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    • 3. 发明授权
    • Reverse osmosis using a composite isocyanurate membrane
    • 使用复合异氰脲酸酯膜进行反渗透
    • US4366062A
    • 1982-12-28
    • US232112
    • 1981-02-06
    • Masaru KuriharaTetsuo WatanabeTetsuo Inoue
    • Masaru KuriharaTetsuo WatanabeTetsuo Inoue
    • C08G59/00B01D71/48B01D71/52B01D71/62B01D71/66C08G59/14C08G59/26C08G63/685C08G65/26C08G65/34C08G65/36C08J5/08B01D13/00
    • C08G65/263B01D71/62C08G59/26C08G63/685C08G65/34C08G65/36
    • A method for the selective separation of at least one water-soluble useful material from an aqueous solution by reverse osmosis is provided. The method comprises contacting the aqueous solution under pressure maintained above the osmotic pressure of the aqueous solution with a semipermeable composite membrane. The semipermeable composite membrane comprises a microporous substrate and a barrier layer having about 0.01 to about 0.1 micron thickness and composed of a cross-linked polymeric material having isocyanurate structures of Formula (I) formed on the microporous substrate: ##STR1## wherein each of R.sub.1, R.sub.2 and R.sub.3 is selected from the group consisting of hydrogen, a glycidyl group, and an alkyl radical containing from 2 to 5 carbon atoms, an alkyl radical carrying a functional hydroxyl group and an alkyl radical carrying a functional glycidyl group, with the proviso that at least two of R.sub.1, R.sub.2 and R.sub.3 are glycidyl groups, alkyl radicals carrying functional hydroxyl groups, alkyl radicals carrying glycidyl groups or a combination thereof. The cross-linked polymeric material has ether linkages, ester linkages or a combination thereof connecting the isocyanurate structures to each other.
    • 提供了通过反渗透从水溶液中选择性分离至少一种水溶性有用材料的方法。 该方法包括在水溶液的渗透压以上保持的压力下与半透膜复合膜接触。 半透膜复合膜包括微孔基材和具有约0.01至约0.1微米厚度的阻挡层,并由在微孔基材上形成的具有式(I)的异氰脲酸酯结构的交联聚合物材料组成:其中 R1,R2和R3各自选自氢,缩水甘油基和含有2至5个碳原子的烷基,带有官能羟基的烷基和带有官能缩水甘油基的烷基, 条件是R1,R2和R3中的至少两个是缩水甘油基,带有官能羟基的烷基,带有缩水甘油基的烷基或它们的组合。 交联聚合物材料具有醚键,酯键或其连接异氰脲酸酯结构彼此的组合。