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1. 发明授权

US07214251B2 Compact steam reformer 有权
标题翻译：紧凑型蒸汽重整器
公开(公告)号：US07214251B2
公开(公告)日：2007-05-08
申请号：US10128735
申请日：2002-04-23
申请人： Young-Sam Oh , Young-Soon Baek , Won-Ihl Cho , Taek-Yong Song , Jeong-Hwan Lee , Sang-Eon Park , Ki-Won Jun , Ri-Sang Choi
发明人： Young-Sam Oh , Young-Soon Baek , Won-Ihl Cho , Taek-Yong Song , Jeong-Hwan Lee , Sang-Eon Park , Ki-Won Jun , Ri-Sang Choi
IPC分类号： B01J8/00 , B01J8/04
CPC分类号： C01B3/48 , B01B1/005 , B01J8/009 , B01J8/0469 , B01J8/0492 , B01J8/0496 , B01J2208/00203 , B01J2208/00309 , B01J2208/00504 , B01J2208/0053 , B01J2208/00849 , B01J2219/185 , B01J2219/1943 , C01B3/384 , C01B2203/0233 , C01B2203/0288 , C01B2203/043 , C01B2203/0811 , C01B2203/1276 , C01B2203/82 , C01B2203/84 , Y02P20/124 , Y02P20/52
摘要： The compact steam reformer of the present invention integrally comprises a housing; a reforming reactor having an upper mixing compartment for mixing natural gas and steam and a lower compartment for accommodating a catalyst bed; a natural gas feeding coiled pipe through which natural gas is introduced while being heated; a steam generating coiled pipe in which pure water is converted to steam by the exhaust; a metal fiber burner for heating the reforming reactor; a high-temperature converter for primarily removing carbon monoxide from a synthetic gas; a low-temperature converter for secondarily reducing the carbon monoxide level of the synthetic gas; and a heat exchanger, provided between the high-temperature converter and the low-temperature converter, for cooling the gas effluent from the high-temperature converter.
摘要翻译：本发明的紧凑型蒸汽重整器整体地包括壳体; 具有用于混合天然气和蒸汽的上部混合室和用于容纳催化剂床的下部隔室的重整反应器; 天然气供给盘管，加热时引入天然气; 蒸汽发生盘管，其中纯水由废气转化成蒸汽; 用于加热重整反应器的金属纤维燃烧器; 用于主要从合成气中除去一氧化碳的高温转化器; 用于二次还原合成气体的一氧化碳水平的低温转化器; 以及设置在高温转换器和低温转换器之间的用于冷却来自高温转换器的气体流出物的热交换器。

2. 发明授权

US07232553B2 Plate type steam reformer 有权
标题翻译：板式蒸汽重整器
公开(公告)号：US07232553B2
公开(公告)日：2007-06-19
申请号：US10136287
申请日：2002-05-02
申请人： Young-Sam Oh , Young-Soon Baek , Taek-Yong Song , Sang-Eon Park , Ki-Won Jun , Ri-Sang Choi
发明人： Young-Sam Oh , Young-Soon Baek , Taek-Yong Song , Sang-Eon Park , Ki-Won Jun , Ri-Sang Choi
IPC分类号： B01J8/04 , B01J10/00 , B01J19/00 , B01J7/00 , C10J3/84
CPC分类号： C01B3/384 , B01J19/249 , B01J2219/00157 , B01J2219/2453 , B01J2219/2458 , B01J2219/2465 , B01J2219/2466 , B01J2219/2467 , B01J2219/2474 , C01B3/48 , C01B2203/00 , C01B2203/0233 , C01B2203/0288 , C01B2203/044 , C01B2203/047 , C01B2203/048 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/0883 , C01B2203/1241 , C01B2203/127 , C01B2203/1288 , C01B2203/16 , C01B2203/1614 , C01B2203/82 , H01M8/0612 , H01M8/0668 , H01M8/0675 , Y02P20/128
摘要： Disclosed is a plate type steam reformer comprising a plate type burner capable of heating a broad area of a reactor as a heat source, positioned on a bottom of the reformer; a reforming reactor requiring a relatively high temperature, positioned over the burner; a high temperature water gas shift reactor requiring a relatively moderate temperature, positioned over the reforming reactor; a low temperature water gas shift reactor requiring a relatively low temperature, positioned over the high temperature water gas shift reactor; and dividing plates positioned between the above three reactors and between the reforming reactor and the burner such that combustion exhaust gas produced in the burner supplies heat to the above reactors.
摘要翻译：公开了一种板式蒸汽重整器，其包括板式燃烧器，其能够加热位于重整器底部的作为热源的反应器的大面积区域; 需要相对较高温度的重整反应器，位于燃烧器上方; 位于重整反应器上方的需要相当温和的高温水煤气变换反应器; 需要相对低温的低温水煤气变换反应器，位于高温水煤气变换反应堆上; 以及位于上述三个反应器之间和重整反应器和燃烧器之间的分隔板，使得在燃烧器中产生的燃烧废气向上述反应器提供热量。

