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1. 发明申请

US20090247798A1 NORBORNENE DERIVATIVE, NORBORNENE POLYMER PRODUCED BY RING-OPENING (CO)POLYMERIZATION, AND PROCESS FOR PRODUCING THE POLYMER BY RING-OPENING (CO)POLYMERIZATION 有权
标题翻译： NORBORNENE衍生物，通过开环（CO）聚合制备的NORBENNENE聚合物，以及通过开环（CO）聚合制备聚合物的方法
公开(公告)号：US20090247798A1
公开(公告)日：2009-10-01
申请号：US12416451
申请日：2009-04-01
申请人： Yoshikazu Miyamoto , Nobuyuki Miyaki , Kohei Goto , Yuichi Hashiguchi
发明人： Yoshikazu Miyamoto , Nobuyuki Miyaki , Kohei Goto , Yuichi Hashiguchi
IPC分类号： C07C13/567
CPC分类号： C07C43/215 , C07C13/72 , C07C25/24 , C07C43/285 , C07C2603/97 , C08G61/06
摘要： The norbornene derivative of the present invention is represented by the following formula (Im). According to the present invention, a novel norbornene derivative that is useful as a precursor monomer for preparing a cycloolefin polymer exhibiting excellent transparency, heat resistance and low-water absorption properties and having been freely controlled in the birefringence properties and the wavelength dispersion properties can be provided. According to the present invention, further, a norbornene ring-opened (co)polymer having excellent transparency and heat resistance, exhibiting high solubility in organic solvents and having specific birefringence properties and wavelength dependence, and a process for preparing the ring-opened (co)polymer can be provided.
摘要翻译：本发明的降冰片烯衍生物由下式（Im）表示。根据本发明，作为用于制备具有优异的透明性，耐热性和低吸水性的环烯烃聚合物的前体单体的新型降冰片烯衍生物可以在双折射性和波长分散性中自由控制，提供。根据本发明，另外，具有优异的透明性和耐热性，在有机溶剂中显示出高溶解性并具有特定的双折射性和波长依赖性的降冰片烯开环（共）聚合物，以及制备开环（共）聚合物。

2. 发明授权

US07541411B2 Norbornene derivative, norbornene polymer produced by ring-opening (co)polymerization, and process for producing the polymer by ring-opening (co)polymerization 有权
标题翻译：降冰片烯衍生物，通过开环（共）聚合制备的降冰片烯聚合物，以及通过开环（共）聚合制备聚合物的方法
公开(公告)号：US07541411B2
公开(公告)日：2009-06-02
申请号：US10556717
申请日：2004-04-27
申请人： Yoshikazu Miyamoto , Nobuyuki Miyaki , Kohei Goto , Yuichi Hashiguchi
发明人： Yoshikazu Miyamoto , Nobuyuki Miyaki , Kohei Goto , Yuichi Hashiguchi
IPC分类号： C08G61/00 , C08G61/06 , C03C1/00 , C07C13/00 , C07C13/72 , C07C25/24 , C07C43/215 , C07C43/285
CPC分类号： C07C43/215 , C07C13/72 , C07C25/24 , C07C43/285 , C07C2603/97 , C08G61/06
摘要： The norbornene derivative of the present invention is represented by the following formula (Im). According to the present invention, a novel norbornene derivative that is useful as a precursor monomer for preparing a cycloolefin polymer exhibiting excellent transparency, heat resistance and low-water absorption properties and having been freely controlled in the birefringence properties and the wavelength dispersion properties can be provided. According to the present invention, further, a norbornene ring-opened (co)polymer having excellent transparency and heat resistance, exhibiting high solubility in organic solvents and having specific birefringence properties and wavelength dependence, and a process for preparing the ring-opened (co)polymer can be provided.
摘要翻译：本发明的降冰片烯衍生物由下式（Im）表示。根据本发明，作为用于制备具有优异的透明性，耐热性和低吸水性的环烯烃聚合物的前体单体的新型降冰片烯衍生物可以双折射性质和波长分散性能自由控制，提供。根据本发明，另外，具有优异的透明性和耐热性，在有机溶剂中显示出高溶解性并具有特定的双折射性和波长依赖性的降冰片烯开环（共）聚合物，以及制备开环（共）聚合物。

