专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明授权

US08410231B2 Production process of olefin polymer 失效
标题翻译：烯烃聚合物的生产工艺
公开(公告)号：US08410231B2
公开(公告)日：2013-04-02
申请号：US12528421
申请日：2008-02-25
申请人： Yasutoyo Kawashima , Tomoaki Goto
发明人： Yasutoyo Kawashima , Tomoaki Goto
IPC分类号： C08F4/00 , C08F4/52 , B01J31/00
CPC分类号： C08F110/02 , C08F4/65912 , C08F4/65927 , C08F210/16 , C08F2410/01 , C08F4/6492 , C08F4/65916 , C08F210/14
摘要： The present invention provides a highly active process for producing an olefin polymer, comprising: the step (I) of preliminarily polymerizing an olefin at 65° C. or lower in the presence of a preliminary polymerization catalyst prepared by bringing the following components (A), (B) and (C) into contact with each other, to produce a preliminary polymerization catalyst component (X); and the step (II) of polymerizing an olefin in the presence of a polymerization catalyst prepared by bringing the preliminary polymerization catalyst component (X) into contact with the following component (D), to produce an olefin polymer; component (A): a metallocene-base complex, component (B): a solid co-catalyst component in which a compound capable of ionizing the metallocene-base complex into an ionic complex is supported on fine particle support, component (C): an organoaluminum compound represented by the general formula R13Al (wherein, R1 is a linear hydrocarbon group of 1 to 8 carbon atoms, wherein the R1 can be the same or different), and component (D): an organoaluminum compound represented by the general formula R23Al (wherein, R2 is a branched hydrocarbon group of 3 to 8 carbon atoms, wherein the R2 can be the same or different).
摘要翻译：本发明提供一种生产烯烃聚合物的高活性方法，包括：在通过使以下组分（A）制备的预聚合催化剂存在下，在65℃或更低温度下预先聚合烯烃的步骤（I），（B）和（C）彼此接触以产生预聚合催化剂组分（X）; 和通过使预聚合催化剂组分（X）与以下组分（D）接触制备的聚合催化剂存在下使烯烃聚合以制备烯烃聚合物的步骤（II）; 组分（A）：茂金属 - 基配合物，组分（B）：其中可将金属茂基络合物离子化成离子络合物的化合物负载在细颗粒载体上的固体助催化剂组分，组分（C）：由通式R 13 Al表示的有机铝化合物（其中，R1为碳原子数为1〜8的直链烃基，其中R1可以相同或不同），成分（D）：由通式 R 23 Al（其中，R 2为3〜8个碳原子的支链烃基，其中R2可以相同或不同）。

2. 发明授权

US07485687B2 Ethylene-α-olefin copolymer, molding thereof and process for producing the copolymer 有权
标题翻译：乙烯-α-烯烃共聚物，其成型及共聚物的制造方法
公开(公告)号：US07485687B2
公开(公告)日：2009-02-03
申请号：US11528444
申请日：2006-09-28
申请人： Yuki Iseki , Tomoaki Goto , Yasutoyo Kawashima
发明人： Yuki Iseki , Tomoaki Goto , Yasutoyo Kawashima
IPC分类号： C08F4/42
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65927 , C08F210/16 , C08L23/0815 , C08L2205/02 , Y10S526/943 , C08F4/6492 , C08F4/65916 , C08L2666/06 , C08F210/14 , C08F2500/12 , C08F2500/04 , C08F2500/20 , C08F2500/17
摘要： An ethylene-α-olefin copolymer containing monomer units derived from ethylene and monomer units of an α-olefin having 3 to 20 carbon atoms and having a melt flow rate of from 0.01 to 100 g/10 min, an activation energy of flow of 50 kJ/mol or more, a molecular weight distribution measured by a gel permeation chromatography of 3 or more and minute defects of 2000/m2 or less in number, a process for producing the copolymer, and a molding of the copolymer.
摘要翻译：包含衍生自乙烯的单体单元和具有3至20个碳原子且具有0.01至100g / 10min的熔体流动速率的α-烯烃的单体单元的乙烯-α-烯烃共聚物，流动的活化能为50 kJ / mol以上，通过3次以上的凝胶渗透色谱法测定的分子量分布，数量为2000个/ m 2以下的微小缺陷，共聚物的制造方法和共聚物的成型。