3. 发明授权

US06808652B2 Modified ⊖-alumina-supported nickel reforming catalyst and its use for producing synthesis gas from natural gas 失效
标题翻译：改性⊖-氧化铝负载镍重整催化剂及其在天然气生产合成气中的应用
公开(公告)号：US06808652B2
公开(公告)日：2004-10-26
申请号：US10750756
申请日：2004-01-05
申请人： Sang-Eon Park , Ki-Won Jun , Hyun-Seog Roh , Seung-Chan Baek , Young-Sam Oh , Young-Soon Baek , Ri-Sang Choi , Taek-Yong Song
发明人： Sang-Eon Park , Ki-Won Jun , Hyun-Seog Roh , Seung-Chan Baek , Young-Sam Oh , Young-Soon Baek , Ri-Sang Choi , Taek-Yong Song
IPC分类号： C07C2700
CPC分类号： B01J21/066 , B01J21/04 , B01J23/78 , B01J23/83 , C01B3/40 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/1052 , C01B2203/1082 , C01B2203/1241 , Y02P20/52
摘要： A modified ⊖-Al2O3-supported nickel reforming catalyst and its use for producing synthesis gas from natural gas, more specifically to a nickel reforming catalyst expressed by the following formula 1, having improved coke resistance, high-temperature catalysis stability and catalytic activity, which is prepared by coating nickel or mixture of nickel and cocatalyst (M1-M2-Ni) on a Al2O3 support modified with metal (M3-M4-ZrO2/⊖-Al2O3), and its use for producing synthesis gas from natural gas through steam reforming, oxygen reforming or steam-oxygen reforming, M1-M2-Ni/M3-M4-ZrO2/⊖-Al2O3 (1) wherein M1 is an alkali metal; each of M2 and M3 is an alkaline earth metal; and M4 is a IIIB element or a lanthanide.
摘要翻译：改性的⊖-Al 2 O 3负载的镍重整催化剂及其用于从天然气制备合成气的用途，更具体地说，涉及由下式1表示的镍重整催化剂，具有改善的耐焦性，高温催化稳定性和催化活性，通过在用金属（M3-M4-ZrO2 /⊖-Al2O3）改性的Al 2 O 3载体上涂覆镍或镍和助催化剂（M1-M2-Ni）的混合物制备，以及其用于通过蒸汽重整从天然气生产合成气的用途，氧气重整或蒸汽 - 氧气重整，其中M1是碱金属; M2和M3各自为碱土金属; M4是IIIB元素或镧系元素。

