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1. 发明申请

US20150225561A1 THERMOPLASTIC ELASTOMER COMPOSITION AND PROCESS TO PRODUCE SAME 审中-公开
标题翻译：热塑性弹性体组合物及其制备方法
公开(公告)号：US20150225561A1
公开(公告)日：2015-08-13
申请号：US14409012
申请日：2012-06-19
申请人： Yuichi Hara , Shun Sato , Edward John Blok , Maria D. Ellul , Anthony J. Dias , Randal Howard Kerstetter, III
发明人： Yuichi Hara , Shun Sato , Edward John Blok , Maria D. Ellul , Anthony J. Dias , Randal Howard Kerstetter, III
IPC分类号： C08L23/28
CPC分类号： C08L23/283 , C08K5/18 , C08L23/16 , C08L2201/08 , C08L2207/04 , C08L2312/00 , C08L77/00
摘要： Disclosed herein is a thermoplastic elastomer composition having improved uv and processability, comprising a post-vulcanized dynamically vulcanized alloy (DVA) and a low molecular weight aromatic amine stabilizer, wherein the DVA comprises an isobutylene elastomeric component dispersed as a domain in a continuous phase comprising at least one thermoplastic resin. A method to produce the thermoplastic elastomer composition is also disclosed.
摘要翻译：本文公开了具有改进的紫外线和加工性的热塑性弹性体组合物，其包含后硫化动态硫化合金（DVA）和低分子量芳族胺稳定剂，其中所述DVA包含分散在连续相中的结构域的异丁烯弹性体组分，至少一种热塑性树脂。还公开了一种制备热塑性弹性体组合物的方法。

2. 发明授权

US08247494B2 Thermoset compositions with dispersed thermoplastic resin therein and process for making them 有权
标题翻译：具有分散的热塑性树脂的热固性组合物及其制备方法
公开(公告)号：US08247494B2
公开(公告)日：2012-08-21
申请号：US12941753
申请日：2010-11-08
申请人： Edward J. Blok , Maria D. Ellul , Sunny Jacob , Alfred V. Pickett
发明人： Edward J. Blok , Maria D. Ellul , Sunny Jacob , Alfred V. Pickett
IPC分类号： C08F8/00 , C08L9/00 , C08L23/10 , C08L45/00
CPC分类号： C08L23/16 , C08L23/10 , C08L2312/08 , C08L2666/06
摘要： A rubber composition comprising: a cured rubber; and thermoplastic resin, where the thermoplastic resin is in the form of discrete domains dispersed within a continuous phase of the cured rubber, and where the cured rubber includes silicon-containing crosslinks.
摘要翻译：一种橡胶组合物，其包含：固化橡胶; 和热塑性树脂，其中热塑性树脂是分散在固化橡胶的连续相中的离散区域形式，其中固化的橡胶包括含硅交联。

3. 发明申请

US20110054093A1 Elastomeric Compositions and Their Use in Articles 有权
标题翻译：弹性组合及其在文章中的应用
公开(公告)号：US20110054093A1
公开(公告)日：2011-03-03
申请号：US12548797
申请日：2009-08-27
申请人： Maria D. Ellul , Anthony Jay Dias , Rodney May
发明人： Maria D. Ellul , Anthony Jay Dias , Rodney May
IPC分类号： C08L23/00 , C08K5/17 , C08K5/10 , C08K5/435
CPC分类号： C08L23/283 , B60C1/00 , C08K3/34 , C08K5/0016 , C08L23/02 , C08L23/0869 , C08L23/22 , C08L77/00 , C08L79/08 , C08L2205/08 , C08L2666/02
摘要： A dynamically vulcanized alloy contains at least one isobutylene-containing elastomer and at least one thermoplastic resin, wherein the elastomer is present as a dispersed phase of small vulcanized or partially vulcanized particles in a continuous phase of the thermoplastic resin. The dynamically vulcanized alloy also contains an anhydride functionalized oligomer. The alloy maintains a high Shore A hardness value while obtaining improved flowability for processing.
摘要翻译：动态硫化合金含有至少一种含异丁烯的弹性体和至少一种热塑性树脂，其中弹性体以热塑性树脂的连续相中的小硫化或部分硫化的颗粒的分散相存在。动态硫化合金还含有酸酐官能化的低聚物。该合金保持高的肖氏A硬度值，同时获得改进的流动性用于加工。

