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1. 发明授权

US06376160B1 Protective epoxy overcoat for photographic elements 失效
标题翻译：用于照相元件的防护环氧涂层
公开(公告)号：US06376160B1
公开(公告)日：2002-04-23
申请号：US09699789
申请日：2000-10-30
申请人： Yongcai Wang , Kevin M. O'Connor , Melvin M. Kestner , James L. Bello
发明人： Yongcai Wang , Kevin M. O'Connor , Melvin M. Kestner , James L. Bello
IPC分类号： G03C1815
CPC分类号： G03C1/7614 , G03C2001/7635 , G03C2200/36 , Y10S430/162
摘要： The present invention relates to photographic elements having a protective overcoat that resists fingerprints, common stains, and spills. The overcoat comprises an epoxy material, an acid polymer, and a water-soluble hydrophilic binder. In one embodiment, a photographic element includes a support, at least one silver halide emulsion layer superposed on the support and a processing-solution-permeable overcoat overlying the silver halide emulsion layer that becomes water-resistant in the final product without requiring lamination or fusing. The present invention is also directed to a method of making a print involving developing the photographic element.
摘要翻译：本发明涉及具有防护指纹，常见污渍和溢出物的保护外套的照相元件。外涂层包含环氧材料，酸性聚合物和水溶性亲水性粘合剂。在一个实施方案中，照相元件包括载体，叠加在载体上的至少一个卤化银乳剂层和覆盖卤化银乳剂层的加工溶液渗透性外涂层，其在最终产品中变得耐水，而不需要层压或熔融。本发明还涉及一种制作涉及显影照相元件的印刷品的方法。

2. 发明授权

US06436617B1 Protective epoxy overcoat for imaging elements 失效
标题翻译：用于成像元件的保护性环氧树脂涂层
公开(公告)号：US06436617B1
公开(公告)日：2002-08-20
申请号：US09699866
申请日：2000-10-30
申请人： Yongcai Wang , Kevin M. O'Connor , Melvin M. Kestner , James L. Bello
发明人： Yongcai Wang , Kevin M. O'Connor , Melvin M. Kestner , James L. Bello
IPC分类号： G03C176
CPC分类号： G03C1/7614 , G03C2200/36 , Y10S430/162
摘要： The present invention relates to photographic elements having a protective overcoat that resists fingerprints, common stains, and spills. The overcoat comprises an epoxy material, an acid polymer, a water-soluble hydrophilic binder and an associative thickener. In one embodiment, a photographic element includes a support, at least one silver halide emulsion layer superposed on the support and a processing-solution-permeable overcoat overlying the silver halide emulsion layer that becomes water-resistant in the final product without requiring lamination or fusing. The present invention is also directed to a method of making a print involving developing the photographic element.
摘要翻译：本发明涉及具有防护指纹，常见污渍和溢出物的保护外套的照相元件。外涂层包含环氧树脂材料，酸聚合物，水溶性亲水性粘合剂和缔合增稠剂。在一个实施方案中，照相元件包括载体，叠加在载体上的至少一个卤化银乳剂层和覆盖卤化银乳剂层的加工溶液渗透性外涂层，其在最终产品中变得耐水，而不需要层压或熔融。本发明还涉及一种制作涉及显影照相元件的印刷品的方法。

3. 发明授权

US5595862A Photographic elements containing matte particles of bimodal size distribution 失效
标题翻译：含有双峰尺寸分布的哑光颗粒的摄影元素
公开(公告)号：US5595862A
公开(公告)日：1997-01-21
申请号：US533625
申请日：1995-09-25
申请人： Alfred B. Fant , Yongcai Wang , Dennis E. Smith , Melvin M. Kestner , Rudolf D. Steinmetz
发明人： Alfred B. Fant , Yongcai Wang , Dennis E. Smith , Melvin M. Kestner , Rudolf D. Steinmetz
IPC分类号： G03C1/00 , G03C1/32 , G03C1/76 , G03C1/95 , G03C3/00
CPC分类号： G03C1/95 , G03C1/32 , G03C1/7614 , G03C1/85 , G03C2001/03594 , G03C2001/7621 , G03C2200/17 , G03C2200/42 , Y10S430/151 , Y10S430/162
摘要： In accordance with the present invention, a photographic element comprises a support, at least one light-sensitive layer, and a protective overcoat comprising a hydrophilic binder and permanent matte particles, the permanent matte particles comprising a polymer of methyl methacrylate and having a size distribution of a first and a second mode, with the first mode being composed of particles having a mean particle size of from 0.2 to 1.2 micrometers in a coating weight of from 10 to 200 mg/m.sup.2 and the second mode having a mean particle size of from 1.5 to 10 micrometers in a coating weight of from 5 to 150 mg/m.sup.2, the total coating weight of the particle of the first and the second modes being greater than 100 mg/m.sup.2.
摘要翻译：根据本发明，照相元件包括载体，至少一个感光层和包含亲水性粘合剂和永久性无光泽颗粒的保护性外涂层，所述永久性无光泽颗粒包含甲基丙烯酸甲酯的聚合物并具有尺寸分布第一模式由平均粒径为0.2至1.2微米的颗粒组成，涂层重量为10至200mg / m 2，第二模式的平均粒径为 1.5至10微米，涂层重量为5至150mg / m 2，第一和第二模式的颗粒的总涂层重量大于100mg / m 2。