4. 发明授权

US06693060B2 Modified &thgr;-Al2O3-supported nickel reforming catalyst and its use for producing synthesis gas from natural gas 失效
标题翻译：改性的θ-Al2O3负载的镍重整催化剂及其从天然气生产合成气的用途
公开(公告)号：US06693060B2
公开(公告)日：2004-02-17
申请号：US10143669
申请日：2002-05-13
申请人： Sang-Eon Park , Ki-Won Jun , Hyun-Seog Roh , Seung-Chan Baek , Young-Sam Oh , Young-Soon Baek , Ri-Sang Choi , Taek-Yong Song
发明人： Sang-Eon Park , Ki-Won Jun , Hyun-Seog Roh , Seung-Chan Baek , Young-Sam Oh , Young-Soon Baek , Ri-Sang Choi , Taek-Yong Song
IPC分类号： B01J2340
CPC分类号： B01J21/066 , B01J21/04 , B01J23/78 , B01J23/83 , C01B3/40 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/1052 , C01B2203/1082 , C01B2203/1241 , Y02P20/52
摘要： A modified &thgr;-Al2O3-supported nickel reforming catalyst and its use for producing synthesis gas from natural gas, more specifically to a nickel reforming catalyst expressed by the following formula 1, having improved coke resistance, high-temperature catalysis stability and catalytic activity, which is prepared by coating nickel or mixture of nickel and cocatalyst (M1—M2—Ni) on a &thgr;-Al2O3 support modified with metal (M3—M4—ZrO2/&thgr;-Al2O3), and its use for producing synthesis gas from natural gas through steam reforming, oxygen reforming or steam-oxygen reforming, M1—M2—Ni/M3—M4—ZrO2/&thgr;-Al2O3 (1) wherein M1 is an alkali metal, each of M2 and M3 is an alkaline earth metal; and M4 is a IIIB element or a lanthanide.
摘要翻译：改性的θ-Al 2 O 3负载的镍重整催化剂及其用于从天然气生产合成气的用途，更具体地说，涉及由下式1表示的镍重整催化剂，具有改善的耐焦性，高温催化稳定性和催化活性，通过在用金属（M3-M4-ZrO 2 /θ-Al 2 O 3）改性的θ-Al 2 O 3载体上涂覆镍或镍和助催化剂（M1-M2-Ni）的混合物制备，以及其用于从天然气生产合成气的用途蒸汽重整，氧气重整或蒸汽 - 氧气重整，其中M1是碱金属，M2和M3各自是碱土金属; M4是IIIB元素或镧系元素。

5. 发明授权

US06476257B1 Method for preparing aromatic carboxylic acids from alkylaromatics by liquid-phase oxidation 失效
标题翻译：通过液相氧化由烷基芳族化合物制备芳族羧酸的方法
公开(公告)号：US06476257B1
公开(公告)日：2002-11-05
申请号：US09964750
申请日：2001-09-28
申请人： Sang-Eon Park , Jin S. Yoo , Ki-Won Jun , David B. Raju , Young-Ho Kim
发明人： Sang-Eon Park , Jin S. Yoo , Ki-Won Jun , David B. Raju , Young-Ho Kim
IPC分类号： C07C5116
CPC分类号： C07C51/265 , C07C63/16 , C07C63/333 , C07C63/36 , C07C63/06 , C07C63/40 , C07C63/24 , C07C63/307 , C07C63/26 , C07C63/38
摘要： The present invention relates to a method for preparing aromatic carboxylic acid from alkylaromatics by liquid-phase oxidation. More particularly, the present invention relates to a method for preparing aromatic carboxylic acid from alkylaromatics by oxidation in acetic acid as solvent with oxygen-containing gas in the presence of cobalt/manganese/bromine complex catalyst, wherein nickel and carbon dioxide in an appropriate amount are added to increase an activity of cobalt/manganese/bromine complex catalyst. Especially nickel has a synergistic effect with carbon dioxide and maximize the to formation of the desired product having the corresponding carboxylic groups to the number of alkyl groups in a reactant.
摘要翻译：本发明涉及通过液相氧化由烷基芳族化合物制备芳族羧酸的方法。更具体地说，本发明涉及一种通过在钴/锰/溴络合物催化剂存在下用含氧气体在乙酸中作为溶剂进行氧化从烷基芳族化合物制备芳族羧酸的方法，其中镍和二氧化碳的量适当加入钴/锰/溴配合物催化剂的活性。特别是镍与二氧化碳具有协同效应，并最大限度地使具有相应羧基的所需产物形成反应物中的烷基数。

6. 发明申请

US20110155325A1 BENDING DEVICE 有权
标题翻译：弯曲装置
公开(公告)号：US20110155325A1
公开(公告)日：2011-06-30
申请号：US12969729
申请日：2010-12-16
申请人： Mun-Yong LEE , Sang-Eon Park
发明人： Mun-Yong LEE , Sang-Eon Park
IPC分类号： B29C53/04
CPC分类号： B29C53/083 , B21D7/06 , B29L2031/008
摘要： The present invention relates to a bending device of which a beam is inserted between laminated moldings formed by slidably layering a plurality of molding plates, and the bending device of which deformation of the laminated moldings may simultaneously realize bending of up and down directions and side directions of a curved portion of a beam, and thus the bending device may realize a 3-dimensional bending process at once.
摘要翻译：弯曲装置技术领域本发明涉及一种弯曲装置，其中梁被插入到通过可滑动地分层多个模板而形成的层压模制件之间，并且层压模制品的变形可以同时实现上下方向和侧向的弯曲的弯曲部分，因此弯曲装置可以立即实现三维弯曲过程。

