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1. 发明申请

US20090247688A1 THERMOPLASTIC ELASTOMER COMPOSITION 审中-公开
标题翻译：热塑性弹性体组合物
公开(公告)号：US20090247688A1
公开(公告)日：2009-10-01
申请号：US12295038
申请日：2007-03-16
申请人： Yosuke Jogo , Mikio Masuda , Noboru Higashida , Shinichi Torigoe , Kazuki Tokuchi , Nobuhiro Moriguchi
发明人： Yosuke Jogo , Mikio Masuda , Noboru Higashida , Shinichi Torigoe , Kazuki Tokuchi , Nobuhiro Moriguchi
IPC分类号： C08L53/02
CPC分类号： C08F8/04 , C08L53/025 , C08F297/04 , C08L2666/04 , C08L2666/02
摘要： A thermoplastic elastomer composition comprising from 35 to 50 parts by mass of a hydrogenated block copolymer (a) having a weight-average molecular weight of from 70000 to 120000, from 30 to 50 parts by mass of a rubber softener (b) and from 5 to 25 parts by mass of a polystyrene-based resin (c) having a weight-average molecular weight of from 100000 to 400000 [provided that the total of (a), (b) and (c) is 100 parts by mass], wherein the hydrogenated block copolymer (a) is prepared by hydrogenating a block copolymer having at least two polymer blocks A mainly comprising a vinyl aromatic compound unit and at least one polymer block B mainly comprising a conjugated diene unit, and has a vinyl aromatic compound unit content of from 35 to 45% by mass, and at least 50% of the carbon-carbon double bonds derived from the conjugated diene in the polymer block B are hydrogenated.
摘要翻译：一种热塑性弹性体组合物，其包含35〜50质量份的重均分子量为70000〜120000的氢化嵌段共聚物（a），30〜50质量份的橡胶软化剂（b）和5 至25质量份的重均分子量为100000〜400000的聚苯乙烯类树脂（c）（条件是（a），（b）和（c）的合计为100质量份）其中氢化嵌段共聚物（a）通过氢化具有至少两个主要包含乙烯基芳族化合物单元的聚合物嵌段A和至少一个主要包含共轭二烯单元的聚合物嵌段B的嵌段共聚物制备，并且具有乙烯基芳族化合物单元含量为35〜45质量％，在聚合物嵌段B中由共轭二烯衍生的碳 - 碳双键的至少50％被氢化。

2. 发明申请

US20110112247A1 THERMOPLASTIC ACRYLIC RESIN COMPOSITION 有权
标题翻译：热塑性丙烯酸树脂组合物
公开(公告)号：US20110112247A1
公开(公告)日：2011-05-12
申请号：US12989193
申请日：2009-04-21
申请人： Kazuki Tokuchi , Wataru Tsuji , Nobuhiro Moriguchi , Noboru Higashida
发明人： Kazuki Tokuchi , Wataru Tsuji , Nobuhiro Moriguchi , Noboru Higashida
IPC分类号： C08L29/04
CPC分类号： C08L33/12 , C08F220/14 , C08L29/14 , Y10T428/31906 , Y10T428/31909 , Y10T428/31928 , C08L2666/04
摘要： Provided is a thermoplastic acrylic resin composition comprising a methacrylic resin (A) and a polyvinyl acetal resin (B) obtained by acetalizing a polyvinyl alcohol resin with an aldehyde having 4 or more carbon atoms and an aldehyde having 3 or less carbon atoms in which the total amount of the vinyl alcohol units acetalized with the aldehyde having 4 or more carbon atoms and the aldehyde having 3 or less carbon atoms is 65 to 85 mol % of all repeating units, and the molar ratio of the vinyl alcohol unit acetalized with the aldehyde having 4 or more carbon atoms to the vinyl alcohol unit acetalized with the aldehyde having 3 or less carbon atoms is from 90/10 to 0/100. Furthermore, provided are an article molded from the thermoplastic acrylic resin composition and a method of producing the thermoplastic acrylic resin composition comprising the steps of mixing a methacrylic resin (A) and a polyvinyl acetal resin (B), increasing the resin temperature to 160° C. or more, and then decreasing the resin temperature to 120° C. or less.
摘要翻译：本发明提供一种热塑性丙烯酸树脂组合物，其包含甲基丙烯酸系树脂（A）和聚乙烯醇缩醛树脂（B），所述聚乙烯醇缩醛树脂（B）通过使聚乙烯醇树脂与碳原子数为4以上的醛和碳原子数3以下的醛缩醛化，用具有4个或更多个碳原子的醛缩醛化的乙烯醇单元和具有3个或更少碳原子的醛的总量是所有重复单元的65至85mol％，并且乙醛醇单元与醛缩合的摩尔比对于具有3个以下碳原子的醛缩醛化的乙烯醇单元具有4个以上的碳原子数为90/10〜0/100。此外，提供了由热塑性丙烯酸类树脂组合物成型的制品和制造热塑性丙烯酸类树脂组合物的方法，其包括将甲基丙烯酸系树脂（A）和聚乙烯醇缩醛树脂（B）混合的步骤，将树脂温度提高到160℃ ℃以上，然后将树脂温度降低至120℃以下。