4. 发明授权

US07812093B2 Peroxide-cured thermoplastic vulcanizates and medical devices made therewith 有权
标题翻译：过氧化物固化的热塑性硫化橡胶和由其制成的医疗器械
公开(公告)号：US07812093B2
公开(公告)日：2010-10-12
申请号：US11311491
申请日：2005-12-19
申请人： Maria D. Ellul , John D. Gorsuch
发明人： Maria D. Ellul , John D. Gorsuch
IPC分类号： C08F8/00 , C08L9/00 , C08L23/00 , C08L33/14 , C08L45/00
CPC分类号： C08L23/16 , C08L23/10 , C08L2666/06
摘要： A method of preparing a thermoplastic vulcanizate, the method comprising dynamically vulcanizing a rubber within a blend with a thermoplastic resin, where the dynamic vulcanization is effected with a cure system that includes a free-radical cure agent and triallyl isocyanurate.
摘要翻译：一种制备热塑性硫化橡胶的方法，所述方法包括用热塑性树脂动态硫化共混物内的橡胶，其中动态硫化用包括自由基固化剂和三烯丙基异氰脲酸酯的固化体系进行。

5. 发明授权

US06630538B1 Polypropylene thermoplastic elastomer compositions having improved processing properties and physical property balance 有权
标题翻译：具有改进的加工性能和物理性能平衡的聚丙烯热塑性弹性体组合物
公开(公告)号：US06630538B1
公开(公告)日：2003-10-07
申请号：US09674654
申请日：2001-08-31
申请人： Maria D. Ellul , Prasadarao Meka , Kang-Bo Wang , Yu-Feng Wang
发明人： Maria D. Ellul , Prasadarao Meka , Kang-Bo Wang , Yu-Feng Wang
IPC分类号： C08L2316
CPC分类号： C08L23/10 , C08L21/00 , C08L23/16 , C08L2666/04
摘要： Thermoplastic elastomer compositions having improved processabillity while maintaining good physical properties are prepared from a mixture of olefinic rubber and a polypropylene composition having a melt flow rate in the range of from about 0.5 to about 5 dg/min. and a molecular weight distribution Mw/Mn of greater than 5.5 up to about 20. The rubber component of the mixture may be at least partially cured by dynamic vulcanization.
摘要翻译：熔体流动速率在约0.5至约5dg / min范围内由烯烃橡胶和聚丙烯组合物的混合物制备而具有改进的加工性，同时保持良好的物理性质的热塑性弹性体组合物。并且分子量分布Mw / Mn大于5.5至约20.混合物的橡胶组分可以通过动态硫化至少部分固化。

6. 发明授权

US06433090B1 Thermoplastic elastomers having improved set foams made therefrom 有权
标题翻译：热塑性弹性体具有改进的固定泡沫
公开(公告)号：US06433090B1
公开(公告)日：2002-08-13
申请号：US09771044
申请日：2001-01-26
申请人： Maria D. Ellul , Abdelhadi Sahnoune
发明人： Maria D. Ellul , Abdelhadi Sahnoune
IPC分类号： C08L2300
CPC分类号： C08L23/16 , C08L21/00 , C08L2203/14 , C08L2207/04 , C08L2314/06 , C08L2666/04
摘要： A thermoplastic vulcanizate prepared by a process comprising the steps of dynamically vulcanizing a vulcanizable rubber within a mixture that includes from about 15 to about 90 percent by weight of the rubber and from about 10 to about 85 percent by weight of a long-chain branched thermoplastic resin, where the long-chain branched thermoplastic resin is (i) an &agr;-olefin polymer, (ii) a copolymer of an &agr;-olefin and an &agr;-&ohgr;-olefin diene, or (iii) a mixture thereof, where the long-chain branched thermoplastic resin is characterized by a weight average molecular weight from about 100,000 to about 600,000, a number average molecular weight from about 40,000 to about 200,000, a z-average molecular weight from about 400,000 to about 2,000,000, a vis from about 0.2 to about 0.95, and a melt flow rate from about 0.3 to about 30 dg/min.
摘要翻译：一种热塑性硫化橡胶，其制备方法包括以下步骤：在混合物中动态硫化可硫化的橡胶，其包括约15至约90重量％的橡胶和约10至约85重量％的长链支化热塑性塑料树脂，其中长支链热塑性树脂是（i）α-烯烃聚合物，（ii）α-烯烃和α-ω-烯烃二烯的共聚物，或（iii）它们的混合物，其中长链链支化热塑性树脂的特征在于重均分子量为约100,000至约600,000，数均分子量为约40,000至约200,000，z平均分子量为约400,000至约2,000,000，a

