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    • 1. 发明申请
    • Method and apparatus for high-efficiency synthesis of carbon nanostructure, and carbon nanostructure
    • 用于高效合成碳纳米结构和碳纳米结构的方法和装置
    • US20100303675A1
    • 2010-12-02
    • US12805528
    • 2010-08-04
    • Osamu SuekaneToshikazu NosakaYoshikazu NakayamaLujun PanTakeshi NagasakaToru SakaiHiroyuki TsuchiyaToshiki GotoXu Li
    • Osamu SuekaneToshikazu NosakaYoshikazu NakayamaLujun PanTakeshi NagasakaToru SakaiHiroyuki TsuchiyaToshiki GotoXu Li
    • B01J19/00
    • B82Y30/00B82Y40/00C01B32/162C01B2202/30
    • Developed is high-efficiency synthesis method and apparatus capable of promoting the initial growth of carbon nanostructure by eliminating the initial fluctuation time and rising time in raw gas flow quantity.A high-efficiency synthesis method of carbon nanostructure according to the present invention is a high-efficiency synthesis method of carbon nanostructure, the method comprising: bringing raw material gas and a catalyst into contact with each other under reactive conditions so as to produce a carbon nanostructure, wherein: the initiation of contact of the raw material gas with the catalyst is carried out instantaneously. Reaction conditions such as temperature and raw material gas concentration are set so as to meet those for catalyst growth, and under the reaction conditions, the initiation of contact of raw material gas G with catalyst 6 is carried out instantaneously. Consequently, the initial growth of carbon nanostructure is positively carried out, and the height growth and thickness growth thereof can be effected in high efficiency. Further, high-density growth and short-time high-speed growth can be realized. The catalyst includes any forms of catalyst such as catalyst substrate, catalyst structure, catalyst powders and catalyst pellet. It is especially preferred to employ a system wherein the feed and interruption of the raw material gas G are intermittently controlled by means of an electromagnetic three-way valve 24.
    • 开发了通过消除原始气体流量的初始波动时间和上升时间,可以促进碳纳米结构初始生长的高效合成方法和装置。 根据本发明的碳纳米结构的高效合成方法是碳纳米结构的高效合成方法,该方法包括:使原料气体和催化剂在反应条件下彼此接触,以产生碳 纳米结构,其中:原料气体与催化剂的接触开始立即进行。 反应条件如温度和原料气体浓度设定为满足催化剂生长的条件,在反应条件下,原料气体G与催化剂6的接触开始立即进行。 因此,积极地进行碳纳米结构的初始生长,并且可以高效率地实现其高度生长和厚度生长。 此外,可以实现高密度生长和短时高速生长。 催化剂包括任何形式的催化剂,如催化剂底物,催化剂结构,催化剂粉末和催化剂颗粒。 特别优选采用通过电磁三通阀24间歇地控制原料气体G的进料和中断的系统。
    • 3. 发明授权
    • Apparatus for high-efficiency synthesis of carbon nanostructure
    • 碳纳米结构高效合成装置
    • US08505478B2
    • 2013-08-13
    • US12805528
    • 2010-08-04
    • Osamu SuekaneToshikazu NosakaYoshikazu NakayamaLujun PanTakeshi NagasakaToru SakaiHiroyuki TsuchiyaToshiki GotoXu Li
    • Osamu SuekaneToshikazu NosakaYoshikazu NakayamaLujun PanTakeshi NagasakaToru SakaiHiroyuki TsuchiyaToshiki GotoXu Li
    • C23C16/52C23C16/455C23F1/00H01L21/306C23C16/06C23C16/22
    • B82Y30/00B82Y40/00C01B32/162C01B2202/30
    • Developed is high-efficiency synthesis method and apparatus capable of promoting the initial growth of carbon nanostructure by eliminating the initial fluctuation time and rising time in raw gas flow quantity.-A high-efficiency synthesis method of carbon nanostructure according to the present invention is a high-efficiency synthesis method of carbon nanostructure, the method comprising: bringing raw material gas and a catalyst into contact with each other under reactive conditions so as to produce a carbon nanostructure, wherein: the initiation of contact of the raw material gas with the catalyst is carried out instantaneously. Reaction conditions such as temperature and raw material gas concentration are set so as to meet those for catalyst growth, and under the reaction conditions, the initiation of contact of raw material gas G with catalyst 6 is carried out instantaneously. Consequently, the initial growth of carbon nanostructure is positively carried out, and the height growth and thickness growth thereof can be effected in high efficiency. Further, high-density growth and short-time high-speed growth can be realized. The catalyst includes any forms of catalyst such as catalyst substrate, catalyst structure, catalyst powders and catalyst pellet. It is especially preferred to employ a system wherein the feed and interruption of the raw material gas G are intermittently controlled by means of an electromagnetic three-way valve 24.
