专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明授权

US4717756A Process for preparing methacrylate polymer 失效
标题翻译：制备甲基丙烯酸酯聚合物的方法
公开(公告)号：US4717756A
公开(公告)日：1988-01-05
申请号：US46983
申请日：1987-04-06
申请人： Yasuyuki Kato , Masahiro Yuyama , Masahiko Moritani , Yukio Yasunori
发明人： Yasuyuki Kato , Masahiro Yuyama , Masahiko Moritani , Yukio Yasunori
IPC分类号： C08F4/00 , C08F2/02 , C08F4/10 , C08F4/28 , C08F4/32 , C08F4/40 , C08F4/42 , C08F4/50 , C08F20/00 , C08F20/10 , C08F20/12 , C08F20/14 , C08F220/10 , C08F220/14 , C08F220/20 , C08F265/06
CPC分类号： C08F220/14 , C08F20/14 , C08F265/06
摘要： A polymerization can be carried out rapidly by polymerizing a methacrylate ester or a mixture of unsaturated monomers comprising the methacrylate ester as a main component in the presence of (1) a hydroperoxide polymerization initiator, (2) a reductant containing sulfur in a molecule, (3) a hydrogen halogenide salt of amine or a quarternary halogenide and (4) a copper-containing compound.
摘要翻译： PCT No.PCT / JP86 / 00400 Sec。 371日期1987年4月6日 102（e）日期1987年4月6日PCT申请日1986年8月4日PCT公布。公开号WO87 / 00842 日本1987年2月12日。聚合可以通过在（1）氢过氧化物聚合引发剂存在下，使甲基丙烯酸酯或包含甲基丙烯酸酯作为主要成分的不饱和单体的混合物进行聚合，（2）还原剂（3）胺或卤化四氯化氢的卤化氢盐和（4）含铜化合物。

2. 发明授权

US4885125A Method for in-mold polymerization of unsaturated compound 失效
标题翻译：不饱和化合物的模内聚合方法
公开(公告)号：US4885125A
公开(公告)日：1989-12-05
申请号：US900974
申请日：1986-08-27
申请人： Yasuyuki Kato , Masahiro Yuyama , Masahiko Moritani , Yukio Yasunori
发明人： Yasuyuki Kato , Masahiro Yuyama , Masahiko Moritani , Yukio Yasunori
IPC分类号： C08G63/00 , B29C39/00 , B29C39/42 , B29C39/44 , B29C67/24 , B29K33/04 , B29L11/00 , C08F2/00 , C08F2/02 , C08F2/38 , C08F2/44 , C08F4/28 , C08F4/34 , C08F4/40 , C08F18/00 , C08F20/00 , C08F20/10 , C08F20/12 , C08F20/18 , C08G63/66 , C08K5/17 , C08L33/10
CPC分类号： B29C67/246 , C08F2/02 , C08F2/38 , C08F20/10 , C08F20/12
摘要： An unsaturated compound having a vinyl or vinylidene group is rapidly in-mold polymerized by mixing the unsaturated compound containing a polymerization initiator and the unsaturated compound containing a polymerization accelerator, pouring the mixture into a mold cavity and polymerizing the monomer for not longer than 30 minutes.
摘要翻译：具有乙烯基或亚乙烯基的不饱和化合物通过混合含有聚合引发剂的不饱和化合物和含有聚合促进剂的不饱和化合物而快速模内聚合，将混合物倒入模腔中并使单体聚合不超过30分钟。

