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    • 1. 发明授权
    • Process for the production of silicon nitride sintered bodies
    • 制造氮化硅烧结体的方法
    • US4521358A
    • 1985-06-04
    • US521283
    • 1983-08-08
    • Kazunori MiuraYoshinori HattoriYasushi Matsuo
    • Kazunori MiuraYoshinori HattoriYasushi Matsuo
    • C04B35/591C04B35/593F02B3/06C04B35/58
    • C04B35/593C04B35/591F02B3/06
    • Processes for the production of a silicon nitride sintered body are disclosed. One process comprises molding a mixed powder of 100 parts by weight of metallic silicon with a maximum particle size of 20 .mu.m or less and 0.2 to 2 parts by weight (calculated as chromium oxide) of a chromium component and, thereafter, reaction sintering the mold in a nitrogen gas or in a non-oxidizing atmosphere containing nitrogen gas at a temperature of 1,300.degree. to 1,500.degree. C. This invention provides further process which comprises molding a mixed powder of 100 parts by weight of metallic silicon with a maximum particle size of 20 .mu.m or less, 0.2 to 1 part by weight (calculated as chromium oxide) of a chromium component, and further 10 to 20 parts by weight of an oxide component of one or more of the oxides of yttrium, lanthanum, cerium, gadolinium, and erbium, reaction sintering the above-prepared mold, and thereafter, hot pressing the reaction sintered body. This silicon nitride hot pressed body is superior in oxidation resistance, and moreover is of high density and has high mechanical strength. Thus it is suitable for use as, e.g., gas turbine parts of diesel engine parts.
    • 公开了制造氮化硅烧结体的方法。 一种方法包括:将100重量份最大粒度为20μm或更小的金属硅和0.2至2重量份(以铬氧化物计)的铬组分的混合粉末模塑,然后将 在氮气中或在含有氮气的非氧化性气氛中在1300〜1500℃的温度下成型。本发明提供了进一步的方法,其包括将最大粒径为100重量份的金属硅的混合粉末 20μm以下,0.2〜1重量份(以氧化铬计算)的铬成分,还含有10〜20重量份的氧化物成分,一种或多种钇,镧,铈, 钆和铒,对上述制备的模具进行反应烧结,然后热压该反应烧结体。 该氮化硅热压体的耐氧化性优异,而且密度高,机械强度高。 因此,它适用于例如柴油发动机部件的燃气轮机部件。