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1. 发明授权

US08133592B2 Laminated adhesive thermoplastic resin film 有权
标题翻译：层压粘合剂热塑性树脂薄膜
公开(公告)号：US08133592B2
公开(公告)日：2012-03-13
申请号：US12526793
申请日：2008-02-14
申请人： Yasushi Takada , Mitsuhiro Horiuchi , Masato Yanagibashi
发明人： Yasushi Takada , Mitsuhiro Horiuchi , Masato Yanagibashi
IPC分类号： B32B27/06 , B32B27/16 , B32B27/20 , B32B27/26 , B32B27/36
CPC分类号： B32B27/36 , Y10T428/25 , Y10T428/2813 , Y10T428/31786 , Y10T428/31794
摘要： A laminated adhesive thermoplastic resin film includes a laminated layer containing a polyester resin (A) and a polyester resin (B) different from each other in glass transition temperature and a melamine-based crosslinking agent (C) as components and having a surface energy of 48 to 55 mN/m, formed at least on one surface of the thermoplastic resin film, wherein the glass transition temperature of the polyester resin (A) is 110° C. or higher; the glass transition temperature of the polyester resin (B) is 60° C. to lower than 110° C.; and the amount of the melamine-based crosslinking agent (C) is 75 to 200 parts by weight per 100 parts by weight based on the weight of the polyester resin (A) and the polyester resin (B).
摘要翻译：层压粘合性热塑性树脂膜包括在玻璃化转变温度下含有彼此不同的聚酯树脂（A）和聚酯树脂（B）的层压层和作为组分的三聚氰胺类交联剂（C），其表面能为至少在热塑性树脂膜的一个表面上形成48至55mN / m，其中聚酯树脂（A）的玻璃化转变温度为110℃或更高; 聚酯树脂（B）的玻璃化转变温度为60℃至低于110℃。相对于聚酯树脂（A）和聚酯树脂（B）的重量，三聚氰胺类交联剂（C）的含量相对于100重量份为75〜200重量份。

2. 发明申请

US20100104854A1 LAMINATED ADHESIVE THERMOPLASTIC RESIN FILM 有权
标题翻译：层压粘合剂热塑性树脂膜
公开(公告)号：US20100104854A1
公开(公告)日：2010-04-29
申请号：US12526793
申请日：2008-02-14
申请人： Yasushi Takada , Mitsuhiro Horiuchi , Masato Yanagibashi
发明人： Yasushi Takada , Mitsuhiro Horiuchi , Masato Yanagibashi
IPC分类号： B32B5/16 , C09J7/00 , C09J133/04
CPC分类号： B32B27/36 , Y10T428/25 , Y10T428/2813 , Y10T428/31786 , Y10T428/31794
摘要： A laminated adhesive thermoplastic resin film includes a laminated layer containing a polyester resin (A) and a polyester resin (B) different from each other in glass transition temperature and a melamine-based crosslinking agent (C) as components and having a surface energy of 48 to 55 mN/m, formed at least on one surface of the thermoplastic resin film, wherein the glass transition temperature of the polyester resin (A) is 110° C. or higher; the glass transition temperature of the polyester resin (B) is 60° C. to lower than 110° C.; and the amount of the melamine-based crosslinking agent (C) is 75 to 200 parts by weight per 100 parts by weight based on the weight of the polyester resin (A) and the polyester resin (B).
摘要翻译：层压粘合性热塑性树脂膜包括在玻璃化转变温度下含有彼此不同的聚酯树脂（A）和聚酯树脂（B）的层压层和作为组分的三聚氰胺类交联剂（C），其表面能为至少在热塑性树脂膜的一个表面上形成48至55mN / m，其中聚酯树脂（A）的玻璃化转变温度为110℃或更高; 聚酯树脂（B）的玻璃化转变温度为60℃至低于110℃。相对于聚酯树脂（A）和聚酯树脂（B）的重量，三聚氰胺类交联剂（C）的含量相对于100重量份为75〜200重量份。

