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1. 发明申请

US20070082977A1 Ink composition for color-memorizing photochromic writing instrument and writing instrument using the same 审中-公开
标题翻译：用于记忆光致变色书写工具和书写工具的墨水组合物
公开(公告)号：US20070082977A1
公开(公告)日：2007-04-12
申请号：US11245167
申请日：2005-10-07
申请人： Yutaka Shibahashi , Michiyuki Yasuda , Masahiro Irie
发明人： Yutaka Shibahashi , Michiyuki Yasuda , Masahiro Irie
IPC分类号： C09D11/00
CPC分类号： C09D11/17 , C09D11/50
摘要： An ink composition for a color-memorizing photochromic writing instrument, which comprises a photochromic agent containing a diarylethene photochromic compound dissolved, dispersed or suspended in a vehicle containing at least a solvent and a binder.
摘要翻译：一种用于记忆光致变色书写工具的油墨组合物，其包含溶解，分散或悬浮在至少含有溶剂和粘合剂的载体中的二烯丙基光致变色化合物的光致变色剂。

2. 发明申请

US20060053975A1 Color-memorizing photochromic writing instrument, color-memorizing photochromic writing instrument set using the same and method for alternately expressing color-memorizing photochromic function of writing image 有权
公开(公告)号：US20060053975A1
公开(公告)日：2006-03-16
申请号：US11226291
申请日：2005-09-15
申请人： Yutaka Shibahashi , Michiyuki Yasuda , Masahiro Irie
发明人： Yutaka Shibahashi , Michiyuki Yasuda , Masahiro Irie
IPC分类号： B41B1/00 , G02B5/23
CPC分类号： B43K5/02 , B43K7/02 , B43K8/03 , B43K23/12 , C09D11/17 , C09D11/18
摘要： A color-memorizing photochromic writing instrument, which comprises a writing tip portion connected to a light-shielding tubular member or refill; and a color-memorizing photochromic ink, wherein the ink is prepared by dissolving, dispersing or suspending a diarylethene photochromic compound in a vehicle containing at least a solvent and a binder, wherein the diarylethene photochromic compound is in a coloring state, and a color-memorizing photochromic writing instrument set comprising the writing instrument and a color-changing means.

3. 发明授权

US08444450B2 Method for alternately expressing color-memorizing photochromic function in toy element, and an alternately color-memorizing photochromic toy 有权
标题翻译：在玩具元件中交替表现存储光致变色功能的方法，以及交替记忆光致变色玩具
公开(公告)号：US08444450B2
公开(公告)日：2013-05-21
申请号：US10694006
申请日：2003-10-28
申请人： Yutaka Shibahashi , Michiyuki Yasuda , Masahiro Irie
发明人： Yutaka Shibahashi , Michiyuki Yasuda , Masahiro Irie
IPC分类号： A63H30/00
CPC分类号： A63H33/22
摘要： A toy comprises a toy element comprising a photochromic layer which contains a photochromic compound having a photo memory function (color-memorizing photochromic property), maintains a coloring state by developing a color through the irradiation of ultraviolet rays or sunlight containing ultraviolet rays and changes into decolorizing state through its decolorization by the irradiation of visible light, and a color-changing means which contains at least one of an ultraviolet ray absorbent and a light-shading pigment capable of shading at least ultraviolet rays, changes the photochromic compound of the coloring state into decolorizing state by cutting off ultraviolet rays of sunlight and thereby effecting irradiation of visible light, and maintains the changed state, wherein a function to memorize and maintain coloring and decolorizing states alternately is expressed by arranging the color-changing means under such a condition that it is contacted or non-contacted with the photochromic layer.
摘要翻译：一种玩具，其特征在于，包括含有具有光记录功能的光致变色化合物（着色光致变色性）的光致变色层的玩具元件，通过紫外线的照射或含有紫外线的太阳光的照射而变色而保持着色状态通过其可见光的照射而脱色的脱色状态，以及包含紫外线吸收剂和能够至少遮蔽紫外线的遮光颜料中的至少一种的变色装置，使着色状态的光致变色化合物通过切断太阳光的紫外线，从而进行可见光的照射而进入脱色状态，并且保持改变状态，其中交替记忆和保持着色和脱色状态的功能是通过将颜色变化装置布置在以下条件下表示的：它与光致变色接触或未接触层。