3. 发明授权

US4859750A Method for the production of polymethyl methacrylate 失效
标题翻译：生产聚甲基丙烯酸甲酯的方法
公开(公告)号：US4859750A
公开(公告)日：1989-08-22
申请号：US898514
申请日：1986-08-21
申请人： Yasuyuki Kato , Masahiro Yuyama , Masahiko Moritani , Yukio Yasunori
发明人： Yasuyuki Kato , Masahiro Yuyama , Masahiko Moritani , Yukio Yasunori
IPC分类号： C08F4/00 , C08F2/02 , C08F4/10 , C08F4/28 , C08F4/32 , C08F4/40 , C08F4/42 , C08F4/50 , C08F20/00 , C08F20/10 , C08F20/12 , C08F20/14 , C08F220/10 , C08F220/14 , C08F220/20 , C08F265/06
CPC分类号： C08F220/14 , C08F20/14 , C08F265/06
摘要： Improved method for the production of a polymer of a monofunctional (unsaturated) monomer, particularly polymethyl methacrylate, by a rapid crosslinking polymerization, which comprises polymerizing a mixture of a monofunctional (unsaturated) monomers, selected from methyl methacrylate and a monomer mixture comprising predominantly methyl methacrylate which may partially contain a polymer of the monomer (i.e. a syrup of the monomer or monomer mixture), and a polyfunctional (unsaturated) monomer in the presence of (1) a radical polymerization initiator, (2) a reducing compound containing sulfur in the molecule thereof, (3) an amine hydrohalogenate or a quaternary ammonium halide and (4) a copper-containing compound. Said polymer has high mechanical properties and excellent transparency and is useful particularly for the production of optical parts such as conventional lenses, Fresnel's lens, optical recording disc media, prisms, mirrors, etc.
摘要翻译：用于通过快速交联聚合制备单官能（不饱和）单体，特别是聚甲基丙烯酸甲酯的聚合物的改进方法，其包括聚合选自甲基丙烯酸甲酯和单体混合物的混合物，所述单体混合物主要包含甲基在（1）自由基聚合引发剂存在下，可以部分含有单体的聚合物（即单体或单体混合物的浆料）和多官能（不饱和的）单体的甲基丙烯酸酯，（2）含硫的还原化合物其分子，（3）氢卤酸胺或季铵卤化物和（4）含铜化合物。所述聚合物具有高机械性能和优异的透明度，并且特别用于制造诸如常规透镜，菲涅尔透镜，光记录盘介质，棱镜，反射镜等的光学部件。

4. 发明授权

US4837286A Method for the production of polymethacrylates 失效
标题翻译：生产聚甲基丙烯酸酯的方法
公开(公告)号：US4837286A
公开(公告)日：1989-06-06
申请号：US901363
申请日：1986-08-28
申请人： Yasuyuki Kato , Masahiro Yuyama , Masahiko Moritani , Yukio Yasunori
发明人： Yasuyuki Kato , Masahiro Yuyama , Masahiko Moritani , Yukio Yasunori
IPC分类号： C08G63/00 , B29C39/00 , B29C39/42 , B29C39/44 , B29C67/24 , B29K33/04 , B29L11/00 , C08F2/00 , C08F2/02 , C08F2/38 , C08F2/44 , C08F4/28 , C08F4/34 , C08F4/40 , C08F18/00 , C08F20/00 , C08F20/10 , C08F20/12 , C08F20/18 , C08G63/66 , C08K5/17 , C08L33/10
CPC分类号： B29C67/246 , C08F2/02 , C08F2/38 , C08F20/10 , C08F20/12
摘要： Improved method for the production of polymethacrylates by a rapid polymerization, which comprises polymerizing an unsaturated monomer selected from a methacrylate and a monomer mixture comprising predominantly a methacrylate which may partially contain a polymer of the monomer (i.e. a syrup of the monomer or monomer mixture) in the presence of a radical polymerization initiator, a reducing compound containing sulfur in the molecule thereof, a copper-containing compound and a specific tertiary amine hydrohalogenate or a quaternary ammonium halide. Said polymethacrylates can give molded products having excellent mold release characteristics and are useful particularly for the production of optical parts such as conventional lenses, Fresnel's lens, optical recording disc media, prisms, mirrors, etc.
摘要翻译：通过快速聚合制备聚甲基丙烯酸酯的改进方法包括聚合选自甲基丙烯酸酯的不饱和单体和主要包含可部分含有单体聚合物（即单体或单体混合物的浆料）的甲基丙烯酸酯的单体混合物，在自由基聚合引发剂的存在下，分子中含有硫的还原性化合物，含铜化合物和特定的叔胺氢卤酸盐或季铵卤化物。所述聚甲基丙烯酸酯可以得到具有优异的脱模特性的成型产品，并且特别用于生产诸如常规透镜，菲涅耳透镜，光记录盘介质，棱镜，反射镜等的光学部件。

