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    • 3. 发明授权
    • Cured or uncured chlorinated polyethylene composition and process for
curing uncured chlorinated polyethylene
    • 固化或未固化的氯化聚乙烯组合物和固化未固化的氯化聚乙烯的方法
    • US4165416A
    • 1979-08-21
    • US781300
    • 1977-03-25
    • Yasuo MatobaAkira HashimotoMikio Sugahara
    • Yasuo MatobaAkira HashimotoMikio Sugahara
    • C08K5/17C08K5/39C08K5/37C08J3/24
    • C08K5/17C08K5/39
    • A cured or uncured chlorinated polyethylene composition free from hexamethylphosphoric triamide complex comprising (A) chlorinated polyethylene, (B) a mercaptotriazine as cross-linking agent, (C) a cross-linking accelerator selected from the group consisting of specified dithiocarbamic compounds, secondary and tertiary amines, and the carboxylates, mercaptothiazole salts, dithiocarbamates and dithiophosphates of said secondary and tertiary amines and the benzothiazylsulfenamides of said secondary amines, and (D) an acid acceptor of metal compounds; as well as a process for curing uncured chlorinated polyethylene which comprises heating same in the absence of hexamethylphosphoric triamide complex in the presence of (B), (C) and (D) at a temperature of about 120.degree. to about 200.degree. C.
    • 不含六甲基磷酰三胺络合物的固化或未固化的氯化聚乙烯组合物,其包含(A)氯化聚乙烯,(B)巯基三嗪作为交联剂,(C)交联促进剂,选自指定的二硫代氨基甲酸酯化合物,仲和 叔胺和所述仲胺和所述仲胺的苯并噻唑基亚磺酰胺的羧酸盐,巯基噻唑盐,二硫代氨基甲酸盐和二硫代磷酸盐,和(D)金属化合物的酸受体; 以及用于固化未固化的氯化聚乙烯的方法,该方法包括在(B),(C)和(D)的存在下,在约120℃至约200℃的温度下,在不存在六甲基磷酰三胺酰胺配合物的情况下对其进行加热。
    • 4. 发明授权
    • Chlorinated polyethylene composition and process for curing chlorinated
polyethylene
    • 氯化聚乙烯组合物和氯化聚乙烯固化方法
    • US4237247A
    • 1980-12-02
    • US898914
    • 1978-04-21
    • Yasuo MatobaAkira HashimotoMikio Sugahara
    • Yasuo MatobaAkira HashimotoMikio Sugahara
    • C08K5/17C08K5/39C08F8/34
    • C08K5/17C08K5/39
    • A cured or uncured chlorinated polyethylene composition free from hexamethyl-phosphoric triamide complex comprising (A) chlorinated polyethylene, (B) a mercaptotriazine as cross-linking agent, (C) a cross-linking accelerator selected from the group consisting of specified dithiocarbamic compounds, secondary and tertiary amines, and the carboxylates, mercaptothiazole salts, dithiocarbamates and dithiophosphates of said secondary and tertiary amines and the benzothiazylsulfenamides of said secondary amines, and (D) an acid acceptor of metal compounds; as well as a process for curing uncured chlorinated polyethylene which comprises heating same in the absence of hexamethylphosphoric triamide complex in the presence of (B), (C) and (C) at a temperature of about 120.degree. to about 200.degree. C.
