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1. 发明授权

US4393106A Laminated plastic container and process for preparation thereof 失效
标题翻译：层压塑料容器及其制备方法
公开(公告)号：US4393106A
公开(公告)日：1983-07-12
申请号：US315952
申请日：1981-10-28
申请人： Yoshitsugu Maruhashi , Isao Tanikawa , Sadao Hirata , Jinichi Yazaki , Kozaburo Sakano
发明人： Yoshitsugu Maruhashi , Isao Tanikawa , Sadao Hirata , Jinichi Yazaki , Kozaburo Sakano
IPC分类号： B29C49/22 , B65D1/02 , B65D23/02 , B65D23/08 , C08J7/04 , B65D23/00 , B05D1/36 , B29D9/04 , B32B31/00
CPC分类号： B29C49/22 , B65D1/0215 , B65D23/02 , B65D23/0814 , C08J7/042 , B29B11/08 , B29B11/10 , B29B11/14 , B29B2911/14053 , B29B2911/14066 , B29B2911/1408 , B29B2911/14093 , B29B2911/1412 , B29B2911/14133 , B29B2911/1414 , B29B2911/1416 , B29B2911/14166 , B29B2911/1424 , B29B2911/14273 , B29B2911/1428 , B29B2911/14293 , B29B2911/14593 , B29B2911/14646 , B29B2911/14653 , B29B2911/14713 , B29B2911/1498 , B29C2049/026 , B29C2049/027 , B29C49/12 , B29K2023/06 , B29K2023/12 , B29K2027/06 , B29K2067/00 , B29K2105/253 , B29K2105/258 , B29K2623/06 , B29K2995/0073 , B29L2031/7158 , C08J2323/12 , C08J2427/08 , C08J2433/12 , Y10T428/1383
摘要： Disclosed is a laminated plastic container in the form of a bottle, the wall of which comprises a substrate formed of a melt-moldable plastic material, a coating layer formed on at least one surface of the substrate, said coating layer being composed of a copolymer consisting essentially of 99 to 70% by weight of vinylidene chloride and 1 to 30% by weight of at least one acrylic or methacrylic monomer and further including up to 100 parts by weight of at least one member selected from other ethylenically unsaturated monomers per 100 parts by weight of the total amount of said two monomers, said copolymer having an oxygen permeation coefficient of less than 9.times.10.sup.-14 cc.multidot.cm/cm.sup.2 .multidot.sec.multidot.cmHg as measured at a temperature of 20.degree. C. and a relative humidity of 100% and a water vapor permeability coefficient of less than 3.times.10.sup.-3 g.multidot.cm/m.sup.2 .multidot.day as determined according to the method of JIS Z-0208, and a protecting surface layer of a film-forming synthetic resin other than a vinylidene chloride resin, which is formed contiguously to said coating layer.This laminated plastic container is excellent in the barrier property to various gases such as oxygen, water vapor, nitrogen and carbon dioxide gas and other properties required for plastic containers. The humidity dependency of the oxygen barrier property is highly improved in this laminated plastic container.
摘要翻译：公开了一种瓶形的层压塑料容器，其壁包括由可熔融模塑的塑料材料形成的基材，形成在基材的至少一个表面上的涂层，所述涂层由共聚物基本上由99至70重量％的偏二氯乙烯和1至30重量％的至少一种丙烯酸或甲基丙烯酸单体组成，并且还包括至多100重量份的选自其它烯属不饱和单体每100份的至少一种的所述两种单体的总量，所述共聚物在20℃的温度和相对湿度为100％下测得的氧透过系数小于9×10-14 ccxcm / cm2xsecxcmHg，水蒸气透过系数根据JIS Z-0208的方法测定的小于3×10 -3 gxcm / m 2·x日，以及除了偏二氯乙烯树脂之外的成膜合成树脂的保护表面层，w 其形成与所述涂层相邻。这种层压塑料容器对于各种气体如氧气，水蒸汽，氮气和二氧化碳气体以及塑料容器所需的其它性能的阻隔性能优异。在该层压塑料容器中，氧阻隔性的湿度依赖性大大提高。