3. 发明申请

US20070100105A1 Ethylene-alpha-olefin copolymer, molding thereof and process for producing the copolymer 有权
标题翻译：乙烯-α-烯烃共聚物，其成型及共聚物的制造方法
公开(公告)号：US20070100105A1
公开(公告)日：2007-05-03
申请号：US11528444
申请日：2006-09-28
申请人： Yuki Iseki , Tomoaki Goto , Yasutoyo Kawashima
发明人： Yuki Iseki , Tomoaki Goto , Yasutoyo Kawashima
IPC分类号： C08F210/00
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65927 , C08F210/16 , C08L23/0815 , C08L2205/02 , Y10S526/943 , C08F4/6492 , C08F4/65916 , C08L2666/06 , C08F210/14 , C08F2500/12 , C08F2500/04 , C08F2500/20 , C08F2500/17
摘要： An ethylene-α-olefin copolymer containing monomer units derived from ethylene and monomer units of an α-olefin having 3 to 20 carbon atoms and having a melt flow rate of from 0.01 to 100 g/10 min, an activation energy of flow of 50 kJ/mol or more, a molecular weight distribution measured by a gel permeation chromatography of 3 or more and minute defects of 2000/m2 or less in number, a process for producing the copolymer, and a molding of the copolymer.
摘要翻译：包含衍生自乙烯的单体单元和具有3至20个碳原子且具有0.01至100g / 10min的熔体流动速率的α-烯烃的单体单元的乙烯-α-烯烃共聚物，流动的活化能为50 kJ / mol以上，通过3次以上的凝胶渗透色谱法测定的分子量分布，数量为2000 / m 2以下的微小缺陷，共聚物的制造方法和成型的共聚物。

4. 发明申请

US20100029868A1 PRODUCTION PROCESS OF OLEFIN POLYMER 失效
标题翻译：烯烃聚合物的生产工艺
公开(公告)号：US20100029868A1
公开(公告)日：2010-02-04
申请号：US12528421
申请日：2008-02-25
申请人： Yasutoyo Kawashima , Tomoaki Goto
发明人： Yasutoyo Kawashima , Tomoaki Goto
IPC分类号： C08F4/6592
CPC分类号： C08F110/02 , C08F4/65912 , C08F4/65927 , C08F210/16 , C08F2410/01 , C08F4/6492 , C08F4/65916 , C08F210/14
摘要： The present invention provides a highly active process for producing an olefin polymer, comprising: the step (I) of preliminarily polymerizing an olefin at 65° C. or lower in the presence of a preliminary polymerization catalyst prepared by bringing the following components (A), (B) and (C) into contact with each other, to produce a preliminary polymerization catalyst component (X); and the step (II) of polymerizing an olefin in the presence of a polymerization catalyst prepared by bringing the preliminary polymerization catalyst component (X) into contact with the following component (D), to produce an olefin polymer; component (A): a metallocene-base complex, component (B): a solid co-catalyst component in which a compound capable of ionizing the metallocene-base complex into an ionic complex is supported on fine particle support, component (C): an organoaluminum compound represented by the general formula R13Al (wherein, R1 is a linear hydrocarbon group of 1 to 8 carbon atoms, wherein the R1 can be the same or different), and component (D): an organoaluminum compound represented by the general formula R23Al (wherein, R2 is a branched hydrocarbon group of 3 to 8 carbon atoms, wherein the R2 can be the same or different).
摘要翻译：本发明提供一种生产烯烃聚合物的高活性方法，包括：在通过使以下组分（A）制备的预聚合催化剂存在下，在65℃或更低温度下预先聚合烯烃的步骤（I），（B）和（C）彼此接触以产生预聚合催化剂组分（X）; 和通过使预聚合催化剂组分（X）与以下组分（D）接触制备的聚合催化剂存在下使烯烃聚合以制备烯烃聚合物的步骤（II）; 组分（A）：茂金属 - 基配合物，组分（B）：其中可将金属茂基络合物离子化成离子络合物的化合物负载在细颗粒载体上的固体助催化剂组分，组分（C）：由通式R 13 Al表示的有机铝化合物（其中，R1为碳原子数为1〜8的直链烃基，其中R1可以相同或不同），成分（D）：由通式 R 23 Al（其中，R 2为3〜8个碳原子的支链烃基，其中R2可以相同或不同）。