3. 发明授权

US07759437B2 Norbornene derivative, norbornene polymer produced by ring-opening (co)polymerization, and process for producing the polymer by ring-opening (co)polymerization 有权
标题翻译：降冰片烯衍生物，通过开环（共）聚合制备的降冰片烯聚合物，以及通过开环（共）聚合制备聚合物的方法
公开(公告)号：US07759437B2
公开(公告)日：2010-07-20
申请号：US12416451
申请日：2009-04-01
申请人： Yoshikazu Miyamoto , Nobuyuki Miyaki , Kohei Goto , Yuichi Hashiguchi
发明人： Yoshikazu Miyamoto , Nobuyuki Miyaki , Kohei Goto , Yuichi Hashiguchi
IPC分类号： C08G61/00 , C08G61/06 , C07C1/00 , C07C13/00 , C07C13/72 , C07C25/24 , C07C43/215 , C07C43/285
CPC分类号： C07C43/215 , C07C13/72 , C07C25/24 , C07C43/285 , C07C2603/97 , C08G61/06
摘要： The norbornene derivative of the present invention is represented by the following formula (Im). According to the present invention, a novel norbornene derivative that is useful as a precursor monomer for preparing a cycloolefin polymer exhibiting excellent transparency, heat resistance and low-water absorption properties and having been freely controlled in the birefringence properties and the wavelength dispersion properties can be provided. According to the present invention, further, a norbornene ring-opened (co)polymer having excellent transparency and heat resistance, exhibiting high solubility in organic solvents and having specific birefringence properties and wavelength dependence, and a process for preparing the ring-opened (co)polymer can be provided.
摘要翻译：本发明的降冰片烯衍生物由下式（Im）表示。根据本发明，作为用于制备具有优异的透明性，耐热性和低吸水性的环烯烃聚合物的前体单体的新型降冰片烯衍生物可以在双折射性和波长分散性中自由控制，提供。根据本发明，另外，具有优异的透明性和耐热性，在有机溶剂中显示出高溶解性并具有特定的双折射性和波长依赖性的降冰片烯开环（共）聚合物，以及制备开环（共）聚合物。

4. 发明申请

US20070065747A1 Norbornene derivative, norbornene polymer produced by ring-opening (co)polymerization, and process for producing the polymer by ring-opening (co)polymerization 有权
标题翻译：降冰片烯衍生物，通过开环（共）聚合制备的降冰片烯聚合物，以及通过开环（共）聚合制备聚合物的方法
公开(公告)号：US20070065747A1
公开(公告)日：2007-03-22
申请号：US10556717
申请日：2004-04-27
申请人： Yoshikazu Miyamoto , Nobuyuki Miyaki , Kohei Goto , Yuichi Hashiguchi
发明人： Yoshikazu Miyamoto , Nobuyuki Miyaki , Kohei Goto , Yuichi Hashiguchi
IPC分类号： G03C1/00
CPC分类号： C07C43/215 , C07C13/72 , C07C25/24 , C07C43/285 , C07C2603/97 , C08G61/06
摘要： The norbornene derivative of the present invention is represented by the following formula (Im). According to the present invention, a novel norbornene derivative that is useful as a precursor monomer for preparing a cycloolefin polymer exhibiting excellent transparency, heat resistance and low-water absorption properties and having been freely controlled in the birefringence properties and the wavelength dispersion properties can be provided. According to the present invention, further, a norbornene ring-opened (co)polymer having excellent transparency and heat resistance, exhibiting high solubility in organic solvents and having specific birefringence properties and wavelength dependence, and a process for preparing the ring-opened (co)polymer can be provided.
摘要翻译：本发明的降冰片烯衍生物由下式（Im）表示。根据本发明，作为用于制备具有优异的透明性，耐热性和低吸水性的环烯烃聚合物的前体单体的新型降冰片烯衍生物可以在双折射性和波长分散性中自由控制，提供。根据本发明，另外，具有优异的透明性和耐热性，在有机溶剂中显示出高溶解性并具有特定的双折射性和波长依赖性的降冰片烯开环（共）聚合物，以及制备开环（共）聚合物。

