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1. 发明授权

US06770431B2 Silver halide color photosensitive material 失效
标题翻译：卤化银色感光材料
公开(公告)号：US06770431B2
公开(公告)日：2004-08-03
申请号：US10329466
申请日：2002-12-27
申请人： Yuki Mizukawa , Masaaki Tsukase , Toshio Kawagishi , Hiroshi Fukuzawa
发明人： Yuki Mizukawa , Masaaki Tsukase , Toshio Kawagishi , Hiroshi Fukuzawa
IPC分类号： G03C108
CPC分类号： G03C7/3835 , G03C7/301 , G03C7/39268
摘要： A silver halide color photosensitive material comprising a 1H-pyrazolo[3,2-c]-1,2,4-triazole type coupler having, in its molecule, at least one substituent represented by the following general formula (I): wherein R1 represents a substituent; m represents an integer of 0 to 4; and R2 represents an alkyl group, alkenyl group or aryl group.
摘要翻译：一种卤化银色感光材料，其包含1H-吡唑并[3,2-c] -1,2,4-三唑型成色剂，其分子中具有至少一个由以下通式（I）表示的取代基：其中R 1 表示取代基; m表示0〜4的整数，并且R 2表示烷基，烯基或芳基。

2. 发明授权

US06645711B2 Silver halide photographic light-sensitive material 失效
标题翻译：卤化银照相感光材料
公开(公告)号：US06645711B2
公开(公告)日：2003-11-11
申请号：US10197488
申请日：2002-07-18
申请人： Osamu Uchida , Toshio Kawagishi , Masaaki Tsukase , Kazuhiko Matsumoto
发明人： Osamu Uchida , Toshio Kawagishi , Masaaki Tsukase , Kazuhiko Matsumoto
IPC分类号： G03C108
CPC分类号： G03C1/49827
摘要： A silver halide color photographic light-sensitive material containing a compound of the formula: wherein R1, R2 and R3 each represent a hydrogen atom or a substituent; R4 represents an alkyl, aryl or heterocyclic group; R1 and R2, or/and R2 and R4 may combine with each other to form a 5-membered, 6-membered or 7-membered ring; Z represents a group of non-metallic atoms that form a 5-membered, 6-membered or 7-membered ring together with the nitrogen atom and two carbon atoms in the benzene ring; R5 represents an alkyl, aryl or heterocyclic group, in which the compound of the formula contains none of a hydroxyl group, a carboxyl group and a sulfo group in each of R1, R2, R3 and R4.
摘要翻译：含有下式化合物的卤化银彩色摄影感光材料：其中R1，R2和R3各自表示氢原子或取代基; R4表示烷基，芳基或杂环基; R 1和R 2，或/和R 2和R 4可以彼此结合形成5元，6元或7元环; Z表示与苯环中的氮原子和两个碳原子一起形成5元，6元或7元环的一组非金属原子; R5表示烷基，芳基或杂环基，其中R1，R2，R3和R4各自不含羟基，羧基和磺基。