7. 发明授权

US06242380B1 Process for preparing supported nickel catalyst for reforming hydrocarbons 失效
标题翻译：制备用于重整碳氢化合物的负载型镍催化剂的方法
公开(公告)号：US06242380B1
公开(公告)日：2001-06-05
申请号：US08978799
申请日：1997-11-26
申请人： Sang-Eon Park , Jong-San Chang , Kyu-Wan Lee
发明人： Sang-Eon Park , Jong-San Chang , Kyu-Wan Lee
IPC分类号： B01J2946
CPC分类号： B01J37/0081 , B01J29/072 , B01J37/088 , C01B3/40 , C01B2203/1052 , Y02P20/52 , Y10S502/514
摘要： A process for preparing supported nickel catalyst consisting of supporting nickel or metal salt of nickel, alkali metal, alkaline earth metal having low melting point on silicon and aluminum-containing support having high surface area such as zeolite, silica and alumina as an oxide by melting effectively nickel or metal salt of nickel, alkali metal and alkaline earth metal having low melting point is disclosed. This process is characterized in that the supported nickel catalyst prepared by the present invention can be used in reforming reaction of hydrocarbons by using carbon dioxide, steam and oxygen as an oxidant. Metal salts used in the preparation of supported nickel catalyst is generally nitrate, chloride, acetate and carbonate having low melting point of 500° C. or less. The contents of nickel, alkali metal and alkaline earth metal of the catalyst are 1 to 20% by weight, 10% by weight or less and 20% by weight or less, respectively. The calcination temperature of the catalyst is in a range of 300° C. to 1200° C.
摘要翻译：一种制备负载型镍催化剂的方法，该方法包括将镍或镍的金属盐，碱金属，在硅上具有低熔点的碱土金属和具有高表面积的含铝载体如沸石，二氧化硅和氧化铝作为氧化物，通过熔化公开了具有低熔点的镍，碱金属和碱土金属的镍或金属盐。该方法的特征在于，通过使用二氧化碳，蒸汽和氧气作为氧化剂，通过本发明制备的负载型镍催化剂可用于烃的重整反应。用于制备负载型镍催化剂的金属盐通常是具有500℃或更低熔点的硝酸盐，氯化物，乙酸盐和碳酸盐。催化剂的镍，碱金属和碱土金属的含量分别为1〜20重量％，10重量％以下且20重量％以下。催化剂的煅烧温度在300℃〜1200℃的范围内。

8. 发明授权

US06958427B2 Method for catalytic dehydrogenation of hydrocarbons using carbon dioxide as a soft oxidant 失效
标题翻译：使用二氧化碳作为软氧化剂催化脱氢烃的方法
公开(公告)号：US06958427B2
公开(公告)日：2005-10-25
申请号：US10376322
申请日：2003-03-03
申请人： Sang-Eon Park , Jong-Son Chang , Min Seok Park
发明人： Sang-Eon Park , Jong-Son Chang , Min Seok Park
IPC分类号： B01J23/847 , C07B61/00 , C07C5/333 , C07C5/42 , C07C15/46 , C07C4/06
CPC分类号： C07C5/3332 , C07C2523/22 , C07C2523/26 , C07C2523/745 , C07C15/46 , C07C15/44
摘要： The present invention relates to a method for catalytic dehydrogenation of alkylaromatic hydrocarbons and more particularly, to a method for catalytic dehydrogenation of alkylaromatic hydrocarbons using carbon dioxide as a soft oxidant in the presence of a heterogeneous catalyst comprising both vanadium and iron, which allows operation at a lower reaction temperature due to improve thermodynamic equilibrium and provides an enhanced conversion of hydrocarbons and energy saving.
摘要翻译：本发明涉及一种烷基芳族烃的催化脱氢方法，更具体地说，涉及一种在包含钒和铁的多相催化剂存在下使用二氧化碳作为软氧化剂催化脱氢烷基芳烃的方法，其允许在由于改善了热力学平衡，反应温度较低，提供了碳氢化合物的转化和节能。