3. 发明申请

US20070202297A1 Laminated Film 失效
标题翻译：层压膜
公开(公告)号：US20070202297A1
公开(公告)日：2007-08-30
申请号：US11663948
申请日：2005-09-26
申请人： Yasushi Takada , Masato Yanagibashi , Masato Ushijima , Yutake Harada
发明人： Yasushi Takada , Masato Yanagibashi , Masato Ushijima , Yutake Harada
IPC分类号： B32B27/40 , B32B27/36 , B32B27/30 , B32B27/20
CPC分类号： C08J7/047 , C08J2367/02 , C08J2433/00 , Y10T428/24355 , Y10T428/25 , Y10T428/26 , Y10T428/265 , Y10T428/269 , Y10T428/28 , Y10T428/31504 , Y10T428/31551 , Y10T428/31565 , Y10T428/31786 , Y10T428/31797 , Y10T428/31855 , Y10T428/31935
摘要： A laminated film including a thermoplastic resin film and an laminated layer that is formed on at least one side of the thermoplastic resin film and comprises (A) a composition, (B) an epoxy crosslinking agent and (C) an acrylic resin having an alkyl chain of 18 to 25 carbon atoms is characterized in that the composition (A) is a composition containing at least a polythiophene and a polyanion and/or a composition containing a polythiophene derivative and a polyanion, the laminated layer contains 15 to 100 parts by weight of the acrylic resin (C) having an alkyl chain of 18 to 25 carbon atoms based on 100 parts by weight of the sum of the composition (A) and the cross-linking agent (B) and/or its reaction product, at least one side of the laminated film has a three-dimensional average surface roughness (SRa) of 3 to 50 nm, and the laminated film contains less than 10 internal contaminant particles with an average particle size of at least 100 μm per 1 m2, so that it has high level of electrical conductivity, good releasability and water resistance, and also has oligomer precipitation-preventing properties during heating.
摘要翻译：一种层压膜，包括热塑性树脂膜和层压层，所述层压层形成在所述热塑性树脂膜的至少一侧上，并且包含（A）组合物，（B）环氧交联剂和（C）具有烷基 18至25个碳原子的链的特征在于，组合物（A）是至少含有聚噻吩和聚阴离子的组合物和/或含有聚噻吩衍生物和聚阴离子的组合物，层叠层含有15〜100重量份的丙烯酸树脂（C），基于100重量份的组合物（A）和交联剂（B）和/或其反应产物的总和，具有18至25个碳原子的烷基链，至少层压膜的一侧的平均表面粗糙度（SRa）为3〜50nm，平均粒径为100μm以上的层叠膜含有少于10个内部污染物颗粒， 2 ，使其高导电性，良好的脱模性和耐水性，并且在加热时也具有低聚物防止沉淀的性质。