5. 发明授权

US4789709A Process for the production of heat resistant thermoplastic copolymer 失效
标题翻译：生产耐热性热塑性共聚物的方法
公开(公告)号：US4789709A
公开(公告)日：1988-12-06
申请号：US924752
申请日：1986-10-30
申请人： Yasuyuki Kato , Masahiro Yuyama , Masahiko Moritani , Hideaki Matsuura , Susumu Iijima , Tsuyoshi Hashimoto
发明人： Yasuyuki Kato , Masahiro Yuyama , Masahiko Moritani , Hideaki Matsuura , Susumu Iijima , Tsuyoshi Hashimoto
IPC分类号： C08F8/48
CPC分类号： C08F8/48
摘要： A process for the production of a thermoplastic copolymer having excellent heat distortion resistance is disclosed. The process includes heat-treating a raw copolymer comprising a vinyl monomer unit including methacrylic and/or acrylic acid units in the presence of a specific ring-closing promoter selected from basic compounds, whereby the methacrylic and/or acrylic acid unit is converted into six-membered cyclic anhydride unit. The copolymer has excellent heat distortion resistance, transparency, mechanical properties and processability, and can produce a formed product without splash on the surface. The copolymer is useful for the production of various parts, such as automobile parts, electrical parts, industrial parts, and miscellaneous goods.
摘要翻译：公开了一种制造具有优异耐热变形性的热塑性共聚物的方法。该方法包括在选自碱性化合物的特定闭环促进剂存在下热处理包含乙烯基单体单元（包括甲基丙烯酸和/或丙烯酸单元）的原料共聚物，由此将甲基丙烯酸和/或丙烯酸单元转化为六环状酸酐单元。该共聚物具有优异的耐热变形性，透明性，机械性能和加工性，并且可以在表面上产生无飞溅的成形产品。该共聚物可用于生产汽车部件，电气部件，工业部件和杂项等各种部件。

6. 发明授权

US4604414A Antistatic acrylic resin composition and method for the production thereof 失效
标题翻译：抗静电丙烯酸树脂组合物及其制备方法
公开(公告)号：US4604414A
公开(公告)日：1986-08-05
申请号：US591853
申请日：1984-03-21
申请人： Yasuyuki Kato , Masahiro Yuyama , Masahiko Moritani , Mikio Futagami
发明人： Yasuyuki Kato , Masahiro Yuyama , Masahiko Moritani , Mikio Futagami
IPC分类号： C08F220/14
CPC分类号： C08F220/14
摘要： An acrylic resin composition having excellent permanent antistatic properties, which comprises a copolymer of an acrylic monomer comprising predominantly methyl methacrylate with a specific sulfonate and optionally a specific alkylene oxide and/or acidic phosphate, and a method for the production thereof. The acrylic resin composition of the invention shows excellent antistatic properties without losing the excellent properties of methacrylic resin, such as excellent transparency, mechanical properties, heat resistance, etc., and is useful for various utilities, such as preparation of advertising displays, lighting fixtures, covers, nameplates, and various decorations.
摘要翻译：具有优异永久抗静电性能的丙烯酸树脂组合物及其制备方法，其包含主要包含甲基丙烯酸甲酯与特定磺酸盐和任选的特定环氧烷和/或酸性磷酸盐的丙烯酸单体的共聚物。本发明的丙烯酸树脂组合物显示出优异的抗静电性能，而不会失去甲基丙烯酸树脂的优异性能，例如优异的透明性，机械性能，耐热性等，并且可用于各种用途，例如制备广告显示器，照明器具，盖板，铭牌和各种装饰品。

