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    • 4. 发明申请
    • HOLLOW FINE PARTICLES, PRODUCTION PROCESS THEREOF, COATING COMPOSITION AND ARTICLE HAVING COATING FILM FORMED
    • 中空精细颗粒,其生产工艺,涂料组合物和形成涂膜的物品
    • US20100000443A1
    • 2010-01-07
    • US12560020
    • 2009-09-15
    • Yohei KAWAITakashige Yoneda
    • Yohei KAWAITakashige Yoneda
    • C09D1/00
    • C09C1/3045C01B33/18C01P2004/34C01P2004/84C08K3/10C08K3/36C09D7/70
    • To provide hollow fine particles with which a coating film having a high antireflection effect and high film strength can be obtained, a production process thereof, a coating composition with which a coating film having a high antireflection effect and high film strength can be formed, and an article which can maintain a high antireflection effect for a long period of time.Hollow fine particles containing SiO2 as the main component and containing other metal, wherein the amount of said other metal (as calculated as oxide) is from 0.2 to 8 parts by mass based on 100 parts by mass of SiO2; a coating composition containing the hollow fine particles and a dispersion medium; an article having a coating film comprising the coating composition formed on a substrate; and a process for producing hollow fine particles, which comprises (a) a step of, in a dispersion containing a SiO2 precursor material, at least one compound containing other metal, selected from the group consisting of a metal chelate compound, an organic tin compound, a metal alcoholate and a metal fatty acid salt, and core fine particles, precipitating a shell containing SiO2 as the main component and containing other metal on the surface of each core fine particle to obtain core/shell particles, and (b) a step of dissolving or decomposing the core fine particles of the core/shell fine particles.
    • 为了提供可以获得具有高抗反射效果和高膜强度的涂膜的中空微粒,其制备方法可以形成具有高抗反射效果和高膜强度的涂膜的涂料组合物,以及 可以长时间保持高抗反射效果的物品。 以SiO 2为主要成分并含有其他金属的中空微粒子,其中相对于100质量份的SiO 2,所述其他金属的量(按氧化物计算)为0.2〜8质量份; 含有中空微粒和分散介质的涂料组合物; 具有包含形成在基材上的涂料组合物的涂膜的物品; 和一种制备中空微粒的方法,其包括(a)在含有SiO 2前体材料的分散液中至少含有一种选自金属螯合物,有机锡化合物, ,金属醇化物和金属脂肪酸盐,以及核心微粒,以含有SiO 2作为主要成分的壳体沉淀并在每个核心微粒的表面上含有其它金属以获得核/壳颗粒,和(b)步骤 溶解或分解芯/壳微粒的核心微粒。