4. 发明授权

US08137788B2 Laminated film 失效
标题翻译：层压膜
公开(公告)号：US08137788B2
公开(公告)日：2012-03-20
申请号：US11663948
申请日：2005-09-26
申请人： Yasushi Takada , Masato Yanagibashi , Masato Ushijima , Yutaka Harada
发明人： Yasushi Takada , Masato Yanagibashi , Masato Ushijima , Yutaka Harada
IPC分类号： B32B7/02 , B32B27/08 , B32B27/18 , B32B27/26 , B32B27/28
CPC分类号： C08J7/047 , C08J2367/02 , C08J2433/00 , Y10T428/24355 , Y10T428/25 , Y10T428/26 , Y10T428/265 , Y10T428/269 , Y10T428/28 , Y10T428/31504 , Y10T428/31551 , Y10T428/31565 , Y10T428/31786 , Y10T428/31797 , Y10T428/31855 , Y10T428/31935
摘要： A laminated film including a thermoplastic resin film and an laminated layer that is formed on at least one side of the thermoplastic resin film and comprises (A) a composition, (B) an epoxy crosslinking agent and (C) an acrylic resin having an alkyl chain of 18 to 25 carbon atoms is characterized in that the composition (A) is a composition containing at least a polythiophene and a polyanion and/or a composition containing a polythiophene derivative and a polyanion, the laminated layer contains 15 to 100 parts by weight of the acrylic resin (C) having an alkyl chain of 18 to 25 carbon atoms based on 100 parts by weight of the sum of the composition (A) and the crosslinking agent (B) and/or its reaction product, at least one side of the laminated film has a three-dimensional average surface roughness (SRa) of 3 to 50 nm, and the laminated film contains less than 10 internal contaminant particles with an average particle size of at least 100 μm per 1 m2, so that it has high level of electrical conductivity, good releasability and water resistance, and also has oligomer precipitation-preventing properties during heating.
摘要翻译：一种层压膜，包括热塑性树脂膜和层压层，所述层压层形成在所述热塑性树脂膜的至少一侧上，并且包含（A）组合物，（B）环氧交联剂和（C）具有烷基 18至25个碳原子的链的特征在于，组合物（A）是至少含有聚噻吩和聚阴离子的组合物和/或含有聚噻吩衍生物和聚阴离子的组合物，层叠层含有15〜100重量份的丙烯酸树脂（C），基于100重量份的组合物（A）和交联剂（B）和/或其反应产物的总和，具有18至25个碳原子的烷基链的丙烯酸树脂（C）和/或其反应产物，至少一个侧面层叠膜的三维平均表面粗糙度（SRa）为3〜50nm，层叠膜含有少于10个平均粒径为1m 2以上的平均粒径为100μm以上的内部污染物粒子，高水平的el 导电性，良好的脱模性和耐水性，并且在加热时也具有低聚物防止沉淀的性质。

5. 发明申请

US20100239868A1 Laminated Film 有权
标题翻译：层压膜
公开(公告)号：US20100239868A1
公开(公告)日：2010-09-23
申请号：US11991836
申请日：2006-09-11
申请人： Yasushi Takada , Masato Yanagibashi
发明人： Yasushi Takada , Masato Yanagibashi
IPC分类号： B32B27/40 , B32B27/08
CPC分类号： B32B27/08 , B32B27/36 , B32B27/40 , C08G18/0823 , C08G18/0866 , C08G18/4277 , C08G18/44 , C08G18/706 , C08G18/8061 , C08J7/047 , C08J2367/02 , C08J2467/00 , C08J2475/00 , C08L75/06 , C09D175/04 , C09D175/16 , Y10T428/31551 , Y10T428/31565 , C08L2666/20
摘要： A laminated film including a thermoplastic resin film, and a laminated layer disposed on at least one surface of the thermoplastic resin film including an acryl-urethane copolymer resin (A), and a polyester resin (B), and a crosslinking agent (C) including an isocyanate crosslinking agent, a carbodiimide crosslinking agent or mixtures thereof, the amount of the crosslinking agent (C) is from 5 to 70 parts by weight based on 100 parts by weight of the sum of the acryl-urethane copolymer resin (A) and the polyester resin (B).
摘要翻译：包含热塑性树脂膜的层压膜和设置在包含丙烯酸 - 氨基甲酸酯共聚物树脂（A）和聚酯树脂（B）的热塑性树脂膜的至少一个表面上的层压膜和交联剂（C）包括异氰酸酯交联剂，碳二亚胺交联剂或其混合物，相对于丙烯酸 - 氨基甲酸酯共聚物树脂（A）的总和100重量份，交联剂（C）的量为5-70重量份，和聚酯树脂（B）。