7. 发明授权

US4661571A Process for the production of heat resistant methacrylic resin 失效
标题翻译：生产耐热甲基丙烯酸树脂的方法
公开(公告)号：US4661571A
公开(公告)日：1987-04-28
申请号：US780903
申请日：1985-09-27
申请人： Yasuyuki Kato , Masahiro Yuyama , Masahiko Moritani , Susumu Iijima
发明人： Yasuyuki Kato , Masahiro Yuyama , Masahiko Moritani , Susumu Iijima
IPC分类号： C08F2/38 , C08F20/14 , C08F2/00
CPC分类号： C08F20/14
摘要： An improved process for the production of a methacrylic polymer having excellent heat resistance, which comprises radical-polymerizing a monomer or monomer mixture consisting of 80 to 100% by weight of methyl methacrylate and 0 to 20% by weight of a copolymerizable vinyl monomer in the presence of a polymerization initiator and one or more of specific chain transfer agents selected from the group consisting of(A) 2-mercaptoethyl alkanecarboxylate of the formula: ##STR1## wherein R is an alkyl having 4 to 12 carbon atoms,(B) alkyl 3-mercaptopropionate of the formula: ##STR2## wherein R is an alkyl having 4 to 18 atoms. The methacrylic resin prepared by this invention has excellent heat resistance and can give formed products having excellent heat resistance (high heat distortion temperature) without increase of monomer content processing thereof.
摘要翻译：一种用于制备具有优异耐热性的甲基丙烯酸类聚合物的改进方法，其包括使由80至100重量％的甲基丙烯酸甲酯和0至20重量％的可共聚乙烯基单体组成的单体或单体混合物自由基聚合存在聚合引发剂和一种或多种选自（A）下式的（A）2-巯基乙基链烷羧酸酯的特定链转移剂：其中R是具有4至12个碳原子的烷基（1） B）下式的3-巯基丙酸烷基酯：其中R是具有4-18个原子的烷基。通过本发明制备的甲基丙烯酸树脂具有优异的耐热性，并且可以提供具有优异的耐热性（高热变形温度）的成型产品，而不增加其单体含量处理。

8. 发明授权

US4699964A Antistatic acrylic resin composition and method for the production thereof 失效
标题翻译：抗静电丙烯酸树脂组合物及其制备方法
公开(公告)号：US4699964A
公开(公告)日：1987-10-13
申请号：US860480
申请日：1986-05-07
申请人： Yasuyuki Kato , Masahiro Yuyama , Masahiko Moritani , Mikio Futagami
发明人： Yasuyuki Kato , Masahiro Yuyama , Masahiko Moritani , Mikio Futagami
IPC分类号： C08F220/14 , C08F2/00
CPC分类号： C08F220/14
摘要： An acrylic resin composition having excellent permanent antistatic properties, which comprises a copolymer of an acrylic monomer comprising predominantly methyl methacrylate with a specific sulfonate and optionally a specific alkylene oxide and/or acidic phosphate, and a method for the production thereof. The acrylic resin composition of the invention shows excellent antistatic properties without losing the excellent properties of methacrylic resin, such as excellent transparency, mechanical properties, heat resistance, etc., and is useful for various utilities, such as preparation of advertising display, lighting fixtures, covers, nameplate, and various decoratings.

