxides by the endothermic reaction of metal chlorides with water. An explosive mixture of gases is supplied to a fluidized bed of solid particles in a reactor as a multiplicity of separated streams, each stream is maintained at a temperature below the ignition temperature of the mixture by cooling a portion thereof outside the reactor, and at a velocity greater than the ignition velocity of the mixture by supplying the mixture under sufficient pressure, and the mixture is then combusted in the bed to produce hot fluidizing gases, thereby maintaining the bed in a fluidized condition at an elevated temperature and providing a suitable environment for the conduct of heat treatments and other reactions.
    • 一种用于热处理流化床中的固体颗粒并在高温下进行热处理和其它反应的方法和装置,例如金属氯化物与水的吸热反应形成金属氧化物。 将气体的爆炸性混合物作为多个分离的物流供应到反应器中的固体颗粒的流化床,每个流通过冷却其在反应器外部的一部分而保持在低于混合物的着火温度的温度下,并且在 通过在足够的压力下供应混合物,混合物的速度大于混合物的点火速度,然后将混合物在床中燃烧以产生热流化气体,从而将床保持在升高的温度下处于流化状态,并为 进行热处理等反应。