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1. 发明授权

US08143423B2 N-heterocyclic carbene (NHC) catalyzed synthesis of hydroxamic acids 失效
标题翻译： N-杂环卡宾（NHC）催化合成异羟肟酸
公开(公告)号：US08143423B2
公开(公告)日：2012-03-27
申请号：US12532613
申请日：2008-03-20
申请人： Yugen Zhang , Jackie Y. Ying , Jayasree Seayad , Fong Tian Wong , Pranab K. Patra
发明人： Yugen Zhang , Jackie Y. Ying , Jayasree Seayad , Fong Tian Wong , Pranab K. Patra
IPC分类号： C07C259/10 , C07C259/06 , C07C259/04 , C07C259/08 , C07D233/90
CPC分类号： C07B43/00 , C07B53/00 , C07C259/06
摘要： A process for preparing hydroxamic acids is provided. The process comprises reacting an aldehyde with a nitroso compound in the presence of a N-heterocyclic carbene (NHC) catalyst.
摘要翻译：提供了制备异羟肟酸的方法。该方法包括在N-杂环卡宾（NHC）催化剂存在下使醛与亚硝基化合物反应。

2. 发明授权

US08071783B2 N-heterocyclic carbene catalyzed synthesis of N-phenylisoxazolidin-5-one derivative and synthesis of β-amino acid ester derivative 有权
标题翻译： N-杂环卡宾催化合成N-苯基异恶唑烷-5-酮衍生物和合成β-氨基酸酯衍生物
公开(公告)号：US08071783B2
公开(公告)日：2011-12-06
申请号：US12531678
申请日：2008-03-14
申请人： Yugen Zhang , Jackie Y. Ying , Jayasree Seayad , Pranab K. Patra
发明人： Yugen Zhang , Jackie Y. Ying , Jayasree Seayad , Pranab K. Patra
IPC分类号： C07D261/04 , C07C229/00
CPC分类号： C07C227/18 , C07D261/04 , C07C229/18
摘要： A process for preparing a N-phenylisoxazolidin-5-one derivative is provided. The process for preparing the N-phenylisoxazolidin-5-one derivative comprises reacting an α,β-unsaturated aldehyde with nitrosobenzene in the presence of a N-heterocyclic carbene (NHC) catalyst. A process for preparing an N-alkoxyphenyl protected β-amino acid ester derivative is further provided. The process for preparing the N-alkoxyphenyl protected β-amino acid ester derivative comprises reacting an α,β-unsaturated aldehyde with nitrosobenzene in the presence of a N-heterocyclic carbene (NHC) catalyst to form a N-phenylisoxazolidin-5-one derivative, and then treating the N-phenylisoxazolidin-5-one derivative with an alcohol in the presence of an acid catalyst. A process for preparing an N-alkoxyphenyl protected β-amino acid ester derivative, comprising treating a N-phenylisoxazolidin-5-one derivative with an alcohol in the presence of an acid catalyst, is also provided.
摘要翻译：提供了制备N-苯基异恶唑烷-5-酮衍生物的方法。制备N-苯基异恶唑烷-5-酮衍生物的方法包括在N-杂环卡宾（NHC）催化剂存在下，使α和bgr-不饱和醛与亚硝基苯反应。还提供了制备N-烷氧基苯基保护的α-氨基酸酯衍生物的方法。制备N-烷氧基苯基保护的α-氨基酸酯衍生物的方法包括在N-杂环卡宾（NHC）催化剂存在下使α和β-不饱和醛与亚硝基苯反应，形成N-苯基异恶唑烷-5- 一种衍生物，然后在酸催化剂存在下用醇处理N-苯基异恶唑烷-5-酮衍生物。还提供了一种制备N-烷氧基苯基保护的氨基酸酯衍生物的方法，其包括在酸催化剂存在下用醇处理N-苯基异恶唑烷-5-酮衍生物。

