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    • 2. 发明授权
    • Fuel cell having a gasket with an adhesive layer
    • 燃料电池具有带粘合剂层的垫圈
    • US06316139B1
    • 2001-11-13
    • US09238740
    • 1999-01-28
    • Makoto UchidaYuko FukuokaYasushi SugawaraHideo OharaNobuo Eda
    • Makoto UchidaYuko FukuokaYasushi SugawaraHideo OharaNobuo Eda
    • H01M802
    • H01M8/0271H01M2300/0082
    • A polymer electrolyte fuel cell having a large economical advantage uses a gasket which includes an elastomer layer that is inexpensive, highly resistant to chemicals, particularly to acids, and exhibits a high sealability. The elastomer layer is provided with an adhesive layer, and the gasket is both easy to position and easy to assemble. The fuel cell includes unit cells each including a positive electrode, an electrolyte plate, and a negative electrode, and gaskets each arranged at the circumferential part of the unit cell alternately stacked via a separator placed therebetween. The gasket includes an elastomer layer and an adhesive layer, with the elastomer layer being adhered to at least one side of the separator via the adhesive layer.
    • 具有大经济优势的聚合物电解质燃料电池使用包括低成本,高耐化学品,特别是酸的弹性体层,并且具有高密封性的垫片。 弹性体层设置有粘合剂层,并且垫圈易于定位并且易于组装。 燃料电池包括各自包括正电极,电解质板和负电极的单元电池,以及分别布置在单元电池的圆周部分上的垫片,其间经由隔板交替堆叠。 垫片包括弹性体层和粘合剂层,弹性体层经由粘合剂层粘合到隔板的至少一侧。
    • 4. 发明授权
    • Measuring method of the specific surface area available for reaction of
noble metal catalyst in the electrode of polymer electrolyte membrane
fuel cell
    • 贵金属催化剂在聚合物电解质膜燃料电池电极中可用于反应的比表面积的测量方法
    • US5866423A
    • 1999-02-02
    • US783577
    • 1997-01-15
    • Yasushi SugawaraMakoto UchidaYuko FukuokaNobuo Eda
    • Yasushi SugawaraMakoto UchidaYuko FukuokaNobuo Eda
    • G01N15/08B01J23/38B01J23/42H01M4/90H01M4/92H01M8/10
    • H01M4/926H01M4/92H01M8/1004H01M2300/0082
    • A measuring method for determining the specific surface area available for reaction of a noble metal catalyst of an electrode for use in a polymer electrolyte membrane fuel cell. The method includes measuring the total specific surface area of the noble metal catalyst and the specific surface area of the noble metal catalyst mixed with a polymer electrolyte by detecting the adsorption amounts of carbon monoxide upon exposure to carbon monoxide after reduction in hydrogen, and subtracting the latter from the former. Also provided is an electrode material for use in a polymer electrolyte membrane fuel cell having excellent polarization characteristics by controlling the utilization of a noble metal catalyst determined from the total specific surface area and specific surface area available for reaction of the noble metal catalyst. The electrode material includes a noble metal catalyst powder and a polymer electrolyte, wherein the utilization ratio of the noble metal catalyst is at least 40% of the saturation value of the utilization of the noble metal catalyst powder.