5. 发明授权

US08436101B2 Ethylene-α-olefin copolymer and molded object thereof 有权
标题翻译：乙烯-α-烯烃共聚物及其成型物
公开(公告)号：US08436101B2
公开(公告)日：2013-05-07
申请号：US13128554
申请日：2009-11-10
申请人： Yoshinobu Nozue , Yasutoyo Kawashima , Naoko Ochi , Takuya Ogane
发明人： Yoshinobu Nozue , Yasutoyo Kawashima , Naoko Ochi , Takuya Ogane
IPC分类号： C08L23/04 , C08F4/646 , C08F4/6592 , C08F10/02
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65927 , C08F2410/01 , C08F4/65916 , C08F210/14 , C08F2500/11 , C08F2500/12 , C08F2500/09 , C08F2500/17 , C08F2500/14 , C08F2500/20 , C08F2500/04 , C08F210/08
摘要： The purpose of the invention is to provide an ethylene-α-olefin copolymer, which has a high melt tension but a small neck-in, and a molded object produced by extrusion molding of the copolymer. An ethylene-α-olefin copolymer having a monomer unit based on ethylene and a monomer unit based on an α-olefin having 3 to 20 carbon atoms, which has a melt flow rate (MFR) of 0.1 to 100 g/10 min, a density (d) of 850 to 940 kg/m3, a ratio (Mw/Mn) of weight average molecular weight (Mw) to number average molecular weight (Mn) of 2 to 12, and a value g* defined by the following formula (I) of 0.50 to 0.75: g*=[η]/([η]GPC×gSCB*) (I).
摘要翻译：本发明的目的是提供一种乙烯-α-烯烃共聚物，该共聚物具有高熔体张力但小的颈缩，以及通过共聚物的挤出成型制备的模制品。具有基于乙烯的单体单元和基于具有3至20个碳原子的α-烯烃的单体单元，其熔体流动速率（MFR）为0.1至100g / 10分钟的乙烯-α-烯烃共聚物，密度（d）为850〜940kg / m 3，重均分子量（Mw）与数均分子量（Mn）的比（Mw / Mn）为2〜12，由下式（I）为0.50至0.75:g * =η/（ηGPC×gSCB *）（I）。

6. 发明申请

US20120316310A1 ETHYLENE-alpha-OLEFIN COPOLYMER 审中-公开
标题翻译：乙烯-α-烯烃共聚物
公开(公告)号：US20120316310A1
公开(公告)日：2012-12-13
申请号：US13515168
申请日：2010-12-03
申请人： Jumma Nomura , Kazuo Takaoki , Takeshi Hatakeyama , Yoshinobu Nozue , Yasutoyo Kawashima
发明人： Jumma Nomura , Kazuo Takaoki , Takeshi Hatakeyama , Yoshinobu Nozue , Yasutoyo Kawashima
IPC分类号： C08F210/02
CPC分类号： C08F210/16 , C08J5/18 , C08J2323/18 , C08F210/14 , C08F2500/04 , C08F2500/11 , C08F2500/12 , C08F2500/17 , C08F2500/20
摘要： The present invention relates to an ethylene-α-olefin copolymer comprising monomer units derived from ethylene and monomer units derived from an α-olefin having from 3 to 20 carbon atoms, wherein the copolymer has a melt flow rate of 0.01 to 100 g/10 min, a density of 860 to 970 kg/m3, a molecular weight distribution of 5.5 to 12, and an activation energy of flow of 50 to 100 kJ/mol, and when the maximum take-up rate of the copolymer at 150° C. is represented by MTV150 and the maximum take-up rate of the copolymer at 190° C. is represented by MTV190, MTV150 is 40 m/min or more, and the ratio of MTV150 to MTV190 is 1 or less.
摘要翻译：本发明涉及包含衍生自乙烯的单体单元和衍生自具有3-20个碳原子的α-烯烃的单体单元的乙烯-α-烯烃共聚物，其中共聚物的熔体流动速率为0.01-100g / 10 min，密度为860〜970kg / m 3，分子量分布为5.5〜12，流动活化能为50〜100kJ / mol，当共聚物在150℃时的最大吸收速度由MTV150表示，共聚物在190℃下的最大吸收速度由MTV190表示，MTV150为40m / min以上，MTV150与MTV190的比例为1以下。

