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    • 6. 发明授权
    • Staged upflow hydroprocessing with noncatalytic impurity removal from
the first stage vapor effluent
    • 从第一级蒸汽流出物中分离出非催化杂质,分阶段上流加氢处理
    • US5989411A
    • 1999-11-23
    • US177735
    • 1998-10-23
    • Ramesh Gupta
    • Ramesh Gupta
    • C10G65/02C10G25/00C10G45/00C10G45/02C10G45/32C10G45/44C10G45/58C10G47/00C10G49/00C10G65/04C10G67/02C10G67/04C10G73/02C10G17/00
    • C10G49/002C10G67/04Y10S203/06
    • A hydroprocessing process for removing impurities from a feed comprising a hydrocarbonaceous liquid comprises at least two cocurrent, upflow hydroprocessing reaction stages and a non-catalytic, vapor-liquid contacting stage. The reaction and contacting stages may all be in the same reactor vessel. The feed and a hydrogen treat gas are passed up into a catalyst bed which comprises the first reaction stage, which produces a partially hydroprocessed liquid and vapor effluent. This first stage vapor is passed up into the contacting stage in which it contacts a hydrocarbonaceous liquid which reduces the vapor impurity content. The impurity-enriched contacting liquid passes down and mixes with the first stage liquid effluent. The combined effluents and hydrogen are passed up into the second reaction stage to form a processed product liquid and hydrogen-containing vapor effluent. This second reaction stage vapor effluent is passed up into the first stage to provide at least a portion of the hydrogen for the first stage reaction. Additional product liquid may be recovered by cooling the contacting and condensing the purified contacting stage vapor effluent.
    • 用于从包含烃液体的进料中除去杂质的加氢处理方法包括至少两个并流,向上加氢处理反应阶段和非催化气液接触阶段。 反应和接触阶段都可以在同一反应容器中。 进料和氢气处理气体被送入催化剂床,催化剂床包括第一反应段,其产生部分加氢处理的液体和蒸气流出物。 该第一级蒸气通入其接触阶段,在该阶段中,其接触含烃液体,这降低了蒸气杂质含量。 杂质富集的接触液体向下流动并与第一级液体流出物混合。 将合并的废水和氢气输送到第二反应阶段以形成加工产物液体和含氢蒸汽流出物。 将该第二反应段蒸气流出物向上流入第一阶段以提供用于第一阶段反应的氢的至少一部分。 可以通过冷却接触并冷凝纯化的接触级蒸气流出物来回收附加的产物液体。
    • 8. 发明授权
    • Continuous in-situ combination process for upgrading heavy oil
    • 连续原位组合工艺提升重油
    • US5935421A
    • 1999-08-10
    • US734322
    • 1996-10-21
    • Glen BronsRonald D. MyersRoby Bearden
    • Glen BronsRonald D. MyersRoby Bearden
    • C10G29/04C10G67/02C10G19/02
    • C10G29/04C10G67/02
    • The invention relates to an integrated, continuous process for the removal of organically bound sulfur (e.g., mercaptans, sulfides and thiophenes) comprising the steps of contacting a heavy oil, sodium hydroxide, hydrogen and water at a temperature of from about 380.degree. C. to 450.degree. C. to partially desulfurize the heavy oil and to form sodium sulfide, contacting said sodium sulfide via steam stripping to convert the sodium sulfide to sodium hydroxide and the sulfur recovered as hydrogen sulfide. The sodium hydroxide is recirculated for reuse. The partially desulfurized, dewatered heavy oil is treated with sodium metal under desulfurizing conditions, typically at a temperature of from about 340.degree. C. to about 450.degree. C., under a hydrogen pressure of at least about 50 psi to essentially desulfurize the oil, and form sodium sulfide. Optionally, the sodium salt generated can be regenerated to sodium metal using regeneration technology. The process advantageously produces essentially sulfur-free product oils having reduced nitrogen, oxygen and metals contents and reduced viscosity, density, molecular weight and heavy ends.
    • 本发明涉及用于去除有机结合硫(例如硫醇,硫化物和噻吩)的一体化连续方法,包括以下步骤:在约380℃的温度下使重质油,氢氧化钠,氢气和水接触。 至450℃,以部分重硫脱硫并形成硫化钠,通过汽提将硫化钠接触,将硫化钠转化为氢氧化钠,硫作为硫化氢回收。 将氢氧化钠再循环以重新使用。 部分脱硫的脱水重油在脱硫条件下,通常在约340℃至约450℃的温度下,在至少约50psi的氢气压力下用金属钠处理以使油基本上脱硫, 并形成硫化钠。 任选地,所生成的钠盐可以使用再生技术再生成金属钠。 该方法有利地产生具有降低的氮,氧和金属含量以及降低的粘度,密度,分子量和重量的基本上无硫产品油。