4. 发明授权

US07575386B2 Color-memorizing photochromic writing instrument, color-memorizing photochromic writing instrument set using the same and method for alternately expressing color-memorizing photochromic function of writing image 有权
标题翻译：彩色记忆光致变色书写工具，使用相同的色彩记忆光致变色书写装置和交替表达写入图像的存储光致变色功能的方法
公开(公告)号：US07575386B2
公开(公告)日：2009-08-18
申请号：US11226291
申请日：2005-09-15
申请人： Yutaka Shibahashi , Michiyuki Yasuda , Masahiro Irie
发明人： Yutaka Shibahashi , Michiyuki Yasuda , Masahiro Irie
IPC分类号： B43K5/00
CPC分类号： B43K5/02 , B43K7/02 , B43K8/03 , B43K23/12 , C09D11/17 , C09D11/18
摘要： A color-memorizing photochromic writing instrument, which comprises a writing tip portion connected to a light-shielding tubular member or refill; and a color-memorizing photochromic ink, wherein the ink is prepared by dissolving, dispersing or suspending a diarylethene photochromic compound in a vehicle containing at least a solvent and a binder, wherein the diarylethene photochromic compound is in a coloring state, and a color-memorizing photochromic writing instrument set comprising the writing instrument and a color-changing means.
摘要翻译：一种彩色记忆光致变色书写工具，其包括连接到遮光管状构件或再填充物的书写尖端部分; 和着色记忆光致变色墨水，其中通过将二芳基乙烯光致变色化合物溶解，分散或悬浮在至少含有溶剂和粘合剂的载体中制备墨，其中二芳基乙烯光致变色化合物处于着色状态，记忆包括书写工具和变色装置的光致变色书写装置。

5. 发明授权

US09937434B2 Photochromic toy 有权
公开(公告)号：US09937434B2
公开(公告)日：2018-04-10
申请号：US14131610
申请日：2012-07-13
申请人： Michiyuki Yasuda , Yutaka Shibahashi , Yoshie Kamiya
发明人： Michiyuki Yasuda , Yutaka Shibahashi , Yoshie Kamiya
IPC分类号： A63H33/22 , C09K9/02 , C09K11/08 , C09K11/77
CPC分类号： A63H33/22 , C09K9/02 , C09K11/0883 , C09K11/7731 , C09K11/7734 , C09K11/7774
摘要： The present invention relates to a photochromic toy containing a light irradiator equipped with a light source and a toy main body containing a photochromic compound, in which the light source has a peak wavelength in the range of from 400 nm to 495 nm and the photochromic compound satisfies the following expression (1) between the integrated value of absorbance (x) in the range of from a wavelength showing a maximum absorbance in less than 400 nm to a wavelength of 400 nm and the integrated value of absorbance (y) in the wavelength range of from 400 nm to 700 nm. y/x≥0.02 (1)

6. 发明授权

US06713431B2 Metallic luster tone thermochromic laminate member 有权
标题翻译：金属色泽热变色层压件
公开(公告)号：US06713431B2
公开(公告)日：2004-03-30
申请号：US10179393
申请日：2002-06-26
申请人： Michiyuki Yasuda , Yutaka Shibahashi
发明人： Michiyuki Yasuda , Yutaka Shibahashi
IPC分类号： B41M540
CPC分类号： B41M5/305 , B41M5/41
摘要： A metallic luster tone thermochromic laminate member 1, which comprises a laminate of a metallic luster layer 2 containing a metallic luster pigment prepared by coating the surface of a synthetic mica or thin section aluminum oxide with a metal oxide and a reversible thermochromic layer 3 containing a thermochromic composition comprising an electron-donating color-forming organic compound, an electron-accepting compound and an organic compound medium in which color reactions of both compounds take place reversibly. The metallic luster tone thermochromic laminate member can visualize metallic luster colors having glittering high brightness and distinct changes in color by its reversible thermochromic layer so that it can be used in versatile applications and developments.
摘要翻译：一种金属光泽热致变色层压件1，其包括金属光泽层2的层压材料，该金属光泽层2含有通过将金属氧化物涂覆合成云母或薄壁氧化铝的表面制备的金属光泽颜料和可逆热致变色层3，包含给电子成色有机化合物，电子接受性化合物和两种化合物的显色反应可逆地发生的有机化合物介质的热变色组合物。金属色泽热变色层压件可以通过其可逆热变色层来显现具有闪烁的高亮度和明显的颜色变化的金属光泽颜色，从而可以用于通用的应用和开发。