4. 发明授权

US5550011A Photographic elements containing matte particles of bimodal size distribution 失效
标题翻译：含有双峰尺寸分布的哑光颗粒的摄影元素
公开(公告)号：US5550011A
公开(公告)日：1996-08-27
申请号：US381803
申请日：1995-02-01
申请人： Alfred B. Fant , Yongcai Wang , Dennis E. Smith , Melvin M. Kestner , Gary W. Visconte
发明人： Alfred B. Fant , Yongcai Wang , Dennis E. Smith , Melvin M. Kestner , Gary W. Visconte
IPC分类号： G03C1/76 , G03C1/95 , G03C1/00 , G03C3/00
CPC分类号： G03C1/95 , G03C1/32 , G03C1/7614 , G03C1/85 , G03C2001/03594 , G03C2001/7621 , G03C2200/17 , G03C2200/42 , Y10S430/151 , Y10S430/162
摘要： An imaging element comprising a support, at least one hydrophilic light-sensitive layer and at least one protective overcoat layer containing a binder and permanent matte particles, the permanent matte particles having a size distribution of a first mode and a second mode, the first mode being organic particles having a median size of from 0.2 to 1.2 micrometers in a coating weight of from 10 to 200 mg/m.sup.2, the said second mode being particles having a mean particle size of from 1.5 to 10 micrometers in a coating weight of from 25 to 150 mg/m.sup.2, the total coating weight of particles of the first and second modes being greater than 100 mg/m.sup.2.
摘要翻译：一种成像元件，包括支撑体，至少一个亲水感光层和至少一个包含粘合剂和永久性哑光颗粒的保护性外涂层，所述永久性哑光颗粒具有第一模式和第二模式的尺寸分布，所述第一模式是中等尺寸为0.2-1.2微米的有机颗粒，涂层重量为10-200mg / m 2，所述第二模式是平均粒度为1.5至10微米的颗粒，涂层重量为25 至150mg / m 2，第一和第二模式的颗粒的总涂层重量大于100mg / m 2。

5. 发明授权

US5393650A Pressure sensitivity relief for photographic products 失效
标题翻译：摄影产品的压力敏感度
公开(公告)号：US5393650A
公开(公告)日：1995-02-28
申请号：US265997
申请日：1994-06-27
申请人： Pranab Bagchi , Melvin M. Kestner
发明人： Pranab Bagchi , Melvin M. Kestner
IPC分类号： G03C1/04 , G03C1/043 , G03C1/38 , G03C1/76 , G03C1/95
CPC分类号： G03C1/95 , G03C1/38
摘要： This invention describes the use of surfactants of the following types:Type A--Surfactant comprising 6 to 22 carbon atom hydrophobic tail with one or more attached hydrophilic chains comprising at least 8 oxyethylene and/or glycidyl ether groups that may or may not be terminated with a negative charge such as a sulfate group.Type B--Block oligomeric surfactants comprising hydrophobic polyoxypropylene blocks (A) and hydrophilic polyoxyethylene blocks (B) joined in the manner of A--B--A, B--A--B, A--B, (A--B.sub.n .tbd.G.tbd.(B--A).sub.n, or (B--A).sub.n .tbd.G(A--B).sub.n, where G is a connective organic moiety and n is between 1 and 3.Type C--Sugar surfactants, comprising between one to three 6 to 22 carbon atom hydrophobic tail with one or more attached hydrophilic mono or oligosaccharidic chains that may or may not be terminated by a negatively charged group such as a sulfate group.in combination with gelatin-grafted-polymer particles to obtain aggregation and defect free photographic multilayer coatings that are considerably low in pressure sensitivity.
摘要翻译：本发明描述了以下类型的表面活性剂的用途：A型表面活性剂，其包含6至22个碳原子的疏水尾部，其具有一个或多个附着的亲水链，其包含至少8个氧化乙烯和/或缩水甘油醚基团，其可以或可以不以负电荷如硫酸根组。包含以ABA，BAB，AB，（A-Bn 3BOND G 3BOND（BA）n或（BA）n 3BOND G）的方式连接的疏水性聚氧丙烯嵌段（A）和亲水性聚氧乙烯嵌段（B）的B型低聚表面活性剂（AB）n，其中G是连接性有机部分，n在1和3之间。C型糖表面活性剂，包含1至3个6至22个碳原子的疏水尾部与一个或多个连接的亲水单糖或寡糖链，或者可能不被带负电荷的基团如硫酸根基团终止，与明胶接枝聚合物颗粒组合以获得相当低的压敏度的聚集和无缺陷的照相多层涂层。