5. 发明授权

US07230058B2 Ring-opened polynorbornenes 有权
标题翻译：开环聚降冰片烯
公开(公告)号：US07230058B2
公开(公告)日：2007-06-12
申请号：US11362086
申请日：2006-02-27
申请人： Nobuyuki Miyaki , Yoshikazu Miyamoto , Souichi Yoshida , Yuichi Hashiguchi
发明人： Nobuyuki Miyaki , Yoshikazu Miyamoto , Souichi Yoshida , Yuichi Hashiguchi
IPC分类号： C08G61/08 , C08F8/04
CPC分类号： C08G61/06 , Y10S525/94
摘要： The disclosure is directed to a partially hydrogenated ring-opened polynorbornene and a process for making the same. The ring-opened polynorbornene is low in birefringence, high in wavelength dependency about birefringence and excellent in transparency and heat resistance.
摘要翻译：本发明涉及部分氢化的开环聚降冰片烯及其制备方法。开环聚降冰片烯的双折射率低，双折射波长依赖性高，透明性和耐热性优异。

6. 发明申请

US20060189771A1 Ring-opened polynorbornenes 有权
标题翻译：开环聚降冰片烯
公开(公告)号：US20060189771A1
公开(公告)日：2006-08-24
申请号：US11362086
申请日：2006-02-27
申请人： Nobuyuki Miyaki , Yoshikazu Miyamoto , Souichi Yoshida , Yuichi Hashiguchi
发明人： Nobuyuki Miyaki , Yoshikazu Miyamoto , Souichi Yoshida , Yuichi Hashiguchi
IPC分类号： C08F222/40
CPC分类号： C08G61/06 , Y10S525/94
摘要： The invention provides a ring-opened norbornene polymer that is relatively small in birefringence, has specific wavelength dependency about birefringence and is excellent in transparency and heat resistance. [Solving means] The polymer of the present invention has a structural unit (I) of the general formula (I): wherein in the general formula (I), m and n are integers of 0 to 2, X1 is an ethylene or vinylene group, R1 and R2 are individually a hydrogen atom or a substituted or unsubstituted hydrocarbon group having 1 to 30 carbon atoms, and R3 is a group of the general formula (I-1) or (I-2), in which in the general formulae (I-1) and (I-2), R11 to R27 are individually a hydrogen atom; a halogen atom; a substituted or unsubstituted hydrocarbon group having 1 to 30 carbon atoms, which may have a linkage containing or not containing oxygen, sulfur, nitrogen and/or silicon atom(s); or a polar group, p and q in the general formula (I-1) are individually 0 or a positive integer, with the proviso that when both p and q are 0, R12 and R15, or R19 and R15 may be bonded to each other to form a carbon ring or heterocyclic ring, and the carbon ring or heterocyclic ring may be either a monocyclic structure or a polycyclic structure, and s in the general formula (I-2) is 0 or a positive integer.
摘要翻译：本发明提供双折射相对较小的开环降冰片烯聚合物，具有关于双折射的特定波长依赖性，透明性和耐热性优异。 [解决方案]本发明的聚合物具有通式（I）的结构单元（I）：其中在通式（I）中，m和n为0-2的整数，X 1， / SUP>是乙烯或亚乙烯基，R 1和R 2分别是氢原子或取代或未取代的具有1至30个碳原子的烃基，R 3是通式（I-1）或（I-2）的基团，其中在通式（I-1）和（I-2）中，R 11 R 27彼此独立地为氢原子; 卤素原子; 取代或未取代的具有1至30个碳原子的烃基，其可以具有含有或不含氧，硫，氮和/或硅原子的键; 或通式（I-1）中的极性基团p和q分别为0或正整数，条件是当p和q均为0时，R 12和R SUP > 15，或R 19和R 15可以彼此键合以形成碳环或杂环，并且碳环或杂环可以为单环结构或多环结构，通式（I-2）中的s为0或正整数。