3. 发明授权

US08969474B2 Thermoplastic acrylic resin composition 有权
标题翻译：热塑性丙烯酸树脂组合物
公开(公告)号：US08969474B2
公开(公告)日：2015-03-03
申请号：US12989193
申请日：2009-04-21
申请人： Kazuki Tokuchi , Wataru Tsuji , Nobuhiro Moriguchi , Noboru Higashida
发明人： Kazuki Tokuchi , Wataru Tsuji , Nobuhiro Moriguchi , Noboru Higashida
IPC分类号： C08G63/48 , C08G63/91 , C08L29/04 , C08L33/12 , C08F220/14 , C08L29/14
CPC分类号： C08L33/12 , C08F220/14 , C08L29/14 , Y10T428/31906 , Y10T428/31909 , Y10T428/31928 , C08L2666/04
摘要： Provided is a thermoplastic acrylic resin composition comprising a methacrylic resin (A) and a polyvinyl acetal resin (B) obtained by acetalizing a polyvinyl alcohol resin with an aldehyde having 4 or more carbon atoms and an aldehyde having 3 or less carbon atoms in which the total amount of the vinyl alcohol units acetalized with the aldehyde having 4 or more carbon atoms and the aldehyde having 3 or less carbon atoms is 65 to 85 mol % of all repeating units, and the molar ratio of the vinyl alcohol unit acetalized with the aldehyde having 4 or more carbon atoms to the vinyl alcohol unit acetalized with the aldehyde having 3 or less carbon atoms is from 90/10 to 0/100. Furthermore, provided are an article molded from the thermoplastic acrylic resin composition and a method of producing the thermoplastic acrylic resin composition comprising the steps of mixing a methacrylic resin (A) and a polyvinyl acetal resin (B), increasing the resin temperature to 160° C. or more, and then decreasing the resin temperature to 120° C. or less.
摘要翻译：本发明提供一种热塑性丙烯酸树脂组合物，其包含甲基丙烯酸系树脂（A）和聚乙烯醇缩醛树脂（B），所述聚乙烯醇缩醛树脂（B）通过使聚乙烯醇树脂与碳原子数为4以上的醛和碳原子数3以下的醛缩醛化，用具有4个或更多个碳原子的醛缩醛化的乙烯醇单元和具有3个或更少碳原子的醛的总量是所有重复单元的65至85mol％，并且乙醛醇单元与醛缩合的摩尔比对于具有3个以下碳原子的醛缩醛化的乙烯醇单元具有4个以上的碳原子数为90/10〜0/100。此外，提供了由热塑性丙烯酸类树脂组合物成型的制品和制造热塑性丙烯酸类树脂组合物的方法，其包括将甲基丙烯酸系树脂（A）和聚乙烯醇缩醛树脂（B）混合的步骤，将树脂温度提高到160℃ ℃以上，然后将树脂温度降低至120℃以下。