3. 发明授权

US06423484B1 Silver halide color photographic light-sensitive material 失效
标题翻译：卤化银彩色摄影感光材料
公开(公告)号：US06423484B1
公开(公告)日：2002-07-23
申请号：US09736391
申请日：2000-12-15
申请人： Yasuhiro Yoshioka , Takehiko Sato , Osamu Takahashi , Toshio Kawagishi , Kozo Sato , Yuki Mizukawa
发明人： Yasuhiro Yoshioka , Takehiko Sato , Osamu Takahashi , Toshio Kawagishi , Kozo Sato , Yuki Mizukawa
IPC分类号： G03C7305
CPC分类号： G03C7/396 , G03C7/301
摘要： There is disclosed a silver halide color photographic light-sensitive material which excels in a color reproduction and an image fastness and which has an excellent color developability. The above silver halide color photographic light-sensitive material comprises a support and provided thereon a yellow color-developing light-sensitive silver halide emulsion layer, a magenta color-developing light-sensitive silver halide emulsion layer and a cyan color-developing light-sensitive silver halide emulsion layer each having a different color-sensitivity, wherein the above magenta color-developing light-sensitive silver halide emulsion layer contains at least one of the non-diffusible dye-forming couplers represented by the following Formula (M), a high boiling organic solvent having a dielectric constant of 6.0 or less and a refraction index of 1.50 or less, and at least one of the water insoluble polymers which are obtained by polymerizing at least one of the monomers having an aromatic group: wherein R1 represents a hydrogen atom or a substituent; Z represents a non-metal atomic group which is necessary to form a 5-membered azole ring containing 2 to 4 nitrogen atoms and the above azole ring may contain a substituent (including a condensed ring); and X represents a hydrogen atom or a group capable of splitting off upon a coupling reaction with an oxidation product of a developing agent.
摘要翻译：公开了一种在色彩再现和图像牢度方面优异并且具有优异的显色性的卤化银彩色照相感光材料。上述卤化银彩色照相感光材料包括支持体，并在其上提供黄色显色感光卤化银乳剂层，品红色显色感光卤化银乳剂层和青色显色光敏感材料卤化银乳剂层各自具有不同的颜色敏感性，其中上述品红显色感光卤化银乳剂层含有由下式（M）表示的至少一种不扩散染料形成成色剂，高介电常数为6.0以下，折射率为1.50以下的沸点有机溶剂，以及至少一种通过聚合至少一种具有芳基的单体得到的水不溶性聚合物：其中R1表示氢原子或取代基; Z表示形成含有2〜4个氮原子的5元唑环所必需的非金属原子团，上述唑环可以含有取代基（包括稠环）。 X表示氢原子或与显影剂的氧化物进行偶联反应时能够分解的基团。

4. 发明授权

US06235457B1 Arylidene compound, azomethine compound and silver halide photographic material 失效
标题翻译：亚芳基化合物，偶氮甲碱化合物和卤化银照相材料
公开(公告)号：US06235457B1
公开(公告)日：2001-05-22
申请号：US09499371
申请日：2000-02-07
申请人： Keizo Kimura , Masashi Ogiyama , Yoshiharu Yabuki , Toshio Kawagishi , Takeshi Nakamine , Yuki Mizukawa
发明人： Keizo Kimura , Masashi Ogiyama , Yoshiharu Yabuki , Toshio Kawagishi , Takeshi Nakamine , Yuki Mizukawa
IPC分类号： G03C183
CPC分类号： G03C1/832 , C07D471/04 , C09B23/0091 , C09B23/02 , C09B23/06 , C09B23/08 , C09B55/009 , Y10S430/145
摘要： An arylidene compound is represented by the formula (I). Each of L1 and L2 independently is a divalent aliphatic group, a divalent aromatic group or a divalent heterocyclic group. L3 is trimethine, pentamethine or heptamethine. Y is ═O, ═S or ═N—R10. R1 is hydrogen, a halogen atom, cyano, nitro, an aliphatic group, an aromatic group, a heterocyclic group, —O—R11, —S—R12, —CO—O—R13, —O—CO—R14, —NR15R16, —CO—NR17R18, —SO2—R19 or —SO2—NR20R21. Each of R2, R3, R6 and R7 independently is hydrogen, a halogen atom, cyano, an aliphatic group, an aromatic group, —O—R22, —CO—R23, —CO—O—R24, —NR25R26, —NHCO—R27, —NH—CO—O—R28, —SO2—R29 or —NH—SO2—R30. Each of R4 and R5 independently is hydrogen, an aliphatic group, an aromatic group, —CO—R31 or —SO2—R32. An azomethine compound and silver halide photographic materials are also disclosed.
摘要翻译：亚芳基化合物由式（I）表示.L1和L2各自独立地为二价脂族基团，二价芳族基团或二价杂环基团。 L3是三甲基，五甲胺或七甲嘧啶。 Y是= O，= S或= N-R10。 R 1是氢，卤原子，氰基，硝基，脂族基，芳基，杂环基，-O-R 11，-S-R 12，-CO-O-R 13，-O-CO-R 14，-NR 15 R 16 ，-CO-NR 17 R 18，-SO 2 -R 19或-SO 2 -NR 20 R 21。 R2，R3，R6和R7各自独立地是氢，卤素原子，氰基，脂族基团，芳族基团，-O-R22，-CO-R23，-CO-O-R24，-NR25R26，-NHCO- R27，-NH-CO-O-R28，-SO2-R29或-NH-SO2-R30。 R 4和R 5各自独立地为氢，脂族基，芳基，-CO-R 31或-SO 2 -R 32。还公开了偶氮甲碱化合物和卤化银照相材料。