9. 发明授权

US4211742A Process for the continuous casting of liquid polymerizable compositions 失效
标题翻译：液体可聚合组合物的连续流延方法
公开(公告)号：US4211742A
公开(公告)日：1980-07-08
申请号：US865180
申请日：1977-12-28
申请人： Yasuyuki Kato , Masahiko Moritani
发明人： Yasuyuki Kato , Masahiko Moritani
IPC分类号： C08F2/00 , B29C35/02 , B29C39/00 , B29C39/16 , B29C39/38 , C08F2/02 , C08F4/00 , C08F4/28 , C08F4/34 , C08F220/00 , C08F220/10 , C08F220/18 , C08F265/06 , B29D7/02
CPC分类号： B29C39/38 , B29C39/006 , B29C39/16 , C08F265/06 , B29C2791/002 , B29C35/02 , B29K2033/04
摘要： A continuous process for producing plate-like polymer articles which comprises subjecting a liquid polymerizable composition comprising a syrup of methyl methacrylate and a specified amount of a polymerization initiator of the formula: ##STR1## (in which R is a C.sub.4 -C.sub.10 alkyl or alkoxyalkyl group), to a casting polymerization at a specified temperature. By this process, plate-like polymer articles having a high quality can be obtained in a very short polymerization time.
摘要翻译：一种用于生产板状聚合物制品的连续方法，其包括使包含甲基丙烯酸甲酯浆料和指定量的下式的聚合引发剂的液体可聚合组合物：其中R是C 4 -C 10烷基或烷氧基烷基组），在特定温度下进行浇铸聚合。通过该方法，可以在非常短的聚合时间内获得具有高质量的板状聚合物制品。

10. 发明授权

US4089918A Process for the continuous casting of liquid polymerizable compositions 失效
标题翻译：液体可聚合组合物的连续流延方法
公开(公告)号：US4089918A
公开(公告)日：1978-05-16
申请号：US643631
申请日：1975-12-23
申请人： Yasuyuki Kato , Masahiko Moritani , Seiichi Suzuki
发明人： Yasuyuki Kato , Masahiko Moritani , Seiichi Suzuki
IPC分类号： C08F2/00 , B01J14/00 , B29C39/00 , B29C39/16 , C08F2/02
CPC分类号： B29C39/16 , B29C39/006
摘要： A process and apparatus for the continuous casting of a liquid polymerizable composition comprising feeding the liquid polymerizable composition together with a pair of continuous gaskets into a spacing between a pair of moving endless belts arranged such that the lower run of the upper belt is disposed above the upper run of the lower belt and said runs are driven concurrently in the same direction at substantially the same speed, said gaskets being fed such that they circumscribe both side end portions of the spacing to form a cavity, while moving together with the moving belts and keeping in contact with the opposing surfaces of the belts. Passing the composition through a portion of the path of the belts to partially polymerize said composition to such a viscosity that a common logarithm of its viscosity in terms of poise at the temperature of polymerization is within the range of 2 to 5, then passing a portion of the path thereof arranged so as to be curved at least once to bring its degree of polymerization within the range of 40 to 60 weight per cent, and thereafter passing the composition through a straight portion of the path for complete polymerization, said path for polymerization being arranged such the lower and upper runs of the respective belts are brought closer together to follow shrinkage of the composition upon polymerization. Finally the resultant polymerized plate product with a good preciseness in thickness in the widthwise direction and with favorable surface qualities is removed, from the discharge end of the belts.
摘要翻译：一种用于液体可聚合组合物的连续铸造的方法和装置，包括将液体可聚合组合物与一对连续的垫片一起进给到一对移动的环形带之间的间隔中，所述间隔布置成使得上部带的下游位于下皮带的上游和所述跑道以基本上相同的速度在相同的方向上同时被驱动，所述垫圈被进给，使得它们围绕间隔的两个侧端部分以形成空腔，同时与移动带一起移动，保持与带的相对表面接触。将组合物通过带的路径的一部分以部分地将所述组合物聚合到这样的粘度，使得其在聚合温度下的平均粘度的常用对数在2至5的范围内，然后通过一部分其路径布置成至少弯曲一次以使其聚合度在40至60重量％的范围内，然后使组合物通过用于完全聚合的路径的直线部分，所述聚合路径被布置成使得各个带的下部和上部运行更靠近在一起以跟随聚合时组合物的收缩。最后，从带的排出端去除在宽度方向上具有良好的厚度精确度和良好的表面质量的所得聚合板产品。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式