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    • 1. 发明申请
    • Methods for elimination of arsenic based defects
    • 消除基于砷的缺陷的方法
    • US20060030095A1
    • 2006-02-09
    • US10913214
    • 2004-08-06
    • Yin-Min GohSimon ChooiTeck LimVincent SihChian SinPing EeZainab IsmailCher Chua
    • Yin-Min GohSimon ChooiTeck LimVincent SihChian SinPing EeZainab IsmailCher Chua
    • H01L21/8238H01L21/4763
    • H01L21/02057H01L21/02068H01L21/28518H01L21/76237H01L21/823814H01L21/823878H01L29/665H01L29/7833
    • Methods of preparing conductive regions such as source/drain regions for silicidation procedures, has been developed. The methods feature removal of native oxide as well as removal of deposited arsenic based defects from conductive surfaces prior to deposition of a metal component of subsequently formed metal silicide regions. Arsenic ions implanted for N type source/drain regions are also implanted into insulator regions such as insulator filled shallow trench isolation regions. A hydrofluoric acid cycle used as a component of the pre-silicidation preparation procedure can release arsenic from the shallow trench isolation regions in the form of arsenic based defects, which in turn can re-deposit on the surface of source/drain region. Therefore pre-silicidation preparation treatments described in this invention feature removal of both native oxide and arsenic based defects from conductive surfaces prior to metal silicide formation. Methods include wet etch procedures featuring hydrofluoric acid and hydrogen peroxide, as well as spin dry and dry etch procedures both employed post hydrofluoric acid treatment to remove re-deposited arsenic based defects.
    • 已经开发了制备用于硅化程序的源极/漏极区域的导电区域的方法。 该方法在沉积随后形成的金属硅化物区域的金属组分之前,特征在于去除自然氧化物以及从导电表面去除沉积的基于砷的缺陷。 注入用于N型源极/漏极区域的砷离子也被注入绝缘体区域,例如绝缘体填充的浅沟槽隔离区域。 用作预硅化物制备方法的组分的氢氟酸循环可以以基于砷的缺陷的形式从浅沟槽隔离区释放砷,其又可以沉积在源极/漏极区的表面上。 因此,本发明中描述的预硅化制备处理在金属硅化物形成之前特征是从导电表面除去天然氧化物和砷的缺陷。 方法包括以氢氟酸和过氧化氢为特征的湿法蚀刻程序,以及在氢氟酸处理之后采用的旋转干燥和干蚀刻方法,以去除重新沉积的基于砷的缺陷。