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    • 4. 发明授权
    • Plasma enhanced CVD deposition of tungsten and tungsten compounds
    • 等离子体增强钨和钨化合物的CVD沉积
    • US06037263A
    • 2000-03-14
    • US186391
    • 1998-11-05
    • Liang-Tung Chang
    • Liang-Tung Chang
    • H01L21/285H01L21/768H01L21/00
    • H01L21/76846H01L21/28518H01L21/76843
    • A method for plasma assisted CVD deposition of tungsten and of tungsten compounds is described wherein a plasma containing a high density of active hydrogen species is maintained to scavenge fluorine and fluoride species formed by the decomposition of the tungsten precursor WF.sub.6. The activated hydrogen species also assist in the breaking of W--F bonds, thereby facilitating the decompoition process and forming high density, high conductivity, fluoride free conductive films of tungsten and of tungsten compounds. The ability to form such fluoride free tungsten films with the assistance of activated hydrogen species, permits the deposition of tungsten directly onto gate oxides thereby enabling the formation of tungsten gate electrodes without underlying polysilicon. Low conductivity tungsten contacts including in-situ formed tungsten compound barrier layers may also be formed by this process.
    • 描述了一种用于钨和钨化合物的等离子体辅助CVD沉积的方法,其中保持含有高密度活性氢物质的等离子体,以清除钨前体WF6分解形成的氟和氟化物物质。 活化的氢物质也有助于断裂W-F键,从而促进了分解过程,并形成了钨和钨化合物的高密度,高导电性,无氟化物导电膜。 借助于活化的氢物质形成这种无氟化钨膜的能力允许钨直接沉积在栅极氧化物上,从而能够形成不含底层多晶硅的钨栅电极。 也可以通过该方法形成包括原位形成的钨化合物阻挡层的低导电性钨触点。
    • 5. 发明授权
    • Method of manufacturing inter-metal dielectric layers for semiconductor devices
    • 制造用于半导体器件的金属间介电层的方法
    • US06239034B1
    • 2001-05-29
    • US09184344
    • 1998-11-02
    • Fu-Liang YangLiang-Tung Chang
    • Fu-Liang YangLiang-Tung Chang
    • H01L21311
    • H01L21/316H01L21/31051H01L21/31612H01L21/76801H01L21/76837
    • A method of manufacturing an inter-metal level dielectric layer for a semiconductor device. The method includes forming spaced conductive lines. Next, a first conformal silicon oxide film (barrier layer) is formed over the spaced conductive lines. Gaps or valleys are between the metal lines covered by the barrier layer. A novel first “gap filling” spin-on-glass layer is formed over the first silicon oxide layer. In a critical step, the first SOG layer is heated to reflow thereby flowing all the first spin-on-glass layer from over the metal lines and leaving all of the first SOG layer in the gaps. Subsequently, a second silicon oxide layer is deposited over the first silicon oxide layer and over the first spin-on-glass layer only in the gaps. A second spin-on-glass layer is then formed over the second silicon oxide layer. An etchback is performed by etching back and removing the entire second spin on glass layer and portions the second silicon oxide layer. Lastly, an insulating cap layer of silicon oxide or silicon nitride is formed over the second silicon oxide layer.
    • 一种制造用于半导体器件的金属间介电层的方法。 该方法包括形成间隔开的导线。 接下来,在隔开的导线上形成第一共形氧化硅膜(阻挡层)。 间隙或谷在被阻挡层覆盖的金属线之间。 在第一氧化硅层上形成新的第一“间隙填充”旋涂玻璃层。 在关键步骤中,第一SOG层被加热以回流,从而使所有第一旋涂玻璃层从金属线上方流出并将所有第一SOG层留在间隙中。 随后,第二氧化硅层仅在间隙中沉积在第一氧化硅层上并且在第一旋涂玻璃层上方。 然后在第二氧化硅层上形成第二自旋玻璃层。 通过蚀刻回去并去除玻璃层上的整个第二自旋并且将第二氧化硅层部分来进行回蚀。 最后,在第二氧化硅层上形成氧化硅或氮化硅的绝缘盖层。
    • 6. 发明授权
    • In-situ low wafer temperature oxidized gas plasma surface treatment
process
    • 原位低晶圆温度氧化气体等离子体表面处理工艺
    • US5858882A
    • 1999-01-12
    • US822664
    • 1997-03-24
    • Liang-Tung ChangChih-Cherng Liao
    • Liang-Tung ChangChih-Cherng Liao
    • H01L21/3105H01L21/768H01L21/283
    • H01L21/76801H01L21/3105H01L21/76826
    • A method of forming an interlevel dielectric layer without peeling or cracking in the fabrication of an integrated circuit device is described. Semiconductor device structures are provided in and on a semiconductor substrate. An insulating layer is provided overlying the semiconductor device structures and a first conducting layer is provided overlying the insulating layer and extending down through the insulating layer to contact one of the semiconductor device structures. A first dielectric layer is deposited overlying the first conducting layer. A spin-on-glass layer is coated over the first dielectric layer and then etched back wherein a polymer builds up on the spin-on-glass surface. The spin-on-glass layer is treated with an oxygen plasma treatment wherein the treatment neutralizes the polymer buildup and prevents cracking and peeling of the spin-on-glass layer. A TEOS layer is deposited overlying the spin-on-glass layer to complete the interlevel dielectric layer. A via opening is etched through the interlevel dielectric layer to the first conducting layer. A second conducting layer is deposited within the via opening and patterned to complete the fabrication of the integrated circuit device.
    • 描述了在集成电路器件的制造中形成层间绝缘层而不剥离或破裂的方法。 半导体器件结构设置在半导体衬底中和半导体衬底上。 设置覆盖半导体器件结构的绝缘层,并且覆盖绝缘层并向下延伸穿过绝缘层以接触半导体器件结构之一的第一导电层。 第一介电层沉积在第一导电层上。 旋涂玻璃层涂覆在第一介电层上,然后回蚀,其中聚合物积聚在玻璃上玻璃表面上。 旋涂玻璃层用氧等离子体处理,其中处理中和聚合物积聚并防止旋涂玻璃层的开裂和剥离。 TEOS层沉积在旋涂玻璃层上以完成层间电介质层。 通孔开口通过层间电介质层蚀刻到第一导电层。 第二导电层沉积在通孔开口内并图案化以完成集成电路器件的制造。