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    • 1. 发明授权
    • Additive for non-aqueous electrolyte and secondary battery using the same
    • 用于非水电解质和二次电池的添加剂
    • US07914707B2
    • 2011-03-29
    • US12649100
    • 2009-12-29
    • Yu Sin KimHyeong Jin KimHye Yun ChaHo Chun Lee
    • Yu Sin KimHyeong Jin KimHye Yun ChaHo Chun Lee
    • H01B1/12C07C255/46
    • H01M10/0567H01M10/052H01M10/0569H01M10/4235
    • Disclosed is a compound represented by the following formula 1: wherein, each of R1˜R13 independently represents —H, —F, —Cl, —Br, —I, —OH, —SH, —COOH, —PO3H2, —NH2, —NO2, —O(CH2CH2O)nH (wherein, n is an integer of 1˜5), C1˜C12 alkyl group, C1˜C12 aminoalkyl group, C1˜C12 hydroxyalkyl group, C1˜C12 haloalkyl group, C2˜C12 alkenyl group, C1˜C12 alkoxy group, C1˜C12 alkylamino group, C1˜C12 dialkylamino group, C6˜C18 aryl group, C6˜C18 aminoaryl group, C6˜C18 hydroxyaryl group, C6˜C18 haloaryl group, C7˜C18 benzyl group, C7˜C18 aminobenzyl group, C7˜C18 hydroxybenzyl group, C7˜C18 halobenzyl group, or nitrile group (—CN); and at least one of R4˜R13 is nitrile group (—CN). A non-aqueous electrolyte comprising: (i) a lithium salt, (ii) a solvent, and (iii) a compound represented by formula 1; and a secondary battery comprising the non-aqueous electrolyte are also disclosed. When the compound represented by formula 1 is added to a non-aqueous electrolyte, it is possible to improve the safety of a secondary battery in an overcharged state.
    • 公开了由下式1表示的化合物:其中,R 1〜R 13各自独立地表示-H,-F,-Cl,-Br,-I,-OH,-SH,-COOH,-PO 3 H 2,-NH 2, -NO 2,-O(CH 2 CH 2 O)n H(其中n为1〜5的整数),C 1〜C 12烷基,C 1〜C 12氨基烷基,C 1〜C 12羟烷基,C 1〜C 12卤代烷基,C 2〜C 12烯基 基团,C 1〜C 12烷氧基,C 1〜C 12烷基氨基,C 1〜C 12二烷基氨基,C 6〜C 18芳基,C 6〜C 18氨基芳基,C 6〜C 18羟基芳基,C 6〜C 18卤代芳基,C 7〜C 18苄基, C 7〜C 18氨基苄基,C 7〜C 18羟基苄基,C 7〜C 18卤代苄基或腈基(-CN); 并且R 4〜R 13中的至少一个为腈基(-CN)。 一种非水电解质,其包含:(i)锂盐,(ii)溶剂,和(iii)由式1表示的化合物; 还公开了包含非水电解质的二次电池。 当将由式1表示的化合物加入到非水电解质中时,可以提高过充电状态的二次电池的安全性。
    • 2. 发明授权
    • Additive for non-aqueous electrolyte and secondary battery using the same
    • 用于非水电解质和二次电池的添加剂
    • US07666330B2
    • 2010-02-23
    • US11406640
    • 2006-04-19
    • Yu Sin KimHyeong Jin KimHye Yun ChaHo Chun Lee
    • Yu Sin KimHyeong Jin KimHye Yun ChaHo Chun Lee
    • H01B1/20H01B1/12
    • H01M10/0567H01M10/052H01M10/0569H01M10/4235
    • Disclosed is a compound represented by the following formula 1: wherein, each of R1˜R13 independently represents —H, —F, —Cl, —Br, —I, —OH, —SH, —COOH, —PO3H2, —NH2, —NO2, —O(CH2CH2O)nH (wherein, n is an integer of 1˜5), C1˜C12 alkyl group, C1˜C12 aminoalkyl group, C1˜C12 hydroxyalkyl group, C1˜C12 haloalkyl group, C2˜C12 alkenyl group, C1˜C12 alkoxy group, C1˜C12 alkylamino group, C1˜C12 dialkylamino group, C6˜C18 aryl group, C6˜C18 aminoaryl group, C6˜C18 hydroxyaryl group, C6˜C18 haloaryl group, C7˜C18 benzyl group, C7˜C18 aminobenzyl group, C7˜C18 hydroxybenzyl group, C7˜C18 halobenzyl group, or nitrile group (—CN); and at least one of R4˜R13 is nitrile group (—CN). A non-aqueous electrolyte comprising: (i) a lithium salt, (ii) a solvent, and (iii) a compound represented by formula 1; and a secondary battery comprising the non-aqueous electrolyte are also disclosed. When the compound represented by formula 1 is added to a non-aqueous electrolyte, it is possible to improve the safety of a secondary battery in an overcharged state.
    • 公开了由下式1表示的化合物:其中,R 1〜R 13各自独立地表示-H,-F,-Cl,-Br,-I,-OH,-SH,-COOH,-PO 3 H 2,-NH 2, -NO 2,-O(CH 2 CH 2 O)n H(其中n为1〜5的整数),C 1〜C 12烷基,C 1〜C 12氨基烷基,C 1〜C 12羟烷基,C 1〜C 12卤代烷基,C 2〜C 12烯基 基团,C 1〜C 12烷氧基,C 1〜C 12烷基氨基,C 1〜C 12二烷基氨基,C 6〜C 18芳基,C 6〜C 18氨基芳基,C 6〜C 18羟基芳基,C 6〜C 18卤代芳基,C 7〜C 18苄基, C 7〜C 18氨基苄基,C 7〜C 18羟基苄基,C 7〜C 18卤代苄基或腈基(-CN); 并且R 4〜R 13中的至少一个为腈基(-CN)。 一种非水电解质,其包含:(i)锂盐,(ii)溶剂,和(iii)由式1表示的化合物; 还公开了包含非水电解质的二次电池。 当将由式1表示的化合物加入到非水电解质中时,可以提高过充电状态的二次电池的安全性。