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    • 1. 发明授权
    • Flame-retardant thermoplastic resin composition and molded article thereof
    • 阻燃热塑性树脂组合物及其成型品
    • US08609754B2
    • 2013-12-17
    • US13510820
    • 2010-11-18
    • Yoshitaka NaitoShigeki HamamotoHirotoshi SaitoHiroshi TanigawaJoichi WatanabeKoichi TezukaMasahito Nakamoto
    • Yoshitaka NaitoShigeki HamamotoHirotoshi SaitoHiroshi TanigawaJoichi WatanabeKoichi TezukaMasahito Nakamoto
    • C08L51/04
    • C08L25/12C08K5/523C08L33/18C08L55/02C08L2201/02C08L2666/24
    • Provided is a flame-retardant thermoplastic resin composition in which any halogenated flame retardant is not used but a phosphoric flame retardant is used, which has flame retardancy meeting U.S. UL Standard 94 V-2, which exhibits excellent dripping performance during burning, and which is excellent in balance between properties. The flame-retardant thermoplastic resin composition contains 100 parts by mass of a copolymer mixture containing a graft copolymer (A) obtained by graft-polymerizing a rubbery polymer, a vinyl cyanide compound, and a copolymerizable vinyl compound and a vinyl copolymer (B) which is obtained by copolymerizing the vinyl cyanide compound and the copolymerizable vinyl compound and which has a mass-average molecular weight of 90,000 to 160,000 and 5 to 20 parts by mass of a phosphoric flame retardant (C) blended with the copolymer mixture. The content CB1 of vinyl cyanide units in the acetone-insoluble fraction of the copolymer mixture is 22.0% to 32.0% by mass, the content CB2 of vinyl cyanide units in the acetone-soluble fraction thereof is 22.0% to 34.0% by mass, and |CB1−CB2| is 0% to 3.0% by mass.
    • 本发明提供一种阻燃热塑性树脂组合物,其中不使用任何卤化阻燃剂,但使用磷阻燃剂,其阻燃性符合美国UL标准94V-2,其在燃烧时表现出优异的滴水性能, 性能之间的平衡优异。 阻燃性热塑性树脂组合物含有100质量份含有通过使橡胶状聚合物,乙烯基氰化合物和可共聚乙烯基化合物接枝聚合得到的接枝共聚物(A)和乙烯基共聚物(B)的共聚物混合物, 通过共聚合乙烯基氰化合物和可共聚的乙烯基化合物,其质均分子量为90,000至160,000,和5至20质量份与共聚物混合物共混的磷阻燃剂(C)。 共聚物混合物的丙酮不溶级分中的乙烯基氰单元的含量CB1为22.0〜32.0质量%,丙酮可溶成分中的乙烯基氰单元的含量CB2为22.0〜34.0质量%, | CB1-CB2 | 为0〜3.0质量%。
    • 2. 发明申请
    • FLAME-RETARDANT THERMOPLASTIC RESIN COMPOSITION AND MOLDED ARTICLE THEREOF
    • 阻燃热塑性树脂组合物及其制品
    • US20120245261A1
    • 2012-09-27
    • US13510820
    • 2010-11-18
    • Yoshitaka NaitoShigeki HamamotoHirotoshi SaitoHiroshi TanigawaJoichi WatanabeKoichi TezukaMasahito Nakamoto
    • Yoshitaka NaitoShigeki HamamotoHirotoshi SaitoHiroshi TanigawaJoichi WatanabeKoichi TezukaMasahito Nakamoto
    • C08L9/06C08K5/52
    • C08L25/12C08K5/523C08L33/18C08L55/02C08L2201/02C08L2666/24
    • Provided is a flame-retardant thermoplastic resin composition in which any halogenated flame retardant is not used but a phosphoric flame retardant is used, which has flame retardancy meeting U.S. UL Standard 94 V-2, which exhibits excellent dripping performance during burning, and which is excellent in balance between properties. The flame-retardant thermoplastic resin composition contains 100 parts by mass of a copolymer mixture containing a graft copolymer (A) obtained by graft-polymerizing a rubbery polymer, a vinyl cyanide compound, and a copolymerizable vinyl compound and a vinyl copolymer (B) which is obtained by copolymerizing the vinyl cyanide compound and the copolymerizable vinyl compound and which has a mass-average molecular weight of 90,000 to 160,000 and 5 to 20 parts by mass of a phosphoric flame retardant (C) blended with the copolymer mixture. The content CB1 of vinyl cyanide units in the acetone-insoluble fraction of the copolymer mixture is 22.0% to 32.0% by mass, the content CB2 of vinyl cyanide units in the acetone-soluble fraction thereof is 22.0% to 34.0% by mass, and |CB1−CB2| is 0% to 3.0% by mass.
    • 本发明提供一种阻燃热塑性树脂组合物,其中不使用任何卤化阻燃剂,但使用磷阻燃剂,其阻燃性符合美国UL标准94V-2,其在燃烧时表现出优异的滴水性能, 性能之间的平衡优异。 阻燃性热塑性树脂组合物含有100质量份含有通过使橡胶状聚合物,乙烯基氰化合物和可共聚乙烯基化合物接枝聚合得到的接枝共聚物(A)和乙烯基共聚物(B)的共聚物混合物, 通过共聚合乙烯基氰化合物和可共聚的乙烯基化合物,其质均分子量为90,000至160,000,和5至20质量份与共聚物混合物共混的磷阻燃剂(C)。 共聚物混合物的丙酮不溶级分中的乙烯基氰单元的含量CB1为22.0〜32.0质量%,丙酮可溶成分中的乙烯基氰单元的含量CB2为22.0〜34.0质量%, | CB1-CB2 | 为0〜3.0质量%。