    • 开发了能够通过消除原始气体流量的初始波动时间和上升时间来促进碳纳米结构的初始生长的高效合成方法和装置。根据本发明的碳纳米结构的高效合成方法是 碳纳米结构的高效合成方法,其特征在于,在反应条件下使原料气体和催化剂相互接触,制成碳纳米结构体,其中:原料气与催化剂的接触开始 是瞬间进行的。 反应条件如温度和原料气体浓度设定为满足催化剂生长的条件,在反应条件下,原料气体G与催化剂6的接触开始立即进行。 因此,积极地进行碳纳米结构的初始生长,并且可以高效率地实现其高度生长和厚度生长。 此外,可以实现高密度生长和短时高速生长。 催化剂包括任何形式的催化剂,如催化剂底物,催化剂结构,催化剂粉末和催化剂颗粒。 特别优选采用通过电磁三通阀24间歇地控制原料气体G的进料和中断的系统。
    • 4. 发明授权
    • Method for high-efficiency synthesis of carbon nanostructure
    • 碳纳米结构高效合成方法
    • US07790228B2
    • 2010-09-07
    • US10551051
    • 2004-03-23
    • Osamu SuekaneToshikazu NosakaYoshikazu NakayamaLujun PanTakeshi NagasakaToru SakaiHiroyuki TsuchiyaToshiki GotoXu Li
    • Osamu SuekaneToshikazu NosakaYoshikazu NakayamaLujun PanTakeshi NagasakaToru SakaiHiroyuki TsuchiyaToshiki GotoXu Li
    • C23C16/00
    • B82Y30/00B82Y40/00C01B32/162C01B2202/30
    • Developed is high-efficiency synthesis method and apparatus capable of promoting the initial growth of carbon nanostructure by eliminating the initial fluctuation time and rising time in raw gas flow quantity.A high-efficiency synthesis method of carbon nanostructure according to the present invention is a high-efficiency synthesis method of carbon nanostructure, the method comprising: bringing raw material gas and a catalyst into contact with each other under reactive conditions so as to produce a carbon nanostructure, wherein: the initiation of contact of the raw material gas with the catalyst is carried out instantaneously. Reaction conditions such as temperature and raw material gas concentration are set so as to meet those for catalyst growth, and under the reaction conditions, the initiation of contact of raw material gas G with catalyst 6 is carried out instantaneously. Consequently, the initial growth of carbon nanostructure is positively carried out, and the height growth and thickness growth thereof can be effected in high efficiency. Further, high-density growth and short-time high-speed growth can be realized. The catalyst includes any forms of catalyst such as catalyst substrate, catalyst structure, catalyst powders and catalyst pellet. It is especially preferred to employ a system wherein the feed and interruption of the raw material gas G are intermittently controlled by means of an electromagnetic three-way valve 24.
    • 开发了通过消除原始气体流量的初始波动时间和上升时间,可以促进碳纳米结构初始生长的高效合成方法和装置。 根据本发明的碳纳米结构的高效合成方法是碳纳米结构的高效合成方法,该方法包括:使原料气体和催化剂在反应条件下彼此接触,以产生碳 纳米结构,其中:原料气体与催化剂的接触开始立即进行。 反应条件如温度和原料气体浓度设定为满足催化剂生长的条件,在反应条件下,原料气体G与催化剂6的接触开始立即进行。 因此,积极地进行碳纳米结构的初始生长,并且可以高效率地实现其高度生长和厚度生长。 此外,可以实现高密度生长和短时高速生长。 催化剂包括任何形式的催化剂,如催化剂底物,催化剂结构,催化剂粉末和催化剂颗粒。 特别优选采用通过电磁三通阀24间歇地控制原料气体G的进料和中断的系统。
    • 5. 发明申请
    • Method and apparatus for high-efficiency synthesis of carbon nanostructure, and carbon nanostructure
    • 用于高效合成碳纳米结构和碳纳米结构的方法和装置
    • US20070037370A1
    • 2007-02-15
    • US10551051
    • 2004-03-23
    • Osamu SuekaneToshikazu NosakaYoshikazu NakayamaLujun PanTakeshi NagasakaToru SakaiHiroyuki TsuchiyaToshiki GotoXu Li
    • Osamu SuekaneToshikazu NosakaYoshikazu NakayamaLujun PanTakeshi NagasakaToru SakaiHiroyuki TsuchiyaToshiki GotoXu Li
    • H01L21/20
    • B82Y30/00B82Y40/00C01B32/162C01B2202/30
    • Developed is high-efficiency synthesis method and apparatus capable of promoting the initial growth of carbon nanostructure by eliminating the initial fluctuation time and rising time in raw gas flow quantity. A high-efficiency synthesis method of carbon nanostructure according to the present invention is a high-efficiency synthesis method of carbon nanostructure, the method comprising: bringing raw material gas and a catalyst into contact with each other under reactive conditions so as to produce a carbon nanostructure, wherein: the initiation of contact of the raw material gas with the catalyst is carried out instantaneously. Reaction conditions such as temperature and raw material gas concentration are set so as to meet those for catalyst growth, and under the reaction conditions, the initiation of contact of raw material gas G with catalyst 6 is carried out instantaneously. Consequently, the initial growth of carbon nanostructure is positively carried out, and the height growth and thickness growth thereof can be effected in high efficiency. Further, high-density growth and short-time high-speed growth can be realized. The catalyst includes any forms of catalyst such as catalyst substrate, catalyst structure, catalyst powders and catalyst pellet. It is especially preferred to employ a system wherein the feed and interruption of the raw material gas G are intermittently controlled by means of an electromagnetic three-way valve 24.
