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    • 9. 发明授权
    • Hair dye composition
    • 染发剂组成
    • US06648924B2
    • 2003-11-18
    • US09825954
    • 2001-04-05
    • Hajime MiyabeKenichi MatsunagaYukihiro OhashiShintaro TotokiYoshinori Saito
    • Hajime MiyabeKenichi MatsunagaYukihiro OhashiShintaro TotokiYoshinori Saito
    • A61K713
    • A61Q5/10A61K8/492A61K8/4926
    • Provided is a hair dye composition comprising a direct dye (1): A—CR1═N—NR2—B X−  (1) [wherein, A represents a group (2) or (3): (in which, R3, R4 and R5 each independently represents a (substituted) C1-6 alkyl group, ring C may have a substituent or may by cyclocondensed with an aromatic ring, R6 and R7 each independently represents a (substituted) C1-6 alkyl group, or may be coupled to form a heterocycle together with the adjacent nitrogen atom, Z represents a (substituted) C1-4 divalent linear hydrocarbon group and ring D may be cyclocondensed with an aromatic ring), B represents a (substituted) aromatic group, R1 represents H or a (substituted) C1-6 alkyl group, R2 represents H or a (substituted) C1-6 alkyl group or a (substituted) aromatic group or may form a heterocycle together with the C atom of the aromatic ring B, and X− represents an anion]. This hair dye composition has markedly strong hair dyeing power and less color fade over time, and undergoes a smaller change in color tone of the dye even after storage.
    • 本发明提供包含直接染料(1)的染发剂组合物:[其中,A表示基团(2)或(3):(其中R 3,R 4和R 5各自独立地表示 (取代的)C 1-6烷基,环C可以具有取代基,或者可以与芳环环化,R 6和R 7各自独立地表示(取代的)C 1-6烷基,或者可以是 偶联以与相邻的氮原子一起形成杂环,Z表示(取代的)C 1-4的二价直链烃基,环D可以与芳环环化),B表示(取代的)芳基,R 1, 表示H或(取代的)C 1-6烷基,R 2表示H或(取代的)C 1-6烷基或(取代的)芳族基团,或者可以与芳环的C原子一起形成杂环 B和X'代表阴离子]。 这种染发剂组合物具有显着强的染发力,随着时间的推移颜色逐渐降低,即使在保存后也会使染料色调变小。
    • 10. 发明授权
    • Hair dye composition
    • 染发剂组成
    • US06616709B2
    • 2003-09-09
    • US09887473
    • 2001-06-25
    • Yukihiro OhashiHajime MiyabeKenichi MatsunagaShintaro TotokiYoshinori Saito
    • Yukihiro OhashiHajime MiyabeKenichi MatsunagaShintaro TotokiYoshinori Saito
    • A61K713
    • A61K8/492A61K8/4926A61K8/4946A61K8/498A61Q5/065
    • Provided is a hair dye composition containing a direct dye (1). This hair dye composition has markedly high hair dyeing power, has less color fade over time and undergoes a small change in the color tone of the dye after storage. wherein, ring A may represents a benzene ring which may have a substituent or the like, B represents an aryl or heterocyclic group, D represents N or CR4 (wherein R4 represents H or alkyl), E represents NR5, CR6R7 or CR6═CR7 (wherein R5 represents alkyl or the like, and R6 and R7 each represents H or alkyl) or, O or S, R1 represents alkyl or the like, and n stands for 0 or 1, with the proviso that at n=0, R2 and R5 form, when taken together with N—C—C, a heterocycle, or R2 is bonded to B, thereby forming a heterocycle and at n=1, R2 and R3 form, when taken together with C═D—N, a heterocycle, and X− represents an anion.
    • 提供含有直接染料(1)的染发剂组合物。 这种染发剂组合物具有显着高的染发力,随着时间的推移,颜色褪色较少,并且在保存后染料的色调发生小的变化。其中环A可以表示可以具有取代基等的苯环, B表示芳基或杂环基,D表示N或CR4(其中R4表示H或烷基),E表示NR5,CR6R7或CR6 = CR7(其中R5表示烷基等,R6和R7各自表示H或烷基) 或者,O或S,R 1表示烷基等,n表示0或1,条件是在n = 0时,R 2和R 5与NCC一起形成杂环,或R 2与B键合 ,从而形成杂环,并且当与C = DN一起与杂环一起时,n = 1,R2和R3形成,X表示阴离子。