2. 发明授权

US4217161A Process for making a container 失效
标题翻译：制造容器的过程
公开(公告)号：US4217161A
公开(公告)日：1980-08-12
申请号：US955614
申请日：1978-10-30
申请人： Muneki Yamada , Sadao Hirata , Jinichi Yazaki , Yoshitsugu Maruhashi , Kozaburo Sakano , Akira Kishimoto , Shunsaku Hirata , Toru Suzuki , Fumio Kano
发明人： Muneki Yamada , Sadao Hirata , Jinichi Yazaki , Yoshitsugu Maruhashi , Kozaburo Sakano , Akira Kishimoto , Shunsaku Hirata , Toru Suzuki , Fumio Kano
IPC分类号： B29C47/06 , B29C51/14 , B32B27/08 , B65D65/40 , B29D7/02
CPC分类号： B32B27/08 , B29C47/0023 , B29C47/065 , B29C47/145 , B29C47/26 , B29C51/14 , B29C47/0019 , B29C47/0021
摘要： A transparent multi-layer container comprising a co-extrudate of an oxygen-barrier resin layer and an orienting resin layer which is monoaxially or biaxially oriented is disclosed. An adhesive resin layer is preferably interposed between the oxygen-barrier layer and the orienting resin layer, and this co-extrudate is drawn and molded at a specific temperature determined relatively to the melting points and softening points of the respective resins. This container is excellent in the combination of transparency, rigidity, mechanical strength, gas-barrier property and interlaminar peel strength.
摘要翻译：公开了一种透明的多层容器，其包含氧阻隔树脂层和单轴或双轴取向的取向树脂层的共挤出物。粘合树脂层优选插入在氧阻隔层和定向树脂层之间，并且该共挤出物在相对于各树脂的熔点和软化点确定的特定温度下拉伸和模制。该容器在透明度，刚性，机械强度，阻气性和层间剥离强度的组合方面优异。

3. 发明授权

US4182457A Multilayer container 失效
标题翻译：多层容器
公开(公告)号：US4182457A
公开(公告)日：1980-01-08
申请号：US821484
申请日：1977-08-03
申请人： Muneki Yamada , Sadao Hirata , Jinichi Yazaki , Yoshitsugu Maruhashi , Kozaburo Sakano , Akira Kishimoto , Shunsaku Hirata , Toru Suzuki , Fumio Kano
发明人： Muneki Yamada , Sadao Hirata , Jinichi Yazaki , Yoshitsugu Maruhashi , Kozaburo Sakano , Akira Kishimoto , Shunsaku Hirata , Toru Suzuki , Fumio Kano
IPC分类号： B29C51/14 , B32B27/00 , B32B27/08 , B65D65/40 , B32B15/08
CPC分类号： B32B27/08 , B29C51/14 , B32B2272/00 , Y10S428/91 , Y10T428/1379
摘要： A transparent multi-layer container comprising a co-extrudate of an oxygen-barrier resin layer and an orienting resin layer which is monoaxially or biaxially oriented is disclosed. An adhesive resin layer is preferably interposed between the oxygen-barrier layer and the orienting resin layer, and this co-extrudate is drawn and molded at a specific temperature determined relatively to the melting points and softening points of the respective resins. This container is excellent in the combination of transparency, rigidity, mechanical strength, gas-barrier property and interlaminar peel strength.
摘要翻译：公开了一种透明的多层容器，其包含氧阻隔树脂层和单轴或双轴取向的取向树脂层的共挤出物。粘合树脂层优选插入在氧阻隔层和定向树脂层之间，并且该共挤出物在相对于各树脂的熔点和软化点确定的特定温度下拉伸和模制。该容器在透明度，刚性，机械强度，阻气性和层间剥离强度的组合方面优异。