7. 发明申请

US20110003950A1 CATALYST COMPONENT FOR POLYMERIZATION OF ETHYLENE AND PROCESS FOR PRODUCING ETHYLENE POLYMER (2) 失效
标题翻译：用于乙烯聚合的催化剂组分和用于生产乙烯聚合物的方法（2）
公开(公告)号：US20110003950A1
公开(公告)日：2011-01-06
申请号：US12865617
申请日：2009-02-17
申请人： Yasutoyo Kawashima
发明人： Yasutoyo Kawashima
IPC分类号： C08F4/602
CPC分类号： C08F110/02 , C08F4/65912 , C08F4/65916 , C08F2410/01 , C08F4/65927 , C08F2500/10 , C08F210/08 , C08F2500/01 , C08F2500/17
摘要： The object is to provide a catalyst component for ethylene polymerization which can produce an ethylene polymer of high molecular weight which has substantially only an ethyl branch, and a process for producing the catalyst component for ethylene polymerization which can produce an ethylene polymer of high molecular weight which has substantially only an ethyl branch. A catalyst component for polymerization of ethylene obtained by contacting the following components (A), (B), (C) and (D): component (A): a meso-metallocene compound, component (B): a compound which ionizes a metallocene compound to form an ionic complex, component (C): an organoaluminum compound, and component (D): an electron donating compound, and a process for producing the ethylene polymer by polymerizing ethylene in the presence of the above catalyst component for ethylene polymerization.
摘要翻译：本发明的目的是提供一种用于乙烯聚合的催化剂组分，其可以生产基本上只有乙基支链的高分子量乙烯聚合物，以及制备乙烯聚合催化剂组分的方法，该方法可制备高分子量的乙烯聚合物其基本上仅具有乙基支链。通过使以下组分（A），（B），（C）和（D）接触获得的乙烯聚合催化剂组分：组分（A）：内消旋 - 茂金属化合物，组分（B）：使茂金属化合物以形成离子络合物，组分（C）：有机铝化合物和组分（D）：给电子化合物，以及通过在上述用于乙烯聚合的催化剂组分的存在下聚合乙烯来制备乙烯聚合物的方法。

8. 发明申请

US20100305292A1 ETHYLENE-a-OLEFIN COPOLYMER AND MOLDED ARTICLE 有权
标题翻译：乙烯-α-烯烃共聚物和成型品
公开(公告)号：US20100305292A1
公开(公告)日：2010-12-02
申请号：US12744857
申请日：2008-11-27
申请人： Yoshinobu Nozue , Naoko Ochi , Yasutoyo Kawashima
发明人： Yoshinobu Nozue , Naoko Ochi , Yasutoyo Kawashima
IPC分类号： C08F210/14 , C08F210/08
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F2410/01 , C08F4/6492 , C08F4/65904 , C08F2500/12 , C08F2500/14 , C08F2500/04 , C08F2500/06
摘要： An ethylene-α-olefin copolymer wherein the copolymer has a monomer unit based on ethylene and a monomer unit based on an α-olefin having 3 to 20 carbon atoms, the density (d) is 860 to 950 kg/m3, the melt flow rate (MFR) is 1 to 100 g/10 min, the ratio (Mw/Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) is 4 to 30, the ratio (Mz/Mw) of the Z average molecular weight (Mz) to the weight average molecular weight (Mw) is 2 to 5, the swell ratio (SR) is 1.8 or more, and the characteristic relaxation time (τ) obtained by linear viscoelasticity measurement is 0.01 to 10 seconds.
摘要翻译：一种乙烯-α-烯烃共聚物，其中共聚物具有基于乙烯的单体单元和基于具有3至20个碳原子的α-烯烃的单体单元，密度（d）为860至950kg / m 3，熔体流动速率（MFR）为1〜100g / 10分钟，重均分子量（Mw）与数均分子量（Mn）的比（Mw / Mn）为4〜30，比例（Mz / Mw）的Z平均分子量（Mz）与重均分子量（Mw）的比为2〜5，溶胀比（SR）为1.8以上，通过线性粘弹性测定得到的特征弛豫时间（τ）为0.01〜 10秒。