    • 不含六甲基磷酸三酰胺络合物的固化或未固化的氯化聚乙烯组合物,其包含(A)氯化聚乙烯,(B)巯基三嗪作为交联剂,(C)交联促进剂,选自指定的二硫代氨基甲酸酯化合物, 仲胺和叔胺,以及所述仲胺和所述仲胺的苯并噻唑基亚磺酰胺的羧酸盐,巯基噻唑盐,二硫代氨基甲酸盐和二硫代磷酸盐,和(D)金属化合物的酸受体; 以及用于固化未固化的氯化聚乙烯的方法,其包括在(B),(C)和(C)存在下,在约120℃至约200℃的温度下,在不存在六甲基磷酰三胺络合物的情况下加热相同的方法。
    • 6. 发明授权
    • Curable composition of halogen-containing polymer
    • 含卤聚合物的固化组合物
    • US4342851A
    • 1982-08-03
    • US239036
    • 1981-02-27
    • Akio SuzuiYasuo Matoba
    • Akio SuzuiYasuo Matoba
    • C08K5/3445C08K5/36C08K13/02C08G65/24C08B11/22C08F8/34
    • C08K5/36C08K13/02C08K5/3445
    • A curable composition of halogen-containing polymer composed of(1) 100 parts by weight of a halogen-containing polymer,(2) as a crosslinking agent, about 0.1 to about 10 parts by weight of a 2,4-dithiohydantoin having the formula ##STR1## wherein R.sub.1 and R.sub.2 are identical or different and represent a member selected from the class consisting of a hydrogen atom, C.sub.1 -C.sub.8 alkyl groups, C.sub.6 -C.sub.8 cycloalkyl groups, C.sub.2 -C.sub.8 alkenyl groups, C.sub.6 -C.sub.8 aryl groups and C.sub.7 -C.sub.8 aralkyl groups, or R.sub.1 and R.sub.2 are bonded together to form a 5- or 7-membered hydrocarbon ring which may contain a nitrogen atom and have at least one lower alkyl group as a substituent,or a metal salt thereof, and(3) as an acid acceptor, about 0.5 to about 50 parts by weight of a compound of a metal of Group II of IVa of the periodic table.
    • 含有卤素的聚合物的可固化组合物由(1)100重量份的含卤聚合物,(2)作为交联剂组成,约0.1至约10重量份的2,4-二硫乙内酰脲,其具有式 (I)其中R 1和R 2相同或不同,并且表示选自氢原子,C 1 -C 8烷基,C 6 -C 8环烷基,C 2 -C 8烯基,C 6 -C 8芳基 基团和C7-C8芳烷基,或R1和R2键合在一起形成可含有氮原子并具有至少一个低级烷基作为取代基的5-或7-元烃环或其金属盐, 和(3)作为酸受体,约0.5至约50重量份的周期表IVa族II族金属的化合物。
    • 10. 发明授权
    • Composition for hologram-recording material, hologram-recording medium, and process for producing the same
    • 全息记录材料的组合物,全息记录介质及其制造方法
    • US07361432B2
    • 2008-04-22
    • US10470771
    • 2002-01-30
    • Hideo TanigawaYasuo MatobaTetsuyuki SaikaTakashi MatsuoKazunori Yokoyama
    • Hideo TanigawaYasuo MatobaTetsuyuki SaikaTakashi MatsuoKazunori Yokoyama
    • G03H1/02
    • C08F2/44G03F7/001G03F7/027G03F7/032G03F7/033G03H1/02G03H2001/0264G03H2260/12
    • An object of the present invention is to provide a hologram recording material composition comprising a radical polymerizable compound being solid at an ordinary temperature and having a 9,9-diarylflourene skeleton, a polymeric binder and a plasticizer, the composition being excellent in transparency and diffraction efficiency, which are characteristics required for a hologram.The hologram recording material composition comprises a thermoplastic resin (A) which is soluble in a solvent, a radical polymerizable compound (B) which is solid at an ordinary temperature and at ordinary pressure and has the 9,9-diarylfluorene skeleton and at least one radical polymerizable unsaturated double bond, a plasticizer (C) and a photopolymerization initiator (D). A weight percentage ratio of the thermoplastic resin (A), the radical polymerizable compound (B) and the plasticizer (C), (A):(B):(C) is 10 to 80:10 to 80:10 to 80. A refractive index of the radical polymerizable compound (B) is larger than a weighted mean of that of the thermoplastic resin (A) and that of the plasticizer (C).
    • 本发明的目的是提供一种全息记录材料组合物,其包含在常温下为固体且具有9,9-二芳基芳烃骨架的自由基聚合性化合物,聚合物粘合剂和增塑剂,所述组合物的透明度和衍射优良 效率,这是全息图所需的特性。 全息记录材料组合物包含可溶于溶剂的热塑性树脂(A),在常温常压下为固体的具有9,9-二芳基芴骨架的自由基聚合性化合物(B)和至少一种 自由基聚合性不饱和双键,增塑剂(C)和光聚合引发剂(D)。 热塑性树脂(A),自由基聚合性化合物(B)和增塑剂(C),(A):( B):( C)的重量比为10〜80:10〜80:10〜80。 自由基聚合性化合物(B)的折射率大于热塑性树脂(A)和增塑剂(C)的折射率的加权平均值。