4. 发明申请

US20130267647A1 POLYVINYL ACETAL RESIN FOR THERMOFORMING 审中-公开
标题翻译：聚乙烯乙烯树脂用于热成型
公开(公告)号：US20130267647A1
公开(公告)日：2013-10-10
申请号：US13876401
申请日：2011-09-26
申请人： Takuya Tsujimoto , Kazuki Tokuchi , Wataru Tsuji , Noboru Higashida , Naoki Fujiwara
发明人： Takuya Tsujimoto , Kazuki Tokuchi , Wataru Tsuji , Noboru Higashida , Naoki Fujiwara
IPC分类号： C08F116/06 , C08K5/103
CPC分类号： C08F116/06 , C08F8/48 , C08F216/38 , C08K5/103 , C08L29/14 , C08L71/02 , C08F8/28 , C08F16/06
摘要： An object of the invention is to provide a polyvinyl acetal resin for thermoforming that allows providing a molded product that is excellent in thermal stability, and excellent in the heat resistance without harming the properties of the polyvinyl acetal resin, and the invention relates to a polyvinyl acetal resin for thermoforming, which is obtained by acetalization of a polyvinyl alcohol resin having a viscosity average polymerization degree of 500 to 2000 and a saponification degree of 99.5 mol % or more with aldehyde, wherein the sum of vinyl alcohol units acetalized with the aldehyde is 65 to 88 mol % with respect to the total repeating units, and the content of alkali metal or alkali earth metal is 0.1 to 50 ppm. The molar ratio of a vinyl alcohol unit acetalized with an aldehyde having four or more carbon atoms/a vinyl alcohol unit acetalized with an aldehyde having three or less carbon atoms is preferably 90/10 to 0/100.
摘要翻译：本发明的目的是提供一种用于热成型的聚乙烯醇缩醛树脂，其能够提供热稳定性优异，耐热性优异而不损害聚乙烯醇缩醛树脂的性能的成型体，本发明涉及聚乙烯醇缩乙醛用于热成型的缩醛树脂，其通过用醛缩聚粘度平均聚合度为500〜2000，皂化度为99.5摩尔％以上的聚乙烯醇树脂，其中用醛缩醛化的乙烯醇单元的总和为相对于总重复单元为65〜88摩尔％，碱金属或碱土金属的含量为0.1〜50ppm。缩醛化的乙烯醇单元与碳原子数为4以上的乙烯醇单元/用碳原子数为3以下的醛缩醛化的乙烯醇单元的摩尔比优选为90/10〜0/100。