9. 发明授权

US08426525B2 Ethylene based polymer composition and film 有权
标题翻译：乙烯基聚合物组合物和薄膜
公开(公告)号：US08426525B2
公开(公告)日：2013-04-23
申请号：US12599069
申请日：2008-05-15
申请人： Yoshinobu Nozue , Yasutoyo Kawashima
发明人： Yoshinobu Nozue , Yasutoyo Kawashima
IPC分类号： C08L23/00 , C08L23/04
CPC分类号： C08L23/04 , C08J5/18 , C08J2323/04 , C08J2323/08 , C08L23/0815 , C08L2205/02 , C08L2666/06
摘要： An ethylene based polymer composition comprising the following component (A) and the following component (B) wherein the content of the component (B) is 0.5 to 20 parts by weight per 100 parts by weight of the component (A): Component (A): an ethylene based polymer satisfying all of the following requirements (a1) to (a3): (a1) the density is 890 to 925 kg/m3, (a2) the melt flow rate (MFR) is 0.1 to 10 g/10 minutes, (a3) the flow activation energy (Ea) is 50 kJ/mol or more, Component (B): an ethylene-α-olefin copolymer satisfying all of the following requirements (b1) to (b3): (b1) the density is 890 to 925 kg/m3, (b2) the intrinsic viscosity [η] measured in a tetralin solution is 4 to 15 dL/g, (b3) the flow activation energy (Ea) is less than 50 kJ/mol.
摘要翻译：包含以下组分（A）和以下组分（B）的乙烯基聚合物组合物，其中组分（B）的含量相对于组分（A）每100重量份为0.5至20重量份：组分（A ）：满足以下所有要求的乙烯系聚合物（a1）〜（a3）：（a1）密度为890〜925kg / m3，（a2）熔体流动速率（MFR）为0.1〜10g / 10 分钟，（a3）流动活化能（Ea）为50kJ / mol以上组分（B）：满足以下所有要求（b1）至（b3）的乙烯-α-烯烃共聚物：（b1）密度为890〜925kg / m3，（b2）在四氢化萘溶液中测定的特性粘度η为4〜15dL / g，（b3）流动活化能（Ea）小于50kJ / mol。

10. 发明申请

US20120184431A1 TRANSITION METAL COMPLEX, PREPARATION METHOD FOR SAID TRANSITION METAL COMPLEX, TRIMERIZATION CATALYST, PREPARATION METHOD FOR 1-HEXENE, PREPARATION METHOD FOR ETHYLENE POLYMER, SUBSTITUTED CYCLOPENTADIENE COMPOUND, AND PREPARATION METHOD FOR SAID SUBSTITUTED CYCLOPENTADIENE COMPOUND 审中-公开
标题翻译：过渡金属络合物，用于固体过渡金属络合物的制备方法，三聚催化剂，1-丁烯的制备方法，乙烯聚合物的制备方法，取代的环己基化合物，以及用于取代的环戊二烯化合物的制备方法
公开(公告)号：US20120184431A1
公开(公告)日：2012-07-19
申请号：US13498980
申请日：2010-09-30
申请人： Yasutoyo Kawashima , Takahiro Hino , Taichi Senda , Masaya Tanimoto
发明人： Yasutoyo Kawashima , Takahiro Hino , Taichi Senda , Masaya Tanimoto
IPC分类号： C08F10/02 , C07C2/32 , B01J31/12 , B01J31/14 , C07F7/28 , C07F7/08
CPC分类号： B01J31/2295 , B01J31/143 , B01J2231/20 , B01J2231/32 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07C2/34 , C07C2531/14 , C07C2531/22 , C07F7/28 , C07F17/00 , C07F19/00 , C08F10/00 , Y02P20/52 , C07C11/107 , C08F4/6592
摘要： Disclosed is transition metal complex that serves as a catalytic component with which 1-hexene can be produced efficiently with excellent selectivity, even under high temperature conditions, by means of an ethylene trimerization reaction. Also disclosed is a method for economically preparing a butyl-branched ethylene polymer, even under high temperature conditions, by using said transition metal complex as an ethylene trimerization catalyst, and polymerizing ethylene in the presence of an olefin polymerization catalyst that is obtained by bringing an olefin copolymerization catalyst and an activating co-catalytic component into contact with one another. Said transition metal complex is represented by the following general formula (1), wherein M1 represents a Group 4 transition metal atom, and R1 through R11 and X1 through X3 each independently represent a hydrogen atom, a halogen atom, or a specific organic group.
摘要翻译：公开了作为催化成分的过渡金属络合物，即使在高温条件下也可以通过乙烯三聚反应，以高选择性有效地制备1-己烯。还公开了一种即使在高温条件下通过使用所述过渡金属配合物作为乙烯三聚催化剂来经济地制备丁基支链的乙烯聚合物的方法，并且在烯烃聚合催化剂存在下聚合乙烯，该方法是通过使烯烃共聚催化剂和活化助催化组分彼此接触。所述过渡金属络合物由以下通式（1）表示，其中M1表示第4族过渡金属原子，R1至R11和X1至X3各自独立地表示氢原子，卤素原子或特定有机基团。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式