    • 一种用于确定用于聚合物电解质膜燃料电池的电极的贵金属催化剂可用于反应的比表面积的测量方法。 该方法包括通过检测在氢还原后暴露于一氧化碳时一氧化碳的吸附量,测量贵金属催化剂的总比表面积和与聚合物电解质混合的贵金属催化剂的比表面积,并减去 后者来自前者。 还提供了一种用于聚合物电解质膜燃料电池的电极材料,其通过控制由可用于贵金属催化剂的反应的总比表面积和比表面积确定的贵金属催化剂的利用而具有优异的极化特性。 电极材料包括贵金属催化剂粉末和聚合物电解质,其中贵金属催化剂的利用率为贵金属催化剂粉末的利用饱和值的至少40%。
    • 5. 发明授权
    • Design for an electrode
    • 电极设计
    • US06242260B1
    • 2001-06-05
    • US09181741
    • 1998-10-28
    • Yasushi SugawaraMakoto UchidaYuko FukuokaNobuo Eda
    • Yasushi SugawaraMakoto UchidaYuko FukuokaNobuo Eda
    • G01N1508
    • H01M4/926H01M4/92H01M8/1004H01M2300/0082
    • A measuring method for determining the specific surface area available for reaction of a noble metal catalyst of an electrode for use in a polymer electrolyte membrane fuel cell. The method includes measuring the total specific surface area of the noble metal catalyst and the specific surface area of the noble metal catalyst mixed with a polymer electrolyte by detecting the adsorption amounts of carbon monoxide upon exposure to carbon monoxide after reduction in hydrogen, and subtracting the latter from the former. Also provided is an electrode material for use in a polymer electrolyte membrane fuel cell having excellent polarization characteristics by controlling the utilization of a noble metal catalyst determined from the total specific surface area and specific surface area available for reaction of the noble metal catalyst. The electrode material includes a noble metal catalyst powder and a polymer electrolyte, wherein the utilization ratio of the noble metal catalyst is at least 40% of the saturation value of the utilization of the noble metal catalyst powder.
    • 一种用于确定用于聚合物电解质膜燃料电池的电极的贵金属催化剂可用于反应的比表面积的测量方法。 该方法包括通过检测在氢还原后暴露于一氧化碳时一氧化碳的吸附量,测量贵金属催化剂的总比表面积和与聚合物电解质混合的贵金属催化剂的比表面积,并减去 后者来自前者。 还提供了一种用于聚合物电解质膜燃料电池的电极材料,其通过控制由可用于贵金属催化剂的反应的总比表面积和比表面积确定的贵金属催化剂的利用而具有优异的极化特性。 电极材料包括贵金属催化剂粉末和聚合物电解质,其中贵金属催化剂的利用率为贵金属催化剂粉末的利用饱和值的至少40%。
    • 8. 发明授权
    • Method for manufacturing solid polymer electrolyte fuel cell
    • 固体高分子电解质燃料电池的制造方法
    • US5723173A
    • 1998-03-03
    • US590118
    • 1996-01-23
    • Yuko FukuokaMakoto UchidaNobuo Eda
    • Yuko FukuokaMakoto UchidaNobuo Eda
    • H01M4/86H01M4/88H01M4/92H01M8/02H01M8/10B05D5/12
    • H01M4/926H01M8/1004H01M2300/0082Y02P70/56Y10T29/49115
    • The invention provides a method for manufacturing a solid polymer electrolyte electrolyte fuel cell which exhibits higher performances by sufficiently and uniformly contacting the solid polymer electrolyte with a catalyst to increase the reaction area inside the electrode. The method comprises the steps of dispersing a carbon powder supporting a noble metal catalyst in an organic solvent to obtain a dispersion, mixing the resulting dispersion with an alcoholic solution of a solid polymer electrolyte to produce a colloid of the solid polymer electrolyte and simultaneously to obtain a mixed solution in which said colloid is adsorbed to the carbon powder, applying the mixed solution on one side of a gas-diffusion layer to produce an electrode, and pressing the resulting electrode on at least one side of a solid polymer electrolyte membrane to integrate them. Furthermore, a fluorocarbon polymer can be added, to thereby form a gas channel without excessive covering of the catalyst and increase gas permeability of the electrode. Thus, a solid polymer electrolyte fuel cell which exhibits high performances in a high current density area can be further provided.