5. 发明申请

US20050210605A1 Method of effecting a reversible colour change of dyed hair 有权
标题翻译：染色头发的可逆变色的方法
公开(公告)号：US20050210605A1
公开(公告)日：2005-09-29
申请号：US10996376
申请日：2004-11-26
申请人： Dominic Pratt , Masayoshi Nojiri , Toshio Kawagishi
发明人： Dominic Pratt , Masayoshi Nojiri , Toshio Kawagishi
IPC分类号： A61K8/00 , A61K8/362 , A61K8/365 , A61K8/40 , A61K8/49 , A61Q5/10 , D06P1/04 , D06P1/653 , D06P1/673 , D06P3/30 , D06P5/04 , A61K7/13
CPC分类号： A61K8/4946 , A61K8/362 , A61K8/365 , A61K8/40 , A61K8/49 , A61K8/4926 , A61Q5/10
摘要： The present invention relates to a method to achieve a reversible change of the colour of hair dyed with an azo dye wherein the change of the colour can be effected by, for example, the salonist or the consumer in a simple manner. The colour of the hair thus dyed may be changed simply by treating the dyed hair with an acid treatment composition at any time after the first dyeing treatment. If desired by the consumer, the colour may be returned to substantially the original post dye colour by treating the hair further with an alkaline treatment composition.
摘要翻译：本发明涉及一种通过偶氮染料染色的毛发的颜色的可逆变化的方法，其中颜色的变化可以由例如沙龙或消费者以简单的方式进行。这样染色的毛发的颜色可以简单地通过在第一次染色处理之后的任何时间用酸处理组合物处理染色的毛发来改变。如果消费者需要，通过用碱处理组合物进一步处理毛发，可以将颜色返回到基本上原始的后染料颜色。

6. 发明授权

US6074810A Silver halide color light-sensitive material 失效
标题翻译：卤化银色感光材料
公开(公告)号：US6074810A
公开(公告)日：2000-06-13
申请号：US168171
申请日：1998-10-08
申请人： Toshio Kawagishi , Hideaki Naruse
发明人： Toshio Kawagishi , Hideaki Naruse
IPC分类号： G03C7/38 , G03C8/40 , G03C1/00 , G03C7/26 , G03C7/32
CPC分类号： G03C7/3825 , G03C8/408 , G03C7/383 , G03C7/3835
摘要： There is disclosed a silver halide color light-sensitive material, which comprises a coupler of the formula (1), (2), or (3) in at least one layer on a base: ##STR1## wherein R.sub.1 is a hydrogen atom, a halogen atom, or a substituent, R.sub.2 is a group of formula (4), R.sub.3 and R.sub.4 each are a hydrogen atom, a halogen atom, or a substituent, with the proviso that at least one of R.sub.3 and R.sub.4 is a group of the formula (4), R.sub.5 and R.sub.6 each are an alkyl group, an amino group, a carbonamido group, an alkoxycarbonylamino group, a sulfonamido group, and the like, R.sub.7 represents a group capable of substitution on a benzene ring; n is an integer of 0 to 3. This light-sensitive material can give a magenta image excellent in discrimination, and it is excellent in preservability before and after processing.
摘要翻译：公开了一种卤化银色感光材料，其在碱的至少一层中包含式（1），（2）或（3）的成色剂：其中R1是氢原子，卤素原子或取代基，R 2为式（4）的基团，R 3和R 4各自为氢原子，卤素原子或取代基，条件是R 3和R 4中的至少一个为式 4）中，R 5和R 6各自为烷基，氨基，碳酰氨基，烷氧基羰基氨基，亚磺酰氨基等，R 7表示可在苯环上取代的基团。 n为0〜3的整数。这种感光材料可以赋予鉴定性优异的品红色图像，加工前后的保存性优异。