4. 发明授权

US4451512A Multi-layer plastic vessel 失效
标题翻译：多层塑料容器
公开(公告)号：US4451512A
公开(公告)日：1984-05-29
申请号：US507461
申请日：1983-06-24
申请人： Jinichi Yazaki , Kozaburo Sakano , Junichi Matsuo
发明人： Jinichi Yazaki , Kozaburo Sakano , Junichi Matsuo
IPC分类号： B32B27/28 , B29C49/22 , B32B7/12 , B32B27/32 , B65D1/02 , C09J123/26 , C09J163/00 , B65D23/00
CPC分类号： B65D1/0215 , B29C49/22 , B32B27/32 , B29K2995/0069 , Y10T428/1379 , Y10T428/1383 , Y10T428/31515 , Y10T428/31913
摘要： Disclosed is a multi-layer plastic vessel comprising a laminate including at least one layer composed mainly of a moisture-resistant thermoplastic resin, at least one layer composed mainly of an ethylene-vinyl alcohol copolymer and a thermoplastic resin adhesive layer interposed between both the resin layers, wherein said adhesive layer is composed of a composition comprising an acid- or acid anhydride-modified olefin resin and an epoxidized unsaturated carboxylic acid ester.
摘要翻译：公开了一种多层塑料容器，其包括层压体，其包括主要由耐湿热塑性树脂组成的至少一层，至少一层主要由乙烯 - 乙烯醇共聚物组成的层和插入在两个树脂之间的热塑性树脂粘合剂层层，其中所述粘合剂层由包含酸或酸酐改性的烯烃树脂和环氧化的不饱和羧酸酯的组合物组成。

5. 发明授权

US4751120A Polyester vessel having improved dimension stability and process for preparation thereof 失效
标题翻译：具有改进的尺寸稳定性的聚酯容器及其制备方法
公开(公告)号：US4751120A
公开(公告)日：1988-06-14
申请号：US14255
申请日：1987-02-11
申请人： Jinichi Yazaki , Kozaburo Sakano
发明人： Jinichi Yazaki , Kozaburo Sakano
IPC分类号： B32B27/32 , B65D23/08 , B65D3/06
CPC分类号： B32B27/32 , Y10T428/1352 , Y10T428/1383 , Y10T428/31736 , Y10T428/31794 , Y10T428/31797
摘要： In a thermoplastic polyester, a compound having at least two ethylenically unsaturated groups and/or oxirane rings in one molecule is coated as a crosslinking agent on the outer surface of the polyester substrate, or a polyester composition containing this crosslinking agent is laminated on the polyester substrate as the inner surface layer, and the crosslinking agent or the crosslinking agent-containing polyester composition is irradiated with ionizing radiant rays or ultraviolet rays. In this processed vessel, the dimension stability and rigidity are highly improved, and deformation under heat and/or pressure can be effectively prevented.
摘要翻译：在热塑性聚酯中，在一个分子中具有至少两个烯键式不饱和基团和/或环氧乙烷环的化合物作为交联剂涂布在聚酯基材的外表面上，或将含该交联剂的聚酯组合物层压在聚酯作为内表面层的基材，交联剂或含交联剂的聚酯组合物用电离辐射线或紫外线照射。在该处理容器中，尺寸稳定性和刚性得到很大改善，并且可以有效地防止在加热和/或压力下的变形。

6. 发明授权

US4687689A Polyester vessel having improved dimension stability and process for preparation thereof 失效
公开(公告)号：US4687689A
公开(公告)日：1987-08-18
申请号：US788212
申请日：1985-10-16
申请人： Jinichi Yazaki , Kozaburo Sakano
发明人： Jinichi Yazaki , Kozaburo Sakano
IPC分类号： B32B27/32 , B65D23/08 , B05D3/06
CPC分类号： B32B27/32 , Y10T428/1352 , Y10T428/1383 , Y10T428/31736 , Y10T428/31794 , Y10T428/31797
摘要： In a thermoplastic polyester, a compound having at least two ethylenically unsaturated groups and/or oxirane rings in one molecule is coated as a crosslinking agent on the outer surface of the polyester substrate, or a polyester composition containing this crosslinking agent is laminated on the polyester substrate as the inner surface layer, and the crosslinking agent or the crosslinking agent-containing polyester composition is irradiated with ionizing radiant rays or ultraviolet rays. In this processed vessel, the dimension stability and rigidity are highly improved, and deformation under heat and/or pressure can be effectively prevented.