7. 发明授权

US06399710B1 Modification of thermolastic vulcanizates with a thermoplastic random copolymer of ethylene 有权
标题翻译：用乙烯热塑性无规共聚物改性热弹性硫化胶
公开(公告)号：US06399710B1
公开(公告)日：2002-06-04
申请号：US09554796
申请日：2000-07-03
申请人： Terry M. Finerman , Maria D. Ellul , Sabet Abdou-Sabet
发明人： Terry M. Finerman , Maria D. Ellul , Sabet Abdou-Sabet
IPC分类号： C08L2302
CPC分类号： C08L23/10 , C08L23/0815 , C08L2314/06 , C08L2666/04
摘要： Random thermoplastic ethylene copolymers can be used to increase the elongation to break and toughness of thermoplastic vulcanizates. Polypropylene is a preferred thermoplastic phase. The rubber can be olefinic rubbers. Random thermoplastic ethylene copolymers are different from Ziegler-Natta ethylene copolymers as the compositional heterogeneity of the copolymer is greater with Ziegler-Natta copolymers. This difference results in substantial differences in properties (elongation to break and toughness) between thermoplastic vulcanizates modified with random thermoplastic ethylene and those modified with Ziegler-Natta ethylene copolymers. An increase in elongation to break results in greater extensibility in the articles made from a thermoplastic vulcanizate.
摘要翻译：随机热塑性乙烯共聚物可用于增加热塑性硫化橡胶的断裂伸长率和韧性。聚丙烯是优选的热塑性相。橡胶可以是烯烃橡胶。无规热塑性乙烯共聚物不同于齐格勒 - 纳塔乙烯共聚物，因为齐格勒 - 纳塔共聚物，共聚物的组成异质性更大。该差异导致用随机热塑性乙烯改性的热塑性硫化橡胶和用齐格勒 - 纳塔乙烯共聚物改性的热塑性硫化橡胶之间的性能（断裂伸长率和韧性）的实质差异。增加断裂伸长率导致由热塑性硫化橡胶制成的制品更大的延展性。

8. 发明授权

US5126501A Elastomeric compositions and tire belt structure 失效
标题翻译：弹性组合物和轮胎带结构
公开(公告)号：US5126501A
公开(公告)日：1992-06-30
申请号：US644523
申请日：1991-01-23
申请人： Maria D. Ellul
发明人： Maria D. Ellul
IPC分类号： B60C9/20 , C08K5/09
CPC分类号： C08K5/09 , B60C9/2006 , Y10T152/1081
摘要： An improved composition for steel cord reinforced tire belts and tire belts as well as other products made from such composition are provided. The composition includes natural or butadiene rubber or mixtures thereof. A sulfur producing curing agent is present. The composition also includes both carbon black and silica as well as up to about 12 phr of zinc dimethacrylate or other metal salt of a low molecular weight organic acid. A silane may also be present.
摘要翻译：提供了一种用于钢帘线增强轮胎带和轮胎带的改进的组合物以及由这种组合物制成的其它产品。该组合物包括天然或丁二烯橡胶或其混合物。存在硫磺固化剂。该组合物还包括炭黑和二氧化硅以及最多约12phr的二甲基丙烯酸锌或其它低分子量有机酸的金属盐。也可以存在硅烷。

