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    • 3. 发明申请
    • PROCESS FOR PRODUCTION OF SYNDIOTACTIC PROPYLENE POLYMER
    • 生产聚丙烯聚合物的方法
    • US20100069588A1
    • 2010-03-18
    • US12312483
    • 2007-11-16
    • Tomohiro YamaguchiJunpei TanakaShiro OtsuzukiYasushi TohiKouji NagahashiNobukazu YamahiraShigenobu IkenagaSunil Krzysztof MoorthiKazunori Kamio
    • Tomohiro YamaguchiJunpei TanakaShiro OtsuzukiYasushi TohiKouji NagahashiNobukazu YamahiraShigenobu IkenagaSunil Krzysztof MoorthiKazunori Kamio
    • C08F4/52C08F4/76
    • C08F10/06C08F4/65912C08F110/06Y10S526/943C08F4/65927C08F2/06C08F2500/16C08F2500/17C08F2500/12C08F2500/26
    • It is an object of the present invention to provide a process for producing a syndiotactic propylene polymer with high polymerization activity and high efficiency by a solution polymerization method without deposition of polymers (excluding a white state), and a production process capable of conducting the above production continuously, provided that these processes could not be attained conventionally.The present invention is: a process for producing a syndiotactic propylene polymer having a syndiotactic pentad fraction (rrrr fraction), as measured by 13C-NMR, of at least 85%, a melting point (Tm), as measured by DSC, of from 145° C. to 170° C., and an intrinsic viscosity [η] of 0.1 to 10 dl/g, which process comprises a step (P1) of solution polymerizing propylene singly or propylene and at least one monomer selected from ethylene and an α-olefin having 4 to 10 carbon atoms at a polymerization temperature (TR) of from 30° C. to 250° C. in an inert hydrocarbon solvent in the presence of an olefin polymerization catalyst which comprises; (A) a bridged metallocene compound represented by the following formula (I), and (B) at least one compound selected from (b-1) an organoaluminum oxy compound, (b-2) a compound capable of forming an ion pair by reacting with the metallocene compound (A), and (b-3) an organoaluminum compound. in which M is a titanium atom or the like, Q is a halogen atom or the like, j is an integer of 1 to 4, Ra and Rb may be identically or differently a single nuclear or polynuclear hydrocarbon residue capable of forming a sandwich structure together with M, Y is a carbon atom or a silicon atom, and Rc and Rd may be the same or different from each other, is selected from hydrogen, a hydrocarbon group and a silicon atom-containing group and further may be bonded each other to form a ring.
    • 本发明的目的是提供一种通过不沉积聚合物(不包括白色状态)的溶液聚合法制备具有高聚合活性和高效率的间同立构丙烯聚合物的方法,以及能够进行上述 只要这些方法不能常规地实现即可。 本发明是通过13 C-NMR测定的具有间同立构五单元组分(rrrr分数)的间同立构丙烯聚合物的方法,其通过DSC测定为至少85%,熔点(Tm) 145℃至170℃,特性粘度[η]为0.1至10dl / g,该方法包括使丙烯单独或丙烯和至少一种选自乙烯和/或丙烯的单体的溶液聚合的步骤(P1) 在烯烃聚合催化剂存在下,在惰性烃溶剂中,在30℃至250℃的聚合温度(TR)下具有4至10个碳原子的α-烯烃,其包含: (A)由下式(I)表示的桥连金属茂化合物和(B)至少一种选自(b-1)有机铝氧化合物的化合物,(b-2)能够形成离子对的化合物 与茂金属化合物(A)和(b-3)有机铝化合物反应。 其中M为钛原子等,Q为卤素原子等,j为1〜4的整数,Ra和Rb可以相同或不同,能形成夹层结构的单核或多核烃残基 与M一起,Y是碳原子或硅原子,并且R c和R d可以相同或不同,选自氢,烃基和含硅原子的基团,并且可以彼此键合 形成一个戒指。
    • 10. 发明授权
    • Image forming apparatus capable of enhancing resolution of image data in high quality
    • 能够高质量地提高图像数据分辨率的图像形成装置
    • US08964243B2
    • 2015-02-24
    • US12558018
    • 2009-09-11
    • Tomohiro Yamaguchi
    • Tomohiro Yamaguchi
    • G06F15/00H04N1/409H04N1/40
    • H04N1/40068H04N1/4092
    • MFP matches low-resolution binary image data received by facsimile with a dot pattern showing a jaggy. If there is any matching region, the image data is converted into multivalued image data by performing jaggy correction in which the tone of a target dot in the region is substituted with a grayscale. MFP also generates a region identification attribute code based on the result of matching and the tone of the input image data. MFP enhances the respective resolutions of the image data after jaggy correction and the region identification attribute code. MFP then binarizes the image data having the enhanced resolution once again by a binarization method according to the region identification attribute code having the enhanced resolution.
    • MFP将通过传真接收的低分辨率二进制图像数据与显示锯齿状的点图案相匹配。 如果存在任何匹配区域,则通过执行其中该区域中的目标点的色调被灰度代替的锯齿校正将图像数据转换为多值图像数据。 MFP还根据匹配结果和输入图像数据的色调生成区域识别属性码。 MFP增强了锯齿校正后的图像数据的分辨率和区域识别属性码。 MFP然后根据具有增强分辨率的区域识别属性码,通过二值化方法再次对具有增强分辨率的图像数据进行二值化。