7. 发明申请

US20060041092A1 Ring-opened polynorbornenes 有权
标题翻译：开环聚降冰片烯
公开(公告)号：US20060041092A1
公开(公告)日：2006-02-23
申请号：US10534003
申请日：2003-11-12
申请人： Nobuyuki Miyaki , Yoshikazu Miyamoto , Souichi Yoshida , Yuichi Hashiguchi
发明人： Nobuyuki Miyaki , Yoshikazu Miyamoto , Souichi Yoshida , Yuichi Hashiguchi
IPC分类号： C08F36/00 , C08F136/00
CPC分类号： C08G61/06 , Y10S525/94
摘要： The invention provides a ring-opened polynorbornene that is relatively low in birefringence, has specific wavelength dependency about birefringence and is excellent in transparency and heat resistance. [Solving means] The polymer of the present invention has a structural unit (I) of the general formula (I): [Chemical formula 1] wherein in the general formula (I), m and n are integers of 0 to 2, X1 is an ethylene or vinylene group, R1 and R2 are individually a hydrogen atom or a substituted or unsubstituted hydrocarbon group having 1 to 30 carbon atoms, and R3 is a group of the general formula (I-1) or (I-2), in which in the general formulae (I-1) and (I-2), R11 to R27 are individually a hydrogen atom; a halogen atom; a substituted or unsubstituted hydrocarbon group having 1 to 30 carbon atoms, which may have a linkage containing or not containing oxygen, sulfur, nitrogen and/or silicon atom(s); or a polar group, p and q in the general formula (I-1) are individually 0 or a positive integer, with the proviso that when both p and q are 0, R12 and R15, or R19 and R15 may be bonded to each other to form a carbon ring or heterocyclic ring, and the carbon ring or heterocyclic ring may be either a monocyclic structure or a polycyclic structure, and s in the general formula (I-2) is 0 or a positive integer.
摘要翻译：本发明提供双折射相对较低的开环聚降冰片烯，对双折射具有特定的波长依赖性，透明性和耐热性优异。 [解决方案]本发明的聚合物具有通式（I）的结构单元（I）：[化学式1]其中在通式（I）中，m和n为0〜2的整数，X 1是乙烯或亚乙烯基，R 1和R 2各自独立地为氢原子或取代或未取代的具有1至30个的烃基碳原子和R 3是通式（I-1）或（I-2）中的基团，其中在通式（I-1）和（I-2）中， R 11至R 27彼此独立地为氢原子; 卤素原子; 取代或未取代的具有1至30个碳原子的烃基，其可以具有含有或不含氧，硫，氮和/或硅原子的键; 或通式（I-1）中的极性基团p和q分别为0或正整数，条件是当p和q均为0时，R 12和R SUP > 15，或R 19和R 15可以彼此键合以形成碳环或杂环，并且碳环或杂环可以为单环结构或多环结构，通式（I-2）中的s为0或正整数。

8. 发明授权

US07157523B2 Ring-opened polynorbornenes 有权
公开(公告)号：US07157523B2
公开(公告)日：2007-01-02
申请号：US10534003
申请日：2003-11-12
申请人： Nobuyuki Miyaki , Yoshikazu Miyamoto , Souichi Yoshida , Yuichi Hashiguchi
发明人： Nobuyuki Miyaki , Yoshikazu Miyamoto , Souichi Yoshida , Yuichi Hashiguchi
IPC分类号： C08F8/04 , C08G61/08
CPC分类号： C08G61/06 , Y10S525/94
摘要： The disclosure is directed to a partially hydrogenated ring-opened polynorbornene and a process for making the same. The ring-opened polynorbornene is low in birefringence, high in wavelength dependency about birefringence and excellent in transparency and heat resistance.