9. 发明授权

US08962762B2 Thermoplastic polymer compositions, methods for making the same, and articles made therefrom 有权
标题翻译：热塑性聚合物组合物，其制造方法和由其制成的制品
公开(公告)号：US08962762B2
公开(公告)日：2015-02-24
申请号：US12598549
申请日：2008-04-14
申请人： Periagaram S. Ravishankar , Maria D. Ellul
发明人： Periagaram S. Ravishankar , Maria D. Ellul
IPC分类号： C08L23/14 , C08L23/10 , C08F210/06 , C08L23/12 , C08L23/16
CPC分类号： C08L23/10 , C08F210/06 , C08L23/12 , C08L23/142 , C08L23/16 , C08L2205/02 , C08L2666/06 , C08L2666/08 , C08F210/16 , C08F2500/20
摘要： Provided are thermoplastic polymer compositions having a single melting point, articles made therefrom, and methods for elevating the melting point of low melting point polymers. Thermoplastic polymer compositions are composed of one or more high melting point polyolefins and a thermoplastic component that includes a low melting point polypropylene. High melting point polyolefins are composed of a stereoregular polypropylene having a tacticity similar to the low melting point polypropylene. The low melting point polypropylene includes, for example, propylene homopolymers and copolymers composed of propylene and one or more comonomers. Thermoplastic polymer compositions may also optionally contain any of the various additives commonly used in such polymer compositions, such as for example oils, etc. In one embodiment, thermoplastic polymer compositions are thermoplastic elastomer compositions that include an elastomeric component composed of an elastomer or rubber. The elastomeric component may be substantially or partially crosslinked to form a thermoplastic vulcanizate.
摘要翻译：提供具有单一熔点的热塑性聚合物组合物，由其制成的制品，以及用于提高低熔点聚合物熔点的方法。热塑性聚合物组合物由一种或多种高熔点聚烯烃和包含低熔点聚丙烯的热塑性组分组成。高熔点聚烯烃由具有类似于低熔点聚丙烯的立构规整度的立体规则聚丙烯构成。低熔点聚丙烯包括例如由丙烯和一种或多种共聚单体组成的丙烯均聚物和共聚物。热塑性聚合物组合物还可任选地含有通常用于这种聚合物组合物，例如油等中的任何各种添加剂。在一个实施方案中，热塑性聚合物组合物是热塑性弹性体组合物，其包括由弹性体或橡胶组成的弹性体组分。弹性体组分可以基本上或部分地交联以形成热塑性硫化橡胶。

10. 发明授权

US08178625B2 Thermoplastic vulcanizate composition 有权
标题翻译：热塑性硫化胶组合物
公开(公告)号：US08178625B2
公开(公告)日：2012-05-15
申请号：US11497091
申请日：2006-08-01
申请人： Maria D. Ellul , Periagaram S. Ravishankar , Jianya Cheng , Paul E. McDaniel
发明人： Maria D. Ellul , Periagaram S. Ravishankar , Jianya Cheng , Paul E. McDaniel
IPC分类号： C08L23/16 , C08L23/12
CPC分类号： C08L47/00 , C08F210/18 , C08L23/10 , C08L23/12 , C08L23/14 , C08L23/16 , C08L2205/02 , C08F4/68 , C08F2/001 , C08L2666/06 , C08F210/06 , C08F236/00 , C08F2500/25 , C08F2500/17 , C08F2500/12 , C08F2500/03 , C08F2500/11
摘要： The instant disclosure is directed to a thermoplastic vulcanizate composition comprising a dynamically-cured rubber; from about 20 to about 300 parts by weight of a thermoplastic resin per 100 parts by weight rubber and from about 30 to about 250 parts by weight additional oil per 100 parts by weight rubber; wherein the rubber comprises a multimodal polymer composition cured with a curing agent, the multimodal polymer composition comprising 45 to 75 wt % of a first polymer fraction and 25 to 55 wt % of a second polymer fraction, each comprising ethylene, a C3-C10 alpha-olefin, and a non-conjugated diene, wherein the polymer fractions have been polymerized using a Ziegler-Natta catalyst system, wherein the first polymer fraction has a Mooney viscosity of greater than or equal to about 150 ML(1+4@125° C.), and the second polymer fraction has a Mooney viscosity of about 20 ML to about 120 ML; and about 10 phr to about 50 phr of an extender oil. A method of producing the thermoplastic vulcanizate is also disclosed.
摘要翻译：本公开涉及包含动态固化橡胶的热塑性硫化橡胶组合物; 每100重量份橡胶约20-300重量份热塑性树脂和每100重量份橡胶约30至约250重量份附加油; 其中所述橡胶包含用固化剂固化的多峰聚合物组合物，所述多峰聚合物组合物包含45至75重量％的第一聚合物部分和25至55重量％的第二聚合物部分，每个包含乙烯，C 3 -C 10α- α-烯烃和非共轭二烯，其中聚合物部分已经使用齐格勒 - 纳塔催化剂体系聚合，其中第一聚合物部分的门尼粘度大于或等于约150ML（1 + 4 @ 125° C），并且第二聚合物级分的门尼粘度为约20ML至约120ML; 和约10phr至约50phr的增量油。还公开了一种生产热塑性硫化橡胶的方法。

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