6. 发明授权

US06828010B2 Laminated polyester film 失效
标题翻译：层压聚酯薄膜
公开(公告)号：US06828010B2
公开(公告)日：2004-12-07
申请号：US10276261
申请日：2002-12-13
申请人： Yuri Kubota , Takashi Mimura , Yasushi Takada , Masato Yanagibashi
发明人： Yuri Kubota , Takashi Mimura , Yasushi Takada , Masato Yanagibashi
IPC分类号： B32B2708
CPC分类号： B41M5/508 , B32B27/36 , C08L67/02 , C08L67/025 , Y10S428/91 , Y10T428/2495 , Y10T428/25 , Y10T428/28 , Y10T428/31786 , Y10T428/31797 , C08L2666/18
摘要： Provided is a laminated polyester film, in which a laminated layer comprising two types of polyester resins having different glass transition points from each other is formed on at least one side of a base polyester film wherein the two types of polyester resins are composed of a polyester resin (A) having a glass transition point of from 60° C. to 100° C., and a polyester resin (B) having a glass transition point of from 0° C. to 60° C. and the polyester resin (B) contains a specified component, and a dicarboxylic acid component having a sulfonic acid metal base is set as a specified ratio of the entire dicarboxylic acid components in the polyester resins (A) and (B), satisfies adhesiveness to various types of coating materials which has conventionally been incompatible and, further, satisfies anti-blocking properties, transparency, scratch resistance and the other properties.
摘要翻译：提供一种叠层聚酯膜，其中在基础聚酯膜的至少一侧上形成包含彼此具有不同玻璃化转变点的两种类型的聚酯树脂的层压层，其中两种类型的聚酯树脂由聚酯玻璃化转变点为60〜100℃的树脂（A）和玻璃化转变点为0℃〜60℃的聚酯树脂（B）和聚酯树脂（B ）含有规定成分，将具有磺酸金属碱的二羧酸成分设定为聚酯树脂（A）和（B）中的二羧酸成分的全部比例，满足对各种类型的涂料的粘合性，通常是不相容的，并且进一步满足防粘连性，透明性，耐擦伤性和其它性能。

7. 发明授权

US09200126B2 Laminated film 有权
标题翻译：层压膜
公开(公告)号：US09200126B2
公开(公告)日：2015-12-01
申请号：US13636871
申请日：2011-03-02
申请人： Kazuyoshi Ota , Masato Yanagibashi , Yasushi Takada , Yu Abe
发明人： Kazuyoshi Ota , Masato Yanagibashi , Yasushi Takada , Yu Abe
IPC分类号： D06N7/04 , B32B27/36 , B32B27/30 , C08J7/04
CPC分类号： C08J7/047 , C08J2367/02 , Y10T428/24372 , Y10T428/31511 , Y10T428/31935
摘要： A laminated film includes a resin layer provided on at least one surface of a thermoplastic resin film substrate, wherein the resin layer comprises an acrylic-modified polyester whose acrylic resin component has a glass-transition temperature of not lower than 67° C. and a sugar alcohol and/or a sugar alcohol derivative; the mass ratio of the acrylic-modified polyester to the sugar alcohol and the sugar alcohol derivative (the mass of the acrylic-modified polyester/the total mass of the sugar alcohol and the sugar alcohol derivative) is from 75/25 to 97/3; the total content of the acrylic-modified polyester and the sugar alcohol and sugar alcohol derivative is 65% by mass or more based on the total resin layer; and the haze value of the laminated film is not more than 2.0%.
摘要翻译：层压膜包括设置在热塑性树脂膜基材的至少一个表面上的树脂层，其中树脂层包含丙烯酸改性聚酯，其丙烯酸树脂组分的玻璃化转变温度不低于67℃，糖醇和/或糖醇衍生物; 丙烯酸改性聚酯与糖醇和糖醇衍生物的质量比（丙烯酸改性聚酯的质量/糖醇和糖醇衍生物的总质量）为75/25至97/3 ; 丙烯酸改性聚酯和糖醇和糖醇衍生物的总含量相对于总树脂层为65质量％以上; 并且层压膜的雾度值不大于2.0％。

