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    • 3. 发明授权
    • Method of evaluating lifetime related quality of semiconductor surface
    • 评估半导体表面寿命相关质量的方法
    • US5612539A
    • 1997-03-18
    • US557563
    • 1995-11-14
    • Ryoji HoshiYutaka KitagawaraTakao Takenaka
    • Ryoji HoshiYutaka KitagawaraTakao Takenaka
    • G01N21/63G01N21/66G01R31/26H01L21/66G01R31/265
    • G01R31/2607G01N21/6489H01L22/14
    • A lifetime related quality evaluation method, used with a semiconductor wafer having a semiconductor thin layer over the main surface of a semiconductor substrate, for evaluating the lifetime related quality of the semiconductor thin layer and/or the vicinity thereof, characterized by: generating electron-hole pairs in the vicinity of a surface of the semiconductor thin layer by the use of excitation light having a larger energy than the band gap of a semiconductor to be tested; then detecting the intensity at a particular wavelength of light emitted by recombination of the electron-hole pairs; and evaluating the lifetime related quality of the semiconductor thin layer and/or the vicinity thereof based on the detected intensity. The lifetime related quality evaluation method realizes a non-contact, non-destructive quality evaluation of the epitaxial semiconductor wafer.
    • 一种寿命相关的质量评估方法,用于在半导体衬底的主表面上具有半导体薄层的半导体晶片,用于评估半导体薄层的寿命相关质量和/或其附近,其特征在于: 通过使用具有比待测半导体的带隙大的能量的激发光,在半导体薄层的表面附近的空穴对; 然后检测由电子 - 空穴对的复合发射的光的特定波长处的强度; 以及基于检测到的强度来评估半导体薄层和/或其附近的寿命相关质量。 寿命相关的质量评估方法实现了外延半导体晶片的非接触,非破坏性的质量评估。
    • 5. 发明授权
    • Method for evaluation of spatial distribution of deep level
concentration in semiconductor crystal
    • 半导体晶体深层次浓度空间分布评价方法
    • US5302832A
    • 1994-04-12
    • US950677
    • 1992-09-25
    • Yutaka KitagawaraRyoji HoshiTakao Takenaka
    • Yutaka KitagawaraRyoji HoshiTakao Takenaka
    • G01N21/64H01L21/66G01N21/63
    • G01N21/6489
    • Spatial distribution of deep level concentration near the surface of a semiconductor wafer is evaluated quickly and accurately by a method which comprises at least a step of scanning the surface of the semiconductor wafer in the X and Y direction with a laser beam for carrier excitation from a laster beam source in accordance with the room-temperature photoluminescence (PL) process thereby measuring the wafer map (M.sub.D) of deep level PL intensity (I.sub.D) and wafer map (M.sub.B) of band edge PL intensity (I.sub.B) in the semiconductor wafer and a step of dividing the wafer map (M.sub.D) of PL intensity (I.sub.D) by the .nu.'th power of the wafer map (M.sub.B) of PL intensity (I.sub.B) {the magnitude of the .nu.'th power presenting the numerical value obtained by empirically confirming the dependence of the band edge PL intensity (I.sub.B) on the power of the excitation laster mean} thereby determining the spatial distribution (M.sub.N) of the relative value of deep level concentration (N.sub.D) and performing the evaluation of the distribution of relative deep level concentration on the basis of the spatial distribution (M.sub.N) of the relative deep level concentration (N.sub.D).
    • 通过一种方法来快速准确地评估半导体晶片表面附近的深度浓度的空间分布,该方法至少包括用X轴和Y方向的半导体晶片的表面用激光束从载体激发扫描 根据室温光致发光(PL)工艺,由此测量半导体晶片中的带边PL强度(IB)的深层PL强度(ID)和晶片图(MB)的晶片图(MD),以及 将PL强度(ID)的晶片图(MD)除以PL强度(IB)的晶片图(MB)的(ny)'功率(第(ny))次的幅度 通过经验性地确认带边缘PL强度(IB)对激发灯的平均值的功率的依赖性获得的数值,从而确定深层次浓度(ND)的相对值的空间分布(MN),并执行 这个地区 在相对深层次浓度(ND)的空间分布(MN)的基础上贡献相对深层次浓度。
    • 9. 发明授权
    • Determining carbon concentration in silicon single crystal by FT-IR
    • 通过FT-IR测定硅单晶中的碳浓度
    • US5444246A
    • 1995-08-22
    • US127522
    • 1993-09-28
    • Yutaka KitagawaraHiroshi KubotaMasaro Tamatsuka
    • Yutaka KitagawaraHiroshi KubotaMasaro Tamatsuka
    • G01N21/35
    • G01N21/3563G01N2021/3568G01N2021/3595
    • The substitutional carbon concentration in a silicon single crystal is determined by determining by FT-IR the infrared absorbance spectrum using as a reference a substantially carbon-free silicon single crystal having substantially the same degree of free carrier absorption and produced by the same process as the sample. A subtraction factor used in the determination is calculated from the infrared absorbance spectra of the sample and the reference. A subtraction spectrum indicating the difference between the sample and the reference at the relevant wave number for carbon is computed, and the carbon concentration in the sample is determined from the distance of the absorption peak of the subtraction spectrum of the localized vibration of substitutional carbon in the sample from a base line of the subtraction spectrum. An FT-IR carbon concentration determination apparatus embodying the method is also disclosed.
    • 通过FT-IR测定红外吸收光谱来确定硅单晶中的取代碳浓度,使用基本上无碳的硅单晶,其基本上具有相同的游离载体吸收程度,并且通过与 样品。 用于测定的减法因子是从样品的红外吸收光谱和参考值计算的。 计算指示样品与碳相关波数的参考值之间的差异的减法谱,样品中的碳浓度由取代碳的局部振动的减法谱的吸收峰的距离确定 来自相减光谱基线的样本。 还公开了体现该方法的FT-IR碳浓度测定装置。