6. 发明授权

US5962210A Color paper with improved wet abrasion sensitivity 失效
标题翻译：彩色纸具有改善的湿磨损敏感性
公开(公告)号：US5962210A
公开(公告)日：1999-10-05
申请号：US5861
申请日：1998-01-12
申请人： Paul T. Hahm , Alberto M. Martinez , Melvin M. Kestner , Eric L. Bell , Walter H. Isaac
发明人： Paul T. Hahm , Alberto M. Martinez , Melvin M. Kestner , Eric L. Bell , Walter H. Isaac
IPC分类号： G03C1/035 , G03C1/09 , G03C1/34
CPC分类号： G03C1/09 , G03C1/035
摘要： The invention relates to a photographic emulsion comprising silver iodochloride grains, said grains further comprising iridium, said grains chemically sensitized with gold in an amount of between 120 and 200 mg gold per silver mole and sulfur in an amount between 0.1 and 20 mg sulfur per silver mole, 1-(3-acetamidophenyl)-5-mercaptotetrazole, 1-phenyl-5-mercaptotetrazole, and a disulfide compound represented by the following formula: ##STR1## wherein X is independently --O--, --NH-- or --NR--, where R is a substituent;m and r are independently 0, 1 or 2;X is --H or a cationic species;Ar is an aromatic group; andL is a linking group, where p is 0 or 1.
摘要翻译：本发明涉及一种包含碘氯化银颗粒的照相乳剂，所述颗粒还包含铱，所述颗粒用金对金银进行化学增感，金量为每个银摩尔为120至200mg金，硫含量为0.1至20mg硫/银摩尔，1-（3-乙酰氨基苯基）-5-巯基四唑，1-苯基-5-巯基四唑和由下式表示的二硫化物：其中X独立地是-O - ， - NH-或-NR-，其中R 是取代基; m和r独立地为0,1或2; X是-H或阳离子物质; Ar是芳族基团; L为连接基团，p为0或1。

7. 发明授权

US5514530A Photographic elements comprising 2-phenylcarbamoyl-1-naphthol image-modifying couplers yielding dyes resistant to crystallization and reduction 失效
公开(公告)号：US5514530A
公开(公告)日：1996-05-07
申请号：US98692
申请日：1993-07-28
申请人： Paul B. Merkel , Jerrold N. Poslusny , Melvin M. Kestner , Ronald E. Leone , David A. Steele
发明人： Paul B. Merkel , Jerrold N. Poslusny , Melvin M. Kestner , Ronald E. Leone , David A. Steele
IPC分类号： G03C7/00 , C07D257/04 , G03C7/305 , G03C7/333 , G03C7/34
CPC分类号： C07D257/04 , G03C7/30523 , Y10S430/158
摘要： Photographic elements comprising certain 2-phenylcarbamoyl-1-naphthol image-modifying couplers exhibit proper hue, a resistance to dye crystallization, and a resistance to leuco cyan dye formation. Such couplers can be utilized for their image-modifying effect and can contribute substantially to the overall dye density of an image.

8. 发明授权

US5506094A Photographic elements comprising 2-phenylcarbamoyl-1-naphthol image-modifying couplers yielding dyes resistant to crystallization and reduction 失效
标题翻译：包含2-苯基氨基甲酰基-1-萘酚图像改性成色剂的摄影元件产生耐结晶和还原的染料
公开(公告)号：US5506094A
公开(公告)日：1996-04-09
申请号：US098552
申请日：1993-07-28
申请人： Paul B. Merkel , Jerrold N. Poslusny , Melvin M. Kestner , Ronald E. Leone , David A. Steele
发明人： Paul B. Merkel , Jerrold N. Poslusny , Melvin M. Kestner , Ronald E. Leone , David A. Steele
IPC分类号： G03C7/00 , G03C7/305 , G03C7/34
CPC分类号： G03C7/30523 , Y10S430/158
摘要： Photographic elements comprising certain 2-phenylcarbamoyl-1-naphthol image-modifying couplers exhibit proper hue, a resistance to dye crystallization, and a resistance to leuco cyan dye formation. Such couplers can be utilized for their image-modifying effect and can contribute substantially to the overall dye density of an image.
摘要翻译：包含某些2-苯基氨基甲酰基-1-萘酚图像改性成色剂的照相元件表现出适当的色调，抗染料结晶性和对无色青色染料形成的抗性。这样的成色剂可以用于其影像修饰效果，并且可以显着地有助于图像的整体染料密度。