7. 发明授权

US07173150B2 Process for recovering terephthalic acid from pulverized product of spent polyethylene terephthalate and system for use in such process 失效
标题翻译：从废聚对苯二甲酸乙二醇酯的粉碎产物中回收对苯二甲酸的方法和用于该方法的体系
公开(公告)号：US07173150B2
公开(公告)日：2007-02-06
申请号：US10424042
申请日：2003-04-24
申请人： Jinichi Yazaki , Kozaburo Sakano , Nobuyuki Funakoshi , Kazuho Tanaka
发明人： Jinichi Yazaki , Kozaburo Sakano , Nobuyuki Funakoshi , Kazuho Tanaka
IPC分类号： C07C51/09
CPC分类号： C07C51/43 , C07C51/09 , C07C51/412 , C07C51/47 , C08J11/24 , C08J2367/02 , Y02W30/706 , C07C63/28 , C07C63/26
摘要： This invention provides a process a process for recovering terephthalic acid from pulverized products of spent polyethylene terephthalate. This process comprises (1) a decomposition reaction step where the pulverized products of spent polyethylene terephthalate are continuously subjected to decomposition reaction in ethylene glycol in the presence of alkali, which is equimolar or excessmolar relative to the polyethylene terephthalate, so that salt of terephthalic acid and ethylene glycol can be continuously obtained; (2) a solid-liquid separation, dissolution, impurities-removing step where the ethylene glycol is separated from decomposition reaction slurry of salt of terephthalic acid and ethylene glycol, and the solid salt of terephthalic acid is dissolved into water, while insoluble impurities are removed; (3) a neutralization, crystallization step, where solution of said salt of terephthalic acid is neutralized with acid so that terephthalic acid can be crystallized; (4) a solid-liquid separation, washing stop where slurry of terephthalic acid crystals is subjected to solid-liquid separation so that the terephthalic acid crystals can be obtained and washed; and (5) a drying, pulverization step where the washed terephthalic acid crystals are dried and pulverized.
摘要翻译：本发明提供一种从废聚对苯二甲酸乙二醇酯的粉碎产物中回收对苯二甲酸的方法。该方法包括：（1）分解反应步骤，其中废聚对苯二甲酸乙二醇酯的粉碎产物在相对于聚对苯二甲酸乙二醇酯等摩尔或过量的碱的存在下在乙二醇中连续进行分解反应，使得对苯二甲酸的盐可连续获得乙二醇; （2）从对苯二甲酸和乙二醇盐的分解反应浆液中分离出乙二醇和对苯二甲酸的固体盐的固液分离，溶解，杂质去除步骤溶解在水中，不溶性杂质为删除（3）中和，结晶步骤，其中所述对苯二甲酸盐的溶液用酸中和，使对苯二甲酸可以结晶; （4）固液分离，其中对苯二甲酸晶体的浆液进行固液分离以使得可以获得和洗涤对苯二甲酸晶体的洗涤停止; 和（5）干燥，粉碎步骤，其中将洗涤的对苯二甲酸晶体干燥并粉碎。

8. 发明授权

US4600648A Hot-melt adhesive as intermediate layer of a laminate structure 失效
标题翻译：热熔胶作为层压结构的中间层
公开(公告)号：US4600648A
公开(公告)日：1986-07-15
申请号：US726366
申请日：1985-04-23
申请人： Jinichi Yazaki , Kozaburo Sakano , Junichi Matsuo
发明人： Jinichi Yazaki , Kozaburo Sakano , Junichi Matsuo
IPC分类号： C09J7/02 , C08G59/00 , C08K5/06 , C08L23/00 , C08L51/00 , C08L51/02 , C08L51/06 , C08L63/00 , C08L101/00 , C09J151/06 , B32B27/08 , B32B27/32 , B32B27/36 , B32B27/38
CPC分类号： C09J151/06 , Y10T428/31507 , Y10T428/31511 , Y10T428/31515 , Y10T428/31797 , Y10T428/31913
摘要： Disclosed is a hot-melt adhesive composed of a composition comprising an acid-modified olefin resin formed by graft modification of an ethylenically unsaturated carboxylic acid or its anhydride or a resin composition containing said modified olefin resin and an oxirane ring-containing compound, wherein said composition has a carbonyl group concentration of 1 to 600 millimoles per 100 g of the composition and an oxirane oxygen concentration of 0.01 to 50 millimoles per 100 g of the composition.
摘要翻译：公开了一种由包含由烯属不饱和羧酸或其酸酐的接枝改性形成的酸改性烯烃树脂或含有所述改性烯烃树脂的树脂组合物和含环氧乙烷环的化合物组成的组合物的热熔性粘合剂，其中所述组合物的羰基浓度为每100g组合物1至600毫摩尔，环氧乙烷氧浓度为每100g组合物0.01至50毫摩尔。

