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    • 5. 发明授权
    • Thermal cracking process for producing petrochemical products from
hydrocarbons
    • 从碳氢化合物生产石化产品的热裂解工艺
    • US4613426A
    • 1986-09-23
    • US625713
    • 1984-06-28
    • Toshiro OkamotoMichio Ohshima
    • Toshiro OkamotoMichio Ohshima
    • C10G9/36C07C4/04C10G9/38C10G47/00C10G47/22C10G47/32C10G69/02
    • C10G47/22
    • A thermal cracking process for producing petrochemical products from hydrocarbons which comprises the steps of: burning hydrocarbons with oxygen in the presence of steam to produce a hot gas of from 1300.degree. to 3000.degree. C. comprising steam; feeding a mixture of methane and hydrogen to the hot gas in such a way that a methane/hydrogen molar ratio is over 0.05; further feeding starting hydrocarbons to the hot gas comprising the methane, hydrogen and steam so that the starting hydrocarbons containing hydrocarbon components of higher boiling points are, respectively, fed to higher temperature zones; subjecting the starting hydrocarbons to thermal cracking while keeping the cracking temperature at 650.degree. to 1500.degree. C., the total residence time at 5 to 1000 milliseconds, the pressure at 2 to 100 bars, and the partial pressure of hydrogen, after thermal cracking of a hydrocarbon comprising hydrocarbon components whose boiling point exceeds 200.degree. C., at least 0.1 bar; and quenching the resulting reaction product.
    • 一种用于从烃生产石油化学产品的热裂解方法,其包括以下步骤:在蒸汽存在下用氧气燃烧烃,以产生含有蒸汽的1300℃至3000℃的热气体; 以甲烷/氢摩尔比超过0.05的方式将甲烷和氢气的混合物供给到热气体中; 进一步将起始烃进料到包括甲烷,氢气和蒸汽的热气体中,使得含有较高沸点的烃组分的起始烃分别进料到较高温度区; 将起始烃进行热裂解,同时保持裂化温度在650〜1500℃,总停留时间为5〜1000毫秒,压力为2〜100巴,氢分压在热裂化后 包含沸点超过200℃,至少0.1巴的烃组分的烃; 并淬灭所得反应产物。
    • 8. 发明授权
    • Thermal cracking process for selectively producing olefins and aromatic
hydrocarbons from hydrocarbons
    • 从烃中选择性生产烯烃和芳烃的热裂解方法
    • US4655904A
    • 1987-04-07
    • US621428
    • 1984-06-18
    • Toshiro OkamotoMichio Ohshima
    • Toshiro OkamotoMichio Ohshima
    • C10G9/00C07C1/00C07C4/04C07C11/02C07C15/02C07C67/00C10G9/38
    • C10G9/38
    • A process for selectively producing olefins and aromatic hydrocarbons by thermal cracking of hydrocarbons which comprises the steps of: burning hydrocarbons with oxygen in the presence of steam to produce a hot gas of from 1300.degree. to 3000.degree. C. comprising steam; feeding a heavy hydrocarbon to the hot gas to thermally crack the heavy hydrocarbon under conditions of a temperature not lower than 1000.degree. C., a pressure not higher than 100 kg/cm.sup.2 g, and a residence time of from 5 to 20 milliseconds; further feeding a light hydrocarbon downstream of the feed of the heavy hydrocarbon in such a way that a light hydrocarbon with a lower boiling point is fed at a lower temperature side downstream of the feed of the heavy hydrocarbon, thereby thermally cracking the light hydrocarbon under conditions of a reactor outlet temperature at not lower than 650.degree. C., a pressure at not higher than 100 kg/cm.sup.2 g, and a residence time at 5 to 1000 milliseconds; and quenching the resulting reaction product.
    • 一种通过碳氢化合物热裂解选择性生产烯烃和芳烃的方法,包括以下步骤:在蒸汽存在下用氧气燃烧烃,以产生含有蒸汽的1300〜3000℃的热气体; 向热气体中加入重质烃,在不低于1000℃,压力不高于100kg / cm2g,停留时间为5至20毫秒的条件下热裂解重质烃; 进一步向重质烃进料下游供给轻质烃,使得在较低温度下一侧加入较低沸点的轻烃,在重烃进料下游,从而在轻质烃条件下 反应器出口温度不低于650℃,压力不高于100kg / cm2g,停留时间为5至1000毫秒; 并淬灭所得反应产物。