5. 发明申请

US20050239963A1 Polymer composition and uses thereof 有权
标题翻译：聚合物组合物及其用途
公开(公告)号：US20050239963A1
公开(公告)日：2005-10-27
申请号：US10509681
申请日：2003-04-21
申请人： Hajime Kitano , Kenji Shachi , Noboru Higashida , Koichi Wada , Mizuho Maeda
发明人： Hajime Kitano , Kenji Shachi , Noboru Higashida , Koichi Wada , Mizuho Maeda
IPC分类号： C08F297/02 , C08L33/00 , C08L53/00 , C08L53/02
CPC分类号： B32B27/32 , B32B27/08 , B32B27/18 , B32B27/302 , C08F297/00 , C08F297/02 , C08L33/00 , C08L53/00 , C08L53/02 , Y10T428/31909 , Y10T428/31917 , Y10T428/31924 , Y10T428/31928 , Y10T428/31935 , C08L2666/04
摘要： The present invention concerns a polymer composition comprising: a block copolymer (a) including a polymer block A, which is composed mainly of an α-methylstyrene, and a hydrogenated or unhydrogenated polymer block B, which is composed of a conjugated diene or isobutylene and has a weight average molecular weight of 30,000 to 200,000; an acrylic resin (b); and a softener (c), wherein proportions (by mass) of the respective components in the polymer composition are such that each of the following relationships (1) and (2) holds: 0.05≦Wb/Wa≦2 (1) and Wc/(Wa+Wb+Wc)≦0.5 (2) wherein Wa, Wb, and Wc represent amounts (by mass) of the block copolymer (a), the acrylic resin (b) and the softener (c), respectively. The polymer composition obtainable in accordance with the present invention is favorable in terms of such physical properties as formability, scratch resistance, abrasion resistance, flexibility, mechanical strength, rubber elasticity, and transparency and exhibits these properties in a well-balanced manner. By exploiting these favorable properties, the polymer composition can be effectively used in a wide range of applications, including stretchable materials, laminates, and foams.
摘要翻译：本发明涉及一种聚合物组合物，其包括：包含主要由α-甲基苯乙烯组成的聚合物嵌段A和由共轭二烯或异丁烯组成的氢化或未氢化的聚合物嵌段B的嵌段共聚物（a）和重均分子量为30,000〜200,000; 丙烯酸树脂（b）; 和软化剂（c），其中聚合物组合物中各成分的比例（质量比）使得以下关系式（1）和（2）中的每一个成立：<？in-line-formula description =“In- 线公式“end =”lead“？> 0.05 <= WB / WA <= 2（1）<？in-line-formula description =”In-line Formulas“end =”tail“？> <？in-line- 公式描述=“内联公式”end =“lead”？>和<？in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula description =“In 线公式“end =”lead“？> Wc /（Wa + Wb + Wc）<= 0.5（2）<？in-line-formula description =”In-line Formulas“end =”tail“？> Wb和Wc分别表示嵌段共聚物（a），丙烯酸树脂（b）和软化剂（c）的量（质量）。根据本发明获得的聚合物组合物在成形性，耐刮擦性，耐磨性，柔韧性，机械强度，橡胶弹性和透明性等物理性能方面是有利的，并且以良好的平衡方式显示出这些性质。通过利用这些有利的性质，聚合物组合物可以有效地用于广泛的应用中，包括可拉伸材料，层压材料和泡沫。

6. 发明授权

US07247674B2 Polymer composition and uses thereof 有权
标题翻译：聚合物组合物及其用途
公开(公告)号：US07247674B2
公开(公告)日：2007-07-24
申请号：US10509681
申请日：2003-04-21
申请人： Hajime Kitano , Kenji Shachi , Noboru Higashida , Koichi Wada , Mizuho Maeda
发明人： Hajime Kitano , Kenji Shachi , Noboru Higashida , Koichi Wada , Mizuho Maeda
IPC分类号： C08L53/02
CPC分类号： B32B27/32 , B32B27/08 , B32B27/18 , B32B27/302 , C08F297/00 , C08F297/02 , C08L33/00 , C08L53/00 , C08L53/02 , Y10T428/31909 , Y10T428/31917 , Y10T428/31924 , Y10T428/31928 , Y10T428/31935 , C08L2666/04
摘要： The present invention concerns a polymer composition comprising: a block copolymer (a) including a polymer block A, which is composed mainly of an α-methylstyrene, and a hydrogenated or unhydrogenated polymer block B, which is composed of a conjugated diene or isobutylene and has a weight average molecular weight of 30,000 to 200,000; an acrylic resin (b); and a softener (c),wherein proportions (by mass) of the respective components in the polymer composition are such that each of the following relationships (1) and (2) holds: 0.05≦Wb/Wa≦2 and (1) Wc/(Wa+Wb+Wc)≦0.5 (2) wherein Wa, Wb, and Wc represent amounts (by mass) of the block copolymer (a), the acrylic resin (b) and the softener (c), respectively. The polymer composition obtainable in accordance with the present invention is favorable in terms of such physical properties as formability, scratch resistance, abrasion resistance, flexibility, mechanical strength, rubber elasticity, and transparency and exhibits these properties in a well-balanced manner. By exploiting these favorable properties, the polymer composition can be effectively used in a wide range of applications, including stretchable materials, laminates, and foams.
摘要翻译：本发明涉及一种聚合物组合物，其包括：包含主要由α-甲基苯乙烯组成的聚合物嵌段A和由共轭二烯或异丁烯组成的氢化或未氢化的聚合物嵌段B的嵌段共聚物（a）和重均分子量为30,000〜200,000; 丙烯酸树脂（b）; 和软化剂（c），其中聚合物组合物中各成分的比例（质量比）使得以下关系式（1）和（2）中的每一个成立：<？in-line-formula description =“In- 行公式“end =”lead“？> 0.05 <= WB / WA <= 2和（1）<？在线公式描述=”在线公式“end =”tail“？> <？in-line -formulae description =“In-line Formulas”end =“lead”？> Wc /（Wa + Wb + Wc）<= 0.5（2）<？in-line-formula description =“In-line Formulas”end = 尾部“○>其中，Wa，Wb和Wc分别表示嵌段共聚物（a），丙烯酸树脂（b）和软化剂（c）的量（质量）。根据本发明获得的聚合物组合物在成形性，耐刮擦性，耐磨性，柔韧性，机械强度，橡胶弹性和透明性等物理性能方面是有利的，并且以良好的平衡方式显示出这些性质。通过利用这些有利的性质，聚合物组合物可以有效地用于广泛的应用中，包括可拉伸材料，层压材料和泡沫。