3. 发明申请

US20110112310A1 AZIRIDINE SYNTHESIS 审中-公开
标题翻译： AZIRIDINE合成
公开(公告)号：US20110112310A1
公开(公告)日：2011-05-12
申请号：US12865707
申请日：2009-01-30
申请人： Pranab K. Patra , Jayasree Seayad , Yugen Zhang , Jackie Y. Ying
发明人： Pranab K. Patra , Jayasree Seayad , Yugen Zhang , Jackie Y. Ying
IPC分类号： C07D203/14
CPC分类号： C07D203/02 , C07D203/14
摘要： The invention relates to a process for making an aziridine. wherein an aldehyde, a nitroso compound and a Michael acceptor are reacted in the presence of an N-heterocyclic carbene (NHC) catalyst.
摘要翻译：本发明涉及制备氮丙啶的方法。其中醛，亚硝基化合物和迈克尔受体在N-杂环卡宾（NHC）催化剂的存在下反应。

4. 发明申请

US20100210744A1 Mesoporous Polymer Colloids 有权
标题翻译：介孔聚合物胶体
公开(公告)号：US20100210744A1
公开(公告)日：2010-08-19
申请号：US12530450
申请日：2007-03-08
申请人： Yugen Zhang , Jackie Y. Ying , Pranab K. Patra
发明人： Yugen Zhang , Jackie Y. Ying , Pranab K. Patra
IPC分类号： C08J9/42
CPC分类号： B01J31/1625 , B01J20/265 , B01J20/267 , B01J20/28057 , B01J20/28071 , B01J20/28073 , B01J20/28083 , B01J20/28092 , B01J20/285 , B01J21/08 , B01J31/0234 , B01J31/0237 , B01J31/0244 , B01J31/063 , B01J31/067 , B01J31/1658 , B01J37/0018 , B01J2231/32 , C08F212/08 , C08J9/26 , C08J2201/024 , C08J2201/0442 , C08J2205/048 , C08J2325/04 , Y02P20/588 , C08F212/36
摘要： The invention provides a particulate material comprising porous polymeric microparticles having a mesoporous structure. A process for making the particles is also presented. The process comprises impregnating a porous microparticulate template material with a liquid comprising one or more monomers. The one or more monomers are then polymerised in and/or on the template material to form a polymer, and the template material is then removed to produce the particulate material.
摘要翻译：本发明提供包含具有中孔结构的多孔聚合物微粒的颗粒材料。还提出了制备颗粒的方法。该方法包括用包含一种或多种单体的液体浸渍多孔微粒模板材料。然后将一种或多种单体在模板材料中和/或模板材料上聚合以形成聚合物，然后除去模板材料以产生颗粒材料。

5. 发明申请

US20090227740A1 Polymeric Salts and Poly-NHC-Metal Complexes 有权
标题翻译：聚合盐和聚NHC-金属络合物
公开(公告)号：US20090227740A1
公开(公告)日：2009-09-10
申请号：US12295716
申请日：2006-07-05
申请人： Jackie Y. Ying , Yugen Zhang , Dingyu Hu , Pranab K. Patra
发明人： Jackie Y. Ying , Yugen Zhang , Dingyu Hu , Pranab K. Patra
IPC分类号： C08F226/06
CPC分类号： C08G73/0611 , B01J31/1691 , B01J31/2273 , B01J2231/4211 , B01J2531/0244 , B01J2531/17 , B01J2531/824 , C08G61/123 , C08G61/124 , C08G83/00
摘要： The invention provides a polymeric salt, wherein the monomer unit of the polymeric salt comprises two nitrogen containing heterocyclic groups joined by a rigid linker group. The nitrogen atoms of the heterocyclic groups are disposed so as to enable a polymeric carbene formed by from the polymeric salt to complex with a metal atom. The invention also provides a polymeric metal complex which may be made from the polymeric salt, and which may be used in a Suzuki coupling reaction. The polymeric salt may be used as a heterogeneous organic catalyst for cyanation reaction.
摘要翻译：本发明提供一种聚合物盐，其中聚合物盐的单体单元包含两个通过刚性连接基团连接的含氮杂环基团。这些杂环基的氮原子被设置成能够使由聚合物盐形成的聚合卡宾与金属原子复合。本发明还提供了可以由聚合物盐制成并可用于Suzuki偶联反应的聚合物金属络合物。聚合盐可用作用于氰化反应的非均相有机催化剂。

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