7. 发明授权

US5985531A Silver halide color photographic light-sensitive material containing a development inhibitor releasing compound 失效
标题翻译：含有显影抑制剂释放化合物的卤化银彩色照相感光材料
公开(公告)号：US5985531A
公开(公告)日：1999-11-16
申请号：US887931
申请日：1997-07-03
申请人： Takeshi Nakamine , Hajime Nakagawa , Osamu Uchida , Hideaki Sato , Toshio Kawagishi
发明人： Takeshi Nakamine , Hajime Nakagawa , Osamu Uchida , Hideaki Sato , Toshio Kawagishi
IPC分类号： G03C7/00 , G03C7/305
CPC分类号： G03C7/30576 , G03C7/30552 , Y10S430/158
摘要： A silver halide color photographic light-sensitive material containing a compound represented by formula (I) belowformula (I)A--O--C(.dbd.O)--N(X.sub.1)--C(X.sub.2)(X.sub.3)--DIwherein A represents a coupler residue, X.sub.1 represents a heterocyclic group or a --C(X.sub.4)(X.sub.5)--Y group, Y represents an --SO.sub.2 R.sup.1, --SO.sub.2 NR.sup.1 R.sup.2, --CONR.sup.1 R.sup.2, --CO.sub.2 Z, --CN, --CF.sub.3, --CCl.sub.3, or --NO.sub.2 group, each of R.sup.1 and R.sup.2 independently represents a hydrogen atom or a substituted or nonsubstituted alkyl, cycloalkyl, alkenyl, aryl, or heterocyclic group, Z represents a hydrogen atom or a substituted or nonsubstituted cycloalkyl, alkenyl, aryl, or heterocyclic group, each of X.sub.2, X.sub.3, X.sub.4, and X.sub.5 represents a hydrogen atom or a substituent group, and DI represents a development inhibitor residue which is bonded by a hetero atom and released to form mercaptoazole.
摘要翻译：含有由式（I）表示的化合物（I）表示的化合物的卤化银彩色照相感光材料AOC（= O）-N（X1）-C（X2）（X3）-DI其中A表示成色剂残基X1 表示杂环基或-C（X 4）（X 5）-Y基，Y表示-SO 2 R 1，-SO 2 NR 1 R 2，-CONR 1 R 2，-CO 2 Z，-CN，-CF 3，-CCl 3或-NO 2基， R 2独立地表示氢原子或取代或未取代的烷基，环烷基，烯基，芳基或杂环基，Z表示氢原子或取代或未取代的环烷基，烯基，芳基或杂环基，X， X4和X5表示氢原子或取代基，DI表示通过杂原子键合并释放形成巯基唑的显影抑制剂残基。