    • 开发了通过消除原始气体流量的初始波动时间和上升时间,可以促进碳纳米结构初始生长的高效合成方法和装置。 根据本发明的碳纳米结构的高效合成方法是碳纳米结构的高效合成方法,该方法包括:使原料气体和催化剂在反应条件下彼此接触,以产生碳 纳米结构,其中:原料气体与催化剂的接触开始立即进行。 反应条件如温度和原料气体浓度设定为满足催化剂生长的条件,在反应条件下,原料气体G与催化剂6的接触开始立即进行。 因此,积极地进行碳纳米结构的初始生长,并且可以高效率地实现其高度生长和厚度生长。 此外,可以实现高密度生长和短时高速生长。 催化剂包括任何形式的催化剂,如催化剂底物,催化剂结构,催化剂粉末和催化剂颗粒。 特别优选采用通过电磁三通阀24间歇地控制原料气体G的进料和中断的系统。
    • 10. 发明申请
    • Catalyst Body for Production of Brush-shaped Carbon Nanostructure
    • 刷形碳纳米结构生产催化剂体
    • US20110319260A1
    • 2011-12-29
    • US13224115
    • 2011-09-01
    • Yoshikazu NakayamaToru SakaiTakeshi Nagasaka
    • Yoshikazu NakayamaToru SakaiTakeshi Nagasaka
    • B01J23/745B01J35/02
    • B01J37/0244B01J21/08B01J23/745B01J35/006B01J35/023B01J37/0238B01J37/14B82Y30/00B82Y40/00C01B32/162C01B2202/34Y10S502/524
    • It is intended to highly efficiently produce a high-density brush shaped carbon nanostructure useful in the production of CNT assembly, such as rope-shaped CNTs, and provide a catalyst body for production of brush-shaped carbon nanostructure that enables the production. The catalyst body for production of brush-shaped carbon nanostructure is one comprising a substrate (32), an aggregation suppressive layer (34) superimposed on a surface thereof and a catalyst layer superimposed on the aggregation suppressive layer (34). The catalyst layer is a catalyst particle layer (44) consisting of metallic catalyst particles (42) composed mainly of a catalytic metal. The metallic catalyst particles (42) have an average particle diameter, D, satisfying the relationship 0.5 nm≦D≦80 nm, and individual particles of the metallic catalyst particles (42) have a diameter, d, falling within the range of the above average particle diameter (D). Further, there are disclosed a process for producing the catalyst body, a brush-shaped carbon nanostructure and a process for producing the same.
    • 旨在高效地生产可用于生产CNT组件(例如绳状CNT)的高密度刷状碳纳米结构,并且提供用于生产能够生产的刷状碳纳米结构的催化剂体。 用于生产刷状碳纳米结构的催化剂体是包括基板(32),叠加在其表面上的聚集抑制层(34)和叠加在聚集抑制层(34)上的催化剂层的催化剂体。 催化剂层是由主要由催化金属组成的金属催化剂颗粒(42)组成的催化剂颗粒层(44)。 金属催化剂粒子(42)的平均粒径D满足0.5nm≦̸ D≦̸ 80nm的关系,金属催化剂粒子(42)的各个粒子的直径d落在上述范围内 平均粒径(D)。 此外,公开了一种催化剂体的制造方法,刷状碳纳米结构体及其制造方法。