8. 发明申请

US20130011613A1 LAMINATED FILM 有权
标题翻译：层压膜
公开(公告)号：US20130011613A1
公开(公告)日：2013-01-10
申请号：US13636871
申请日：2011-03-02
申请人： Kazuyoshi Ota , Masato Yanagibashi , Yasushi Takada , Yu Abe
发明人： Kazuyoshi Ota , Masato Yanagibashi , Yasushi Takada , Yu Abe
IPC分类号： B32B27/14 , B29C35/02 , B32B5/16 , B29C55/04 , B32B27/36 , B32B27/38
CPC分类号： C08J7/047 , C08J2367/02 , Y10T428/24372 , Y10T428/31511 , Y10T428/31935
摘要： A laminated film includes a resin layer provided on at least one surface of a thermoplastic resin film substrate, wherein the resin layer comprises an acrylic-modified polyester whose acrylic resin component has a glass-transition temperature of not lower than 67° C. and a sugar alcohol and/or a sugar alcohol derivative; the mass ratio of the acrylic-modified polyester to the sugar alcohol and the sugar alcohol derivative (the mass of the acrylic-modified polyester/the total mass of the sugar alcohol and the sugar alcohol derivative) is from 75/25 to 97/3; the total content of the acrylic-modified polyester and the sugar alcohol and sugar alcohol derivative is 65% by mass or more based on the total resin layer; and the haze value of the laminated film is not more than 2.0%.
摘要翻译：层压膜包括设置在热塑性树脂膜基材的至少一个表面上的树脂层，其中树脂层包含丙烯酸改性聚酯，其丙烯酸树脂组分的玻璃化转变温度不低于67℃，糖醇和/或糖醇衍生物; 丙烯酸改性聚酯与糖醇和糖醇衍生物的质量比（丙烯酸改性聚酯的质量/糖醇和糖醇衍生物的总质量）为75/25至97/3 ; 丙烯酸改性聚酯和糖醇和糖醇衍生物的总含量相对于总树脂层为65质量％以上; 并且层压膜的雾度值不大于2.0％。

9. 发明授权

US07972700B2 Laminated film 有权
标题翻译：层压膜
公开(公告)号：US07972700B2
公开(公告)日：2011-07-05
申请号：US11991836
申请日：2006-09-11
申请人： Yasushi Takada , Masato Yanagibashi
发明人： Yasushi Takada , Masato Yanagibashi
IPC分类号： B32B27/40
CPC分类号： B32B27/08 , B32B27/36 , B32B27/40 , C08G18/0823 , C08G18/0866 , C08G18/4277 , C08G18/44 , C08G18/706 , C08G18/8061 , C08J7/047 , C08J2367/02 , C08J2467/00 , C08J2475/00 , C08L75/06 , C09D175/04 , C09D175/16 , Y10T428/31551 , Y10T428/31565 , C08L2666/20
摘要： A laminated film including a thermoplastic resin film, and a laminated layer disposed on at least one surface of the thermoplastic resin film including an acryl-urethane copolymer resin (A), and a polyester resin (B), and a crosslinking agent (C) including an isocyanate crosslinking agent, a carbodiimide crosslinking agent or mixtures thereof, the amount of the crosslinking agent (C) is from 5 to 70 parts by weight based on 100 parts by weight of the sum of the acryl-urethane copolymer resin (A) and the polyester resin (B).
摘要翻译：包含热塑性树脂膜的层压膜和设置在包含丙烯酸 - 氨基甲酸酯共聚物树脂（A）和聚酯树脂（B）的热塑性树脂膜的至少一个表面上的层压膜和交联剂（C）包括异氰酸酯交联剂，碳二亚胺交联剂或其混合物，相对于丙烯酸 - 氨基甲酸酯共聚物树脂（A）的总和100重量份，交联剂（C）的量为5-70重量份，和聚酯树脂（B）。

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