8. 发明授权

US5605788A Silver halide color photographic material 失效
标题翻译：卤化银彩色照相材料
公开(公告)号：US5605788A
公开(公告)日：1997-02-25
申请号：US556141
申请日：1995-11-09
申请人： Toshio Kawagishi , Takeshi Nakamine , Masuji Motoki
发明人： Toshio Kawagishi , Takeshi Nakamine , Masuji Motoki
IPC分类号： G03C7/00 , C07D487/04 , G03C7/38
CPC分类号： C07D487/04 , G03C7/3835
摘要： A silver halide color photographic material containing a pyrazolotriazole coupler represented by the following formula (I) or (II): ##STR1## wherein R.sub.1 represents a hydrogen atom, a halogen atom, or a substituent; X represents a hydrogen atom, a halogen atom, or a group capable of being splitted off by the reaction with an oxidation product of a developing agent; L.sub.1 represents an (n+1)-valent linking group; L.sub.2 represents a group represented by the following formula (III); and n represents 1 or 2, and when n is 2, two L.sub.2 's may be the same or different;--[(A.sub.1).sub.a (B.sub.1).sub.b (A.sub.2).sub.c (B.sub.2).sub.d (A.sub.3).sub.e (B.sub.3).sub.f (A.sub.4).sub.g (B.sub.4).sub.h ](III)wherein A.sub.1, A.sub.2, A.sub.3 and A.sub.4 each represents --O--, --S--, --NR.sub.2 --, --N(R.sub.2)CO--, --CON(R.sub.2)--, --N(R.sub.2)SO.sub.2 --, --SO.sub.2 N(R.sub.2)--, --CO.sub.2 --, --OCO--, --N(R.sub.2)CON(R.sub.3)--, --OCON(R.sub.2)-- or --N(R.sub.2)CO.sub.2 --; R.sub.2 and R.sub.3 each represents a hydrogen atom, an alkyl group, an aryl group, an acyl group, an alkanesulfonyl group or an arenesulfonyl group; B.sub.1, B.sub.2 and B.sub.3 each represents an alkylene group or an arylene group; B.sub.4 represents an alkyl group or an aryl group; a, b, c, d, e, f and g each represents 0 or 1, and h represents 1, provided that a-b=0, c-d=0 and e-f=0; and at least one group represented by R.sub.2, R.sub.3, B.sub.1, B.sub.2, B.sub.3 and B.sub.4 in the substituents represented by L.sub.2 has a group represented by the following formula (IV):--A--NH--R.sub.4 (IV)wherein A represents --CO-- or --SO.sub.2 --; and R.sub.4 represents a hydrogen atom or an alkyl group.
摘要翻译：含有由下式（I）或（II）表示的吡唑并三唑成色剂的卤化银彩色照相材料：其中R 1表示氢原子，卤素原子或取代基; X表示氢原子，卤素原子或能够通过与显影剂的氧化产物反应而分裂的基团; L1表示（n + 1）价连接基团; L2表示由下式（III）表示的基团。 - （A1）a（B1）b（A2）c（B2）d（A3）e（B3）f（A4）其中n为1或2，当n为2时，两个L2可以相同或不同; ）g（B4）h]（III）其中A1，A2，A3和A4各自表示-O - ， - S - ， - NR2-，-N（R2）CO-，-CON（R2） - ， - N（ R2）SO2-，-SO2N（R2） - ，-COO2-，-OCO-，-N（R2）CON（R3） - ， - OCON（R2） - 或-N（R2）CO2-; R2和R3各自表示氢原子，烷基，芳基，酰基，链烷磺酰基或芳烃磺酰基; B1，B2和B3各自表示亚烷基或亚芳基; B4表示烷基或芳基; a，b，c，d，e，f和g各自表示0或1，h表示1，条件是a-b = 0，c-d = 0，e-f = 0; 在由L2表示的取代基中的R2，R3，B1，B2，B3和B4表示的至少一个基团具有下式（IV）表示的基团：-A-NH-R4（IV）其中A表示-CO - 或-SO 2 - ; R4表示氢原子或烷基。

9. 发明授权

US5538837A Silver halide color photographic light-sensitive material 失效
标题翻译：卤化银彩色摄影感光材料
公开(公告)号：US5538837A
公开(公告)日：1996-07-23
申请号：US323069
申请日：1994-10-14
申请人： Keiji Mihayashi , Seiji Ichijima , Toshio Kawagishi
发明人： Keiji Mihayashi , Seiji Ichijima , Toshio Kawagishi
IPC分类号： G03C7/305 , G03C7/407 , G03C7/44 , G03C1/46
CPC分类号： G03C7/30594 , Y10S430/158
摘要： A silver halide color photographic light-sensitive material which causes less fluctuation in the photographic processing activity of a processing solution in continuously processing the light-sensitive material and which has less unevenness in processing and excellent color reproducibility and sharpness. The silver halide color photographic light-sensitive material comprises a support, and provided thereon at least one red-sensitive emulsion layer, at least one green-sensitive emulsion layer, and at least one blue-sensitive emulsion layer, and containing a coupler represented by the following Formula (I) and a coupler represented by the following Formula (II):Formula (I)A.sub.1 -(TIME).sub.a -DIFormula (II)A.sub.2 -(TIME).sub.a -DIwherein A.sub.1 represents a group having an anti-diffusion group and releasing (TIME).sub.a -DI upon a reaction with an oxidation product of an aromatic primary amine developing agent; A.sub.2 represents a group having no anti-diffusion group and releasing (TIME).sub.a -DI upon a reaction with an oxidation product of an aromatic primary amine developing agent; TIME represents a timing group which splits from DI after separating from A; DI represents a development inhibitor which is substantially deactivated after eluting in a developing solution; and a represents 1 or 2, and when a is 2, the two TIME's are the same or different.
摘要翻译：一种卤化银彩色照相感光材料，其在连续处理感光材料中导致处理溶液的照相处理活性波动较小，并且处理不均匀性和优异的色彩再现性和清晰度。卤化银彩色照相感光材料包括载体，并在其上提供至少一种感红乳剂层，至少一种感绿乳剂层和至少一种感蓝乳剂层，并含有由下式（I）和由下式（II）表示的成色剂：式（I）A1-（时间）a-DIFormula（II）A2-（时间）a-DI其中A1表示具有抗扩散在与芳族伯胺显影剂的氧化产物反应的同时释放（TIME）a-DI; A2表示与芳族伯胺显影剂的氧化产物反应时没有抗扩散基团并释放（TIME）a-DI的基团; TIME表示从A分离后与DI分离的定时组; DI表示显影抑制剂，其在显影液中洗脱后基本上失活; a表示1或2，当a为2时，两个TIME相同或不同。