7. 发明申请

US20130280540A1 INTERLAYER FILM FOR LAMINATED GLASS, METHOD FOR PRODUCING SAME, AND LAMINATED GLASS USING SAME 审中-公开
标题翻译：用于层压玻璃的层间膜，其制造方法和使用其的层压玻璃
公开(公告)号：US20130280540A1
公开(公告)日：2013-10-24
申请号：US13992936
申请日：2011-12-06
申请人： Yusuke Amano , Keisuke Morikawa , Noboru Higashida , Jan Beekhuizen
发明人： Yusuke Amano , Keisuke Morikawa , Noboru Higashida , Jan Beekhuizen
IPC分类号： B32B17/10
CPC分类号： B32B17/10761 , B32B17/10633 , B32B17/10678 , B32B17/10688 , B32B2250/03 , B32B2329/06 , C08K5/0016 , C08K5/098 , C08K5/521 , Y10T428/3163 , Y10T428/31946 , C08L29/14
摘要： Provided is an interlayer film for laminated glass comprising: a layer x which contains polyvinyl acetal (A1) having a content of vinyl alcohol units of 22 mol % or less, a plasticizer (B), heat ray shielding microparticles (C), phosphoric acid ester (D), and alkali metal salt and/or alkali earth metal salt (F), and has an acid number in accordance with JIS K2501 of 1.5 KOH mg/g or less; and a layer y containing polyvinyl acetal (A2) having a content of vinyl alcohol units of from 25 to 34 mol %, the plasticizer (B), and an ultraviolet absorber (E), wherein the layers y are located on both sides of the layer x. This enables to provide an interlayer film for laminated glass that is excellent in transparency, adhesion, durability, sound insulation, and a heat ray shielding property.
摘要翻译：本发明提供一种夹层玻璃用中间膜，其特征在于，含有乙烯醇单元的含量为22摩尔％以下的聚乙烯醇缩醛（A1），增塑剂（B），热射线屏蔽微粒（C），磷酸酯（D）和碱金属盐和/或碱土金属盐（F），并且根据JIS K2501的酸值为1.5KOHmg / g以下; 和含有乙烯醇单元含量为25〜34摩尔％的聚乙烯醇缩醛（A2）的层y，增塑剂（B）和紫外线吸收剂（E），其中层y位于层x。由此，能够提供透明性，粘合性，耐久性，隔音性和热射线屏蔽性优异的夹层玻璃用中间膜。

