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    • 1. 发明申请
    • PROCESS OF PURIFYING NANODIAMOND COMPOSITIONS AND APPLICATIONS THEREOF
    • 纯化NANODIAMOND组合物的方法及其应用
    • US20100028675A1
    • 2010-02-04
    • US12300660
    • 2007-05-14
    • Yury GogotsiVadym MochalinSebastian OsswaldGleb Yushin
    • Yury GogotsiVadym MochalinSebastian OsswaldGleb Yushin
    • C01B31/06
    • B82Y30/00C01B32/28Y10T428/2982
    • The presence of large amounts of non-diamond carbon in detonation synthesized nanodiamond (ND) severely limits applications of this exciting nanomaterial. An environmentally-friendly process is disclosed to selectively remove sp2-bonded carbon from ND. The content of up to 96% of sp3-bonded carbon in the oxidized samples is comparable to that found in microcrystalline diamond and is unprecedented for ND powders. Transmission electron microscopy and Fourier transform infrared spectroscopy studies show high purity 5-nm ND particles covered by oxygen-containing surface functional groups. The surface functionalization can be controlled by subsequent treatments. In contrast to current purification techniques, the disclosed process does not require the use of toxic or aggressive chemicals, catalysts or inhibitors and opens avenues for numerous new applications of nanodiamond.
    • 爆炸合成纳米金刚石(ND)中大量非金刚石碳的存在严重限制了这种激发纳米材料的应用。 公开了一种环境友好的方法来选择性地从ND去除sp2结合的碳。 氧化样品中高达96%的sp3键合碳的含量与微晶金刚石中的含量相当,对于ND粉末是前所未有的。 透射电子显微镜和傅里叶变换红外光谱研究显示由含氧表面官能团覆盖的高纯度5-nm ND颗粒。 表面官能化可以通过后续处理来控制。 与目前的纯化技术相反,所公开的方法不需要使用有毒或侵蚀性的化学物质,催化剂或抑制剂,并为纳米金刚石的众多新应用开辟了途径。