10. 发明授权

US5002860A Method for processing a silver halide color photographic material 失效
标题翻译：用于处理卤化银彩色照相材料的方法
公开(公告)号：US5002860A
公开(公告)日：1991-03-26
申请号：US313279
申请日：1989-02-21
申请人： Takatoshi Ishikawa , Toshio Kawagishi
发明人： Takatoshi Ishikawa , Toshio Kawagishi
IPC分类号： G03C7/38 , G03C7/42
CPC分类号： G03C7/42 , G03C7/3835
摘要： A novel process for processing a silver halide color photographic material is disclosed, which comprises color-developing a silver halide color photographic material which has been imagewise exposed to light, and then processing the silver halide color photographic material with a processing solution having a bleaching ability, wherein the silver halide color photographic material comprises at least one magenta coupler represented by formula (M-1) and the processing solution having a bleaching ability comprises as a bleaching agent (1) at least one of ferric complex salts of compounds selected from Compound Group (A) and (2) a ferric 1,3-diaminopropanetetraacetate complex salt in a molar proportion of the (1) to the (2) of 3 or less:Compound Group (A)A-1: Ethylenediaminetetraacetic acidA-2: Diethylenetriaminepentaacetic acidA-3: Cyclohexanediaminetetraacetic acidA-4: 1,2-Propylenediaminetetraacetic acid ##STR1## wherein Za and Zb each represents --CH.dbd., ##STR2## or .dbd.N--; R.sub.1 and R.sub.2 each represents a hydrogen atom or a substituent; and X represents a hydrogen atom or a group which is released upon a coupling reaction with an oxidation product of an aromatic primary amine developing agent, with the proviso that when Za.dbd.Zb is a carbon-carbon double bond, it is a portion of an aromatic ring.
摘要翻译：公开了一种用于处理卤化银彩色照相材料的新方法，其包括对成像曝光的卤化银彩色照相材料进行彩色显影，然后用具有漂白能力的处理溶液处理卤化银彩色照相材料，其中所述卤化银彩色照相材料包含至少一种由式（M-1）表示的品红成色剂，并且具有漂白能力的处理溶液包含漂白剂（1）至少一种选自化合物组分（A）和（2）以（1）〜（2）为3以下的摩尔比例的1,3-二氨基丙烷四乙酸铁配合物盐：化合物组（A）A-1：乙二胺四乙酸A-2 ：二亚乙基三胺五乙酸A-3：环己烷二胺四乙酸A-4：1,2-丙二胺四乙酸（M-1）其中Za和Zb各自表示-CH =，IMAGE或= N-; R1和R2各自表示氢原子或取代基; X表示氢原子或与芳族伯胺显影剂的氧化物进行偶联反应而释放的基团，条件是当Za = Zb为碳 - 碳双键时，其为芳香环。

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