9. 发明授权

US4548985A Hot-melt adhesive 失效
标题翻译：热熔胶
公开(公告)号：US4548985A
公开(公告)日：1985-10-22
申请号：US507915
申请日：1983-06-27
申请人： Jinichi Yazaki , Kozaburo Sakano , Junichi Matsuo
发明人： Jinichi Yazaki , Kozaburo Sakano , Junichi Matsuo
IPC分类号： C09J7/02 , C08G59/00 , C08K5/06 , C08L23/00 , C08L51/00 , C08L51/02 , C08L51/06 , C08L63/00 , C08L101/00 , C09J151/06
CPC分类号： C09J151/06 , Y10T428/31507 , Y10T428/31511 , Y10T428/31515 , Y10T428/31797 , Y10T428/31913
摘要： Disclosed is a hot-melt adhesive composed of a composition comprising an acid-modified olefin resin formed by graft modification of an ethylenically unsaturated carboxylic acid or its anhydride or a resin composition containing said modified olefin resin and an oxirane ring-containing compound, wherein said composition has a carbonyl group concentration of 1 to 600 millimoles per 100 g of the composition and an oxirane oxygen concentration of 0.01 to 50 millimoles per 100 g of the composition.
摘要翻译：公开了一种由包含由烯属不饱和羧酸或其酸酐的接枝改性形成的酸改性烯烃树脂或含有所述改性烯烃树脂的树脂组合物和含环氧乙烷环的化合物组成的组合物的热熔性粘合剂，其中所述组合物的羰基浓度为每100g组合物1至600毫摩尔，环氧乙烷氧浓度为每100g组合物0.01至50毫摩尔。

10. 发明授权

US4511610A Multi-layer drawn plastic vessel 失效
标题翻译：多层拉伸塑料容器
公开(公告)号：US4511610A
公开(公告)日：1985-04-16
申请号：US536846
申请日：1983-09-29
申请人： Jinichi Yazaki , Kozaburo Sakano
发明人： Jinichi Yazaki , Kozaburo Sakano
IPC分类号： B32B27/32 , B65D65/40 , B65D85/00 , B32B27/08
CPC分类号： B32B27/322 , B32B27/32 , Y10S428/91 , Y10T428/1379 , Y10T428/1383 , Y10T428/31913
摘要： Disclosed is a multi-layer drawn plastic vessel comprising at least one layer composed mainly of at least one crystalline olefin resin selected from crystalline polypropylene and crystalline propylene/ethylene copolymers having an ethylene content of 1 to 20 mole %, at least one oxygen-barrier layer composed mainly of an ethylene/vinyl alcohol copolymer having an ethylene content of 25 to 60 mole %, and an adhesive resin layer interposed between said two resin layers, said adhesive resin layer containing an acid- or acid anhydride-modified, linear, low-density polyethylene or a mixture of said polyethylene with an acid- or acid anhydride-modified propylene resin and said crystalline olefin resin layer being molecularly oriented in at least one direction.
摘要翻译：公开了一种多层拉伸塑料容器，其包含至少一层主要由至少一种选自结晶聚丙烯的结晶烯烃树脂和乙烯含量为1至20摩尔％的结晶丙烯/乙烯共聚物组成的层，至少一个氧阻隔层主要由乙烯含量为25〜60摩尔％的乙烯/乙烯醇共聚物组成的层，以及插入在所述两个树脂层之间的粘合树脂层，所述粘合树脂层含有酸或酸酐改性的线性低密度聚乙烯或所述聚乙烯与酸或酸酐改性丙烯树脂的混合物，所述结晶烯烃树脂层在至少一个方向上分子取向。

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