9. 发明授权

US06846890B2 Norbornene derivative and norbornene polymer obtained therefrom through ring opening polymerization 失效
标题翻译：降冰片烯衍生物和通过开环聚合得到的降冰片烯聚合物
公开(公告)号：US06846890B2
公开(公告)日：2005-01-25
申请号：US10488096
申请日：2002-10-08
申请人： Nobuyuki Miyaki , Yoshikazu Miyamoto , Seiji Fukuhara , Toshihiro Ootsuki
发明人： Nobuyuki Miyaki , Yoshikazu Miyamoto , Seiji Fukuhara , Toshihiro Ootsuki
IPC分类号： C07C69/00 , C08G61/06 , C08G61/08
CPC分类号： C07C69/76 , C07C69/753 , C07C2602/42 , C07C2603/18 , C07C2603/24 , C07C2603/86 , C08G61/06 , C08G61/08
摘要： A novel norbornene derivative represented by a general formula (1m) shown below is provided. By conducting a ring opening polymerization of this norbornene derivative, or by performing a subsequent hydrogenation following the ring opening polymerization, a ring opening polymer or a hydrogenated product thereof with an excellent low birefringence can be obtained. [wherein, at least one of R1 to R4 is a group selected from the group consisting of groups represented by a general formula (1-1) shown below and groups represented by a general formula (1-2) shown below] [wherein, at least one of RA, RB and Z is a group represented by the formula —C(O)O—].
摘要翻译：提供由下述通式（1m）表示的新型降冰片烯衍生物。通过进行该降冰片烯衍生物的开环聚合，或通过在开环聚合后进行后续的氢化，可以得到具有优异的低双折射率的开环聚合物或其氢化物。[式中， 1〜R 4为选自下述通式（1-1）表示的基团和由下述通式（1-2）表示的基团的基团] [其中，至少一个的R A，R B和Z是由式-C（O）O-]表示的基团。

10. 发明申请

US20080177002A1 Thermoplastic Resin Composition, Optical Film, And Process For Producing Film 审中-公开
标题翻译：热塑性树脂组合物，光学膜及其制造方法
公开(公告)号：US20080177002A1
公开(公告)日：2008-07-24
申请号：US11813382
申请日：2005-12-27
申请人： Nobuyuki Miyaki , Yoshikazu Miyamoto , Naoyui Kawashima , Ichiro Kajiwara , Soichi Yoshida
发明人： Nobuyuki Miyaki , Yoshikazu Miyamoto , Naoyui Kawashima , Ichiro Kajiwara , Soichi Yoshida
IPC分类号： C08L45/00 , G02B1/04
CPC分类号： G02B5/3083 , C08J5/18 , C08J2333/24 , C08J2365/00 , C08L33/24 , C08L35/06 , C08L45/00 , C08L65/00 , C08L2666/04
摘要： The present invention is intended to provide a thermoplastic resin composition which is inhibited from suffering phase separation and from which an optical film having excellent transparency is readily obtained, an optical film containing the composition as a main component, a retardation film which is a film obtained by stretching the optical film and exhibits positive wavelength dependence and has a small coefficient of photoelasticity and transparency, and a process for producing the retardation film. The thermoplastic resin composition contains (A) a cycloolefin-based polymer and (B) a vinyl-based polymer having a unit represented by the following formula (II): wherein at least one of R1 to R4 is a group represented by the formula (III), the remainder of R1 to R4 if any, and R5 and R6 are each a hydrogen atom, a halogen atom, a substituted) hydrocarbon group which may have a linkage containing a hetero atom, or a polar group, R5 and R6 may be bonded to each other to form a monocyclic or polycyclic group which may have a hetero atom, or may be united to form a divalent hydrocarbon group and Y is a divalent hydrocarbon group.
摘要翻译：本发明旨在提供一种热塑性树脂组合物，其被抑制相分离，容易获得具有优异透明性的光学膜，含有该组合物作为主要成分的光学膜，作为获得的膜的相位差膜通过拉伸光学膜并呈现正的波长依赖性并且具有小的光弹性和透明度系数以及用于制造延迟膜的工艺。该热塑性树脂组合物含有（A）环烯烃系聚合物和（B）具有下述式（II）所示的单元的乙烯基系聚合物，其中，R 1〜R 4中的至少1个 4是由式（III）表示的基团，R 1至R 4的剩余部分（如果有的话）和R 5 R 6和R 6各自为氢原子，卤素原子，可具有含杂原子键的取代的烃基或极性基团R 5， / SUP>和R 6可以彼此键合以形成可以具有杂原子的单环或多环基团，或可以一起形成二价烃基，Y是二价烃基。

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