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    • 3. 发明授权
    • Liquid coating compositions containing little or no solvent
    • 含有很少或不含溶剂的液体涂料组合物
    • US4204014A
    • 1980-05-20
    • US36708
    • 1979-05-07
    • Jorg DorffelWerner AndrejewskiWilfried Bartz
    • Jorg DorffelWerner AndrejewskiWilfried Bartz
    • C08G63/16C08G63/20C08G63/91C09D167/00B05D3/02C08L61/20C08L67/00
    • C08G63/914C08G63/16C08G63/20C09D167/00
    • In a liquid coating composition comprising a small amount of solvent or no solvent, a binder and optionally conventional auxiliary agents, wherein the binder consists essentially of:(A) 45-10% by weight of an aminoplast, the low molecular weight precursors thereof, or mixtures thereof; and(B) 55-90% by weight of an at least difunctional polyester or a mixture of such polyesters; wherein the polyester component B has been produced by the condensation of a conventional alcohol component I with an acid component III, wherein component III consists essentially of a mixture of:III.1 67-92 molar percent of hexahydroterephthalic acid or a lower alkyl ester thereof; andIII.2 8-33 molar percent of an aromatic dicarboxylic acid or a lower alkyl ester derivative thereof;wherein the polyester component B has a molecular weight of 300-1,500 and wherein the binder may be obtained by the cocondensation of aminoplast component A with polyester component B, or by the cocondensation of the starting materials used for the production of aminoplast component A with polyester component B;the improvement wherein component III.2 is terephthalic acid or a lower alkyl ester derivative thereof.
    • 在包含少量溶剂或无溶剂的液体涂料组合物中,粘合剂和任选的常规助剂,其中所述粘合剂基本上由以下组成:(A)45-10重量%的氨基塑料,其低分子量前体, 或其混合物; 和(B)55-90重量%的至少双官能聚酯或这些聚酯的混合物; 其中聚酯组分B通过常规醇组分I与酸组分III的缩合制备,其中组分III基本上由下列混合物组成:III.167-92摩尔%的六氢对苯二甲酸或其低级烷基酯 ; 和III.2 8-33摩尔%的芳族二羧酸或其低级烷基酯衍生物; 其中聚酯组分B的分子量为300-1,500,其中粘合剂可以通过氨基塑料组分A与聚酯组分B的缩聚获得,或通过用于生产氨基塑料组分A的原料与聚酯的共缩聚 组分B; 其中组分III.2是对苯二甲酸或其低级烷基酯衍生物的改进。
    • 5. 发明授权
    • Process for the orthomethylation of phenolic compounds
    • 酚类化合物的正甲基化方法
    • US4482758A
    • 1984-11-13
    • US449294
    • 1982-12-13
    • Reinhard Seig
    • Reinhard Seig
    • B01J23/00C07B61/00C07C27/00C07C37/16C07C39/07C07C67/00
    • C07C37/16
    • For the orthomethylation of phenolic compounds containing at least one hydrogen atom in the ortho position, the phenol compound is reacted with methanol in the gaseous phase in the presence of an oxidic catalyst containing iron, chromium, and cerium in an atomic ratio of Fe:Cr:Ce of 1:0.005 to 0.1:0.005 to 0.1, at temperatures of 270.degree.-450.degree. C., pressures of 1-40 bar, and rates per unit volume of 0.05-3 h.sup.-1. The temperature within the catalyst bed is maintained constant within a narrow temperature range .DELTA.T of up to 20.degree. C. The catalyst has a very long service life with a high activity, and provides a high selectivity.
    • 对于在邻位含有至少一个氢原子的酚类化合物的正甲基化,在含铁,铬和铈的氧化催化剂存在下,使酚化合物与甲醇在气相中反应,原子比为Fe:Cr :Ce为1:0.005〜0.1:0.005〜0.1,温度为270〜-450℃,压力为1-40巴,单位体积率为0.05-3h-1。 催化剂床内的温度在高达20℃的DELTA T的窄温度范围内保持恒定。催化剂具有非常长的使用寿命,具有高活性,并提供高选择性。