7. 发明授权

US5352649A Thermochromic laminate member, and composition and sheet for producing the same 失效
标题翻译：热变色层压构件，及其制造用组合物和片材
公开(公告)号：US5352649A
公开(公告)日：1994-10-04
申请号：US907577
申请日：1992-07-02
申请人： Yutaka Shibahashi , Michiyuki Yasuda
发明人： Yutaka Shibahashi , Michiyuki Yasuda
IPC分类号： A61K8/02 , A61Q3/00 , B41M3/14 , B41M5/26 , B41M5/28 , B41M5/40 , B41M5/42 , B44F1/08 , D06M23/00 , D06P1/00 , D06Q1/00 , D06Q1/10
CPC分类号： A61Q3/00 , A61K8/02 , B41M3/142 , B41M5/282 , B41M5/426 , B44F1/08 , D06M23/00 , D06P1/0096 , D06Q1/00 , D06Q1/10 , A61K2800/438 , A63F2250/1031 , H01H2209/0021 , Y10S428/913 , Y10T428/251 , Y10T428/2991
摘要： A thermochromic laminate member capable of reversible change from a metallic luster color to a colorless state, comprises a first layer for regulating the wavelength of reflected light, composed of a metal luster pigment, which consists of natural mica surfacially covered with titanium oxide and has a grain size of 5 to 100 .mu.m, and a film forming material; anda second layer composed of a thermochromic material, which consists of an electron donating compound, an electron accepting compound, and an organic medium enabling a reversible color-forming reaction between said compounds and has a luminocity value of 6 or lower in the colored state and a luminocity value of 8 or higher in the colorless state, and a film forming material.
摘要翻译：能够从金属光泽颜色变为无色状态的热致变色层压构件包括由金属光泽颜料构成的用于调节反射光的波长的第一层，该金属光泽颜料由表面覆盖有氧化钛的天然云母组成，并具有晶粒尺寸为5〜100μm，成膜材料为以及由电致发光化合物，电子接受性化合物和能够在所述化合物之间进行可逆成色反应的有机介质构成的热致变色材料构成的第二层，并且在着色状态下具有6以下的发光度值无色状态下的亮度值为8以上，成膜材料。

8. 发明申请

US20140141689A1 PHOTOCHROMIC TOY 有权
标题翻译：光电玩具
公开(公告)号：US20140141689A1
公开(公告)日：2014-05-22
申请号：US14131610
申请日：2012-07-13
申请人： Michiyuki Yasuda , Yutaka Shibahashi , Yoshie Kamiya
发明人： Michiyuki Yasuda , Yutaka Shibahashi , Yoshie Kamiya
IPC分类号： A63H33/22
CPC分类号： A63H33/22 , C09K9/02 , C09K11/0883 , C09K11/7731 , C09K11/7734 , C09K11/7774
摘要： The present invention relates to a photochromic toy containing a light irradiator equipped with a light source and a toy main body containing a photochromic compound, in which the light source has a peak wavelength in the range of from 400 nm to 495 nm and the photochromic compound satisfies the following expression (1) between the integrated value of absorbance (x) in the range of from a wavelength showing a maximum absorbance in less than 400 nm to a wavelength of 400 nm and the integrated value of absorbance (y) in the wavelength range of from 400 nm to 700 nm. y/x≧0.02 (1)
摘要翻译：本发明涉及一种含有装有光源的光照射器和含有光致变色化合物的玩具主体的光致变色玩具，其中光源的峰值波长在400nm至495nm的范围内，光致变色化合物满足以下表达式（1）在从小于400nm到波长400nm的最大吸光度的波长范围内的吸光度（x）的积分值与波长中的吸光度（y）的积分值范围为400nm至700nm。 y /x≥0.02（1）

9. 发明申请

US20050012081A1 Photochromic material 有权
标题翻译：光致变色材料
公开(公告)号：US20050012081A1
公开(公告)日：2005-01-20
申请号：US10892156
申请日：2004-07-16
申请人： Michiyuki Yasuda , Jun Sugai , Fumihiro Kimura
发明人： Michiyuki Yasuda , Jun Sugai , Fumihiro Kimura
IPC分类号： C09K9/02 , C08K5/357 , C09K15/30 , G02B5/23
CPC分类号： C08K5/357 , Y10S428/913
摘要： A photochromic material comprising a styrene-based oligomer having a weight average molecular weight of from 200 to 6000 and a photochromic compound selected from the group consisting of spirooxazine derivatives and spiropyran derivatives.
摘要翻译：包含重均分子量为200-6000的苯乙烯基低聚物和选自螺恶嗪衍生物和螺吡喃衍生物的光致变色化合物的光致变色材料。

10. 发明授权

US5928803A Temperature-sensitive reversibly deformable laminate 失效
标题翻译：温度敏感的可逆变形层压板
公开(公告)号：US5928803A
公开(公告)日：1999-07-27
申请号：US827254
申请日：1997-03-28
申请人： Michiyuki Yasuda
发明人： Michiyuki Yasuda
IPC分类号： A63H33/22 , B32B7/02 , B32B27/08 , B32B27/32 , B41M5/28 , B41M3/12
CPC分类号： A63H33/22 , B32B27/32 , B41M5/28 , Y10S428/927 , Y10T428/24998 , Y10T428/249982 , Y10T428/249992
摘要： A temperature-sensitive reversibly deformable laminate which is reversibly deformable towards both sides thereof with changes in temperature to take three states; an original state at room temperature, a contracted state at a low temperature, and an expanded state at a high temperature, wherein the laminate is composed of at least two resin layers having different coefficients of thermal expansion.
摘要翻译：一种温度敏感的可逆变形的层压板，其可朝两侧可逆地变形，温度变化为三种状态; 在室温下的原始状态，低温下的收缩状态和高温下的膨胀状态，其中层压体由具有不同热膨胀系数的至少两个树脂层构成。

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