    • 本发明提供一种固体高分子电解质型燃料电池的制造方法,其特征在于,通过使固体高分子电解质与催化剂充分均匀地接触,能够提高电极内部的反应面积,显示出更高的性能。 该方法包括将负载贵金属催化剂的碳粉分散在有机溶剂中以获得分散体的步骤,将所得分散体与固体高分子电解质的醇溶液混合,制成固体聚合物电解质的胶体,同时获得 将所述胶体吸附到碳粉末上的混合溶液,将混合溶液施加在气体扩散层的一侧以产生电极,并将所得电极压在固体聚合物电解质膜的至少一侧上以使其整合 他们。 此外,可以加入氟碳聚合物,从而形成气体通道,而不会过度地覆盖催化剂并增加电极的气体渗透性。 因此,可以进一步提供在高电流密度区域表现出高性能的固体聚合物电解质燃料电池。
    • 9. 发明授权
    • Solid polymer type fuel cell and method for manufacturing the same
    • 固体聚合物型燃料电池及其制造方法
    • US5474857A
    • 1995-12-12
    • US265730
    • 1994-06-27
    • Makoto UchidaYuko AoyamaNobuo EdaMasahiko Ogawa
    • Makoto UchidaYuko AoyamaNobuo EdaMasahiko Ogawa
    • H01M4/86H01M4/88H01M8/02H01M8/10
    • H01M8/1004Y02P70/56Y10T29/49115
    • The invention provides a solid polymer electrolyte having high performances in which the reaction area of electrode is increased by uniformly dispersing and bonding a solid polymer electrolyte and a catalyst and the ability of gas feeding to the reaction site is improved by adding a fluoropolymer so that the catalyst is not excessively coated. A method for making the fuel cell is also provided. The electrode provided on at least one side of a solid polymer electrolyte membrane is formed by coating on one side of a gas-diffusible layer a mixed dispersion of a noble metal catalyst, a carbon fine powder and a colloidal dispersion of a solid polymer electrolyte, the colloidal dispersion being prepared using an organic solvent having a polar group other than hydroxyl group in the molecule and having a carbon chain of 1-8 carbon atoms which bonds to the polar group or having a dielectric constant of 3-10.
    • 本发明提供了一种具有高性能的固体聚合物电解质,其中通过均匀分散和粘合固体聚合物电解质和催化剂来增加电极的反应面积,并且通过加入含氟聚合物来提高进料到反应部位的能力,使得 催化剂没有过度涂层。 还提供了制造燃料电池的方法。 设置在固体聚合物电解质膜的至少一侧的电极通过在气体扩散层的一侧上涂覆贵金属催化剂,碳细粉末和固体聚合物电解质的胶体分散体的混合分散体而形成, 该胶体分散体使用在分子中具有除羟基以外的极性基团并具有与极性基团键合或介电常数为3-10的碳原子数为1-8个碳原子的有机溶剂制备。
    • 10. 发明授权
    • Cylindrical air-cell
    • 圆柱形气囊
    • US5518834A
    • 1996-05-21
    • US355600
    • 1994-12-14
    • Hiroshi YoshizawaIsao KuboShigeto NoyaTakafumi FujiwaraAkira MiuraNobuo Eda
    • Hiroshi YoshizawaIsao KuboShigeto NoyaTakafumi FujiwaraAkira MiuraNobuo Eda
    • H01M2/04H01M2/08H01M4/70H01M12/06H01M10/34
    • H01M2/08H01M12/06
    • The sealing of the top and/or bottom of the cylindrical positive electrode of an air-cell is improved and leakage of the electrolyte from the jellied zinc negative electrode disposed within the positive electrode which is constituted of a collector layer, catalyst layer, and a porous layer is prevented. By utilizing a positive electrode constituted of a metallic collector layer made of a metal mesh or such, a catalyst layer disposed around said collector, and a fluororesin porous layer as an air diffusion layer, an outer cup and an inner cup are pressed on the top of the positive electrode in order to prevent the leakage of the electrolyte. The possible leakage of electrolyte from the bottom of the positive electrode can be prevented by providing a resin sealing body with a ring shaped indentation fitted to the bottom of a positive electrode, and by inserting this resin sealing body into the positive electrode cannister, and by pressing the side wall of the positive electrode cannister against the side of the resin sealing body, in order to fit the bottom of the positive electrode to the indentation of the resin sealing body.
    • 空气电池的圆筒形正极的顶部和/或底部的密封被改善,并且电解质从布置在正极内的凝胶状锌负电极泄漏,该正极由集电极层,催化剂层和 防止多孔层。 通过利用由金属网等构成的金属集电体构成的正极,设置在集电体周围的催化剂层和作为空气扩散层的氟树脂多孔层,将外杯和内杯按压在顶部 的正极,以防止电解液的泄漏。 可以通过设置安装在正极底部的环形压痕的树脂密封体,并将该树脂密封体插入正极罐中,并通过 将正极罐的侧壁压在树脂密封体的侧面,以便将正极的底部装配到树脂密封体的凹部。