9. 发明授权

US5451496A Color photographic materials and methods containing DIR or DIAR couplers and phenolic coupler solvents 失效
标题翻译：含有DIR或DIAR成色剂和酚类成色剂溶剂的彩色照相材料和方法
公开(公告)号：US5451496A
公开(公告)日：1995-09-19
申请号：US218855
申请日：1994-03-28
申请人： Paul B. Merkel , Melvin M. Kestner , Paul L. Zengerle
发明人： Paul B. Merkel , Melvin M. Kestner , Paul L. Zengerle
IPC分类号： G03C7/305 , G03C7/34 , G03C7/388
CPC分类号： G03C7/3885 , G03C7/305 , Y10S430/158
摘要： Color photographic materials comprise a substrate bearing a silver halide emulsion and a coupler composition comprising (a) a 2-phenylcarbamoyl-1-naphthol compound selected from the group consisting of development inhibitor releasing couplers and timed development inhibiting releasing couplers, and (b) a phenolic coupler solvent. The phenolic coupler solvent is employed to reduce dye density changes and/or dye hue changes resulting from cold storage of the photographic materials.
摘要翻译：彩色照相材料包括含有卤化银乳剂的底物和成色剂组合物，其包含（a）选自显影抑制剂释放成色剂和定时显影抑制释放成色剂的2-苯基氨基甲酰基-1-萘酚化合物，和（b）酚醛成色剂溶剂。酚类成色剂溶剂用于减少由照相材料的冷藏造成的染料密度变化和/或染料色调变化。

10. 发明授权

US5426020A Pressure sensitivity relief for photographic products 失效
标题翻译：摄影产品的压力敏感度
公开(公告)号：US5426020A
公开(公告)日：1995-06-20
申请号：US114535
申请日：1993-08-31
申请人： Pranab Bagchi , Melvin M. Kestner
发明人： Pranab Bagchi , Melvin M. Kestner
IPC分类号： G03C1/04 , G03C1/043 , G03C1/38 , G03C1/76 , G03C1/95 , G03C1/77
CPC分类号： G03C1/95 , G03C1/38
摘要： This invention describes the use of surfactants of the following types:Type A--Surfactant comprising 6 to 22 carbon atom hydrophobic tail with one or more attached hydrophilic chains comprising at least 8 oxyethylene and/or glycidyl ether groups that may or may not be terminated with a negative charge such as a sulfate group,Type B--Block oligomeric surfactants comprising hydrophobic polyoxypropylene blocks (A) and hydrophilic polyoxyethylene blocks (B) joined in the manner of A--B--A, B--A--B, A--B, (A--B.sub.n .tbd.G.tbd.(B--A).sub.n, or (B--A).sub.n .tbd.G(A--B).sub.n, where G is a connective organic moiety and n is between 1 and 3,Type C--Sugar surfactants, comprising between one to three 6 to 22 carbon atom hydrophobic tail with one or more attached hydrophilic mono or oligosaccharidic chains that may or may not be terminated by a negatively charged group such as a sulfate group.in combination with gelatin-grafted-polymer particles to obtain aggregation and defect free photographic multilayer coatings that are considerably low in pressure sensitivity.
摘要翻译：本发明描述了以下类型的表面活性剂的用途：A型表面活性剂，其包含6至22个碳原子的疏水尾部，其具有一个或多个附着的亲水链，其包含至少8个氧化乙烯和/或缩水甘油醚基团，其可以或可以不以包含疏水性聚氧丙烯嵌段（A）和亲水性聚氧乙烯嵌段（B）的B型嵌段低聚表面活性剂如ABA，BAB，AB，（A-Bn 3BOND G 3BOND（BA） n或（BA）n 3BOND G（AB）n，其中G是连接性有机部分，n在1和3之间，C型糖表面活性剂包含1至3个6至22个碳原子的疏水尾部与1个或更多附着的亲水单糖或寡糖链，其可以或可以不被带负电荷的基团如硫酸根基团终止，与明胶接枝聚合物颗粒组合以获得聚集和无缺陷的照相多层涂层 at压力敏感度相当低。

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