9. 发明申请

US20050043168A1 Preparation method of nanoporous VSB-5 molecular sieve 失效
标题翻译：纳米多孔VSB-5分子筛的制备方法
公开(公告)号：US20050043168A1
公开(公告)日：2005-02-24
申请号：US10875962
申请日：2004-06-25
申请人： Sung Jhung , Jong-San Chang , Sang-Eon Park , A.K. Cheetham
发明人： Sung Jhung , Jong-San Chang , Sang-Eon Park , A.K. Cheetham
IPC分类号： C01B39/54 , B01J20/02 , B01J29/82 , C01B3/00 , C01B37/00 , B01J29/04
CPC分类号： B01J20/2808 , B01J20/0225 , B01J20/0259 , B01J20/041 , B01J20/226 , B01J20/3078 , B01J29/82 , C01B3/001 , C01B37/002 , Y02E60/324
摘要： The present invention relates to a process for preparing nanoporous VSB-5 molecular sieves, and more particularly, to a process for preparing nanoporous VSB-5 molecular sieves useful as a hydrogen storage material, a catalyst, a catalyst supporter and an adsorbent, performed in such a manner that low-cost inorganic base or monoamine instead of a template essential in the conventional process is, as a pH modifier, incorporated into raw materials comprised of nickel and phosphorous compounds and crystallized to give VSB-5 molecular sieves in an economical and efficient manner.
摘要翻译：本发明涉及一种制备纳米多孔VSB-5分子筛的方法，更具体地说，涉及制备用作储氢材料的纳米多孔VSB-5分子筛的方法，催化剂，催化剂载体和吸附剂，其在这样的方式是将常规方法中所需的低成本无机碱或单胺替代模板作为pH调节剂掺入由镍和磷化合物组成的原料中并结晶化得到VSB-5分子筛的经济和有效的方式。

10. 发明授权

US5855815A Process for producing a synthesis gas from carbon dioxide 失效
标题翻译：从二氧化碳生产合成气的方法
公开(公告)号：US5855815A
公开(公告)日：1999-01-05
申请号：US601025
申请日：1996-04-29
申请人： Sang-Eon Park , Jong-San Chang , Kyu-Wan Lee
发明人： Sang-Eon Park , Jong-San Chang , Kyu-Wan Lee
IPC分类号： C10J1/00 , B01J23/78 , C01B3/40 , C07C1/02
CPC分类号： B01J23/78 , C01B3/40 , C01B2203/1052 , Y02P20/52
摘要： A process for producing a synthesis gas having carbon monoxide and hydrogen from the reduction of carbon dioxide with natural gas or lower hydrocarbons having methane as a main component and oxygen and steam over catalyst composed of nickel and, as promotors, alkali metal and alkaline earth metal component supported on silicon-containing support such as zeolite, silica, silicate and silica-alumina which are stable under reaction condition is disclosed. This process characterized in that the catalytic activity and performance property are improved by supporting alkali metal, alkaline earth metal and nickel oxide from metal salts having low melting point uniformly on silicon-containing support having high surface area by solid-state reaction. The amounts of adding alkali metal, alkaline earth metal and nickel are 0.01 to 10% by weight, 1 to 20% by weight and 1 to 20% by weight, respectively. The present invention is conducted in the temperature range from 600.degree. C. to 1000 .degree. C., and under a pressure of normal pressure to 20 atm, and gas hourly space velocity of 1,000 to 500,000/hour.
摘要翻译： PCT No.PCT / KR94 / 00113 Sec。 371日期：1996年4月29日 102（e）日期1996年4月29日PCT 1994年8月23日PCT公布。出版物WO95 / 06000 日期1995年3月2日由具有甲烷作为主要成分的天然气或低级烃的二氧化碳还原制备具有一氧化碳和氢气的合成气的方法，由镍构成的催化剂和作为促进剂的碱公开了在反应条件下稳定的负载在含硅载体如沸石，二氧化硅，硅酸盐和二氧化硅 - 氧化铝上的金属和碱土金属组分。该方法的特征在于，通过在具有高表面积的含硅载体上通过固相反应将碱金属，碱土金属和氧化镍从具有低熔点的金属盐均匀地支撑而提高了催化活性和性能。添加碱金属，碱土金属和镍的量分别为0.01〜10重量％，1〜20重量％和1〜20重量％。本发明在600〜1000℃的温度范围内，在常压至20大气压的压力下进行，气时空速为1000〜500,000 /小时。

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