8. 发明授权

US07718588B2 Lubricating oil additive containing acrylic polymer and lubricating oil compositions 有权
标题翻译：含丙烯酸聚合物和润滑油组合物的润滑油添加剂
公开(公告)号：US07718588B2
公开(公告)日：2010-05-18
申请号：US11632481
申请日：2005-07-14
申请人： Yoshihiro Morishita , Noboru Higashida , Hidetaka Oonuma , Kenichi Hamada , Kazushige Ishiura
发明人： Yoshihiro Morishita , Noboru Higashida , Hidetaka Oonuma , Kenichi Hamada , Kazushige Ishiura
IPC分类号： C10M145/14 , C08F220/18
CPC分类号： C10M145/14 , C08F293/005 , C08F297/026 , C08L53/00 , C10M2203/1006 , C10M2209/084 , C10N2220/02 , C10N2220/021 , C10N2220/022 , C10N2220/033 , C10N2230/02 , C10N2240/042 , C10N2240/045 , C10N2240/08 , C10N2240/10 , C10N2270/00 , C08L2666/02
摘要： A lubricating oil additive containing at least one acrylic block copolymer having a weight-average molecular weight of 10,000 to 1,000,000 and a molecular weight distribution [ratio of weight-average molecular weight (Mw) to number-average molecular weight (Mn), i.e., Mw/Mn ratio] of 1.5 or below; and lubricating oil compositions containing the additive. The lubricating oil additive exhibits a thickening effect higher than those of conventional acrylic lubricating oil additives and can improve the viscosity index of lubricating oil even when added in a small amount. Further, the additive can also improve the low-temperature characteristics, flow characteristics, and shear stability. The lubricating oil compositions enable energy saving and can lengthen the lifetime of lubricating oil and reduce the load on the global environment.
摘要翻译：一种润滑油添加剂，其含有至少一种重均分子量为10,000〜1,000,000的丙烯酸系嵌段共聚物和分子量分布[重均分子量（Mw）与数均分子量（Mn）的比例，即， Mw / Mn比]为1.5以下; 和含有添加剂的润滑油组合物。润滑油添加剂比常规的丙烯酸润滑油添加剂显示增稠效果，并且即使添加少量也能够提高润滑油的粘度指数。此外，添加剂还可以改善低温特性，流动特性和剪切稳定性。润滑油组合物能够节能并且可以延长润滑油的使用寿命并降低对全球环境的负荷。

9. 发明申请

US20080058234A1 Lubricating Oil Additive Containing Acrylic Polymer and Lubricating Oil Compositions 有权
标题翻译：含丙烯酸聚合物和润滑油组合物的润滑油添加剂
公开(公告)号：US20080058234A1
公开(公告)日：2008-03-06
申请号：US11632481
申请日：2005-07-14
申请人： Yoshihiro Morishita , Noboru Higashida , Hidetaka Oonuma , Kenichi Hamada , Kazushige Ishiura
发明人： Yoshihiro Morishita , Noboru Higashida , Hidetaka Oonuma , Kenichi Hamada , Kazushige Ishiura
IPC分类号： C10M145/14
CPC分类号： C10M145/14 , C08F293/005 , C08F297/026 , C08L53/00 , C10M2203/1006 , C10M2209/084 , C10N2220/02 , C10N2220/021 , C10N2220/022 , C10N2220/033 , C10N2230/02 , C10N2240/042 , C10N2240/045 , C10N2240/08 , C10N2240/10 , C10N2270/00 , C08L2666/02
摘要： A lubricating oil additive containing at least one acrylic block copolymer having a weight-average molecular weight of 10,000 to 1,000,000 and a molecular weight distribution [ratio of weight-average molecular weight (Mw) to number-average molecular weight (Mn), i.e., Mw/Mn ratio] of 1.5 or below; and lubricating oil compositions containing the additive. The lubricating oil additive exhibits a thickening effect higher than those of conventional acrylic lubricating oil additives and can improve the viscosity index of lubricating oil even when added in a small amount. Further, the additive can also improve the low-temperature characteristics, flow characteristics, and shear stability. The lubricating oil compositions enable energy saving and can lengthen the lifetime of lubricating oil and reduce the load on the global environment.
摘要翻译：一种润滑油添加剂，其含有至少一种重均分子量为10,000〜1,000,000的丙烯酸系嵌段共聚物和分子量分布[重均分子量（Mw）与数均分子量（Mn）的比例，即， Mw / Mn比]为1.5以下; 和含有添加剂的润滑油组合物。润滑油添加剂比常规的丙烯酸润滑油添加剂显示增稠效果，并且即使添加少量也能够提高润滑油的粘度指数。此外，添加剂还可以改善低温特性，流动特性和剪切稳定性。润滑油组合物能够节能并且可以延长润滑油的使用寿命并降低对全球环境的负荷。

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