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    • 4. 发明授权
    • Optical waveguide forming material and method
    • 光波导形成材料及方法
    • US07283715B2
    • 2007-10-16
    • US10911686
    • 2004-08-05
    • Kinya KodamaTsutomu KashiwagiToshio Shiobara
    • Kinya KodamaTsutomu KashiwagiToshio Shiobara
    • G02B6/10G02B6/00
    • G02B6/138C03C17/30G02B1/046C08L83/06
    • An optical waveguide comprising a substrate, a lower clad layer on the substrate, a core layer and an upper clad layer, at least one of the lower clad layer, the core layer and the upper clad layer is formed of a cured product of a photo-curable organopolysiloxane composition comprising(A) a (meth)acryloyloxy group-containing organopolysiloxane of the following average compositional formula (1): (CH2═CR1COO(CH2)n)a(Ph)bR2c(R3O)dSiO(4-a-b-c-d)/2  (1) wherein R1 is hydrogen or methyl, R2 is an C1–C8 alkyl or C2–C8 alkenyl group, Ph is phenyl, R3 is hydrogen or an unsubstituted or alkoxy-substituted C1–C4 alkyl group, subscripts a, b, c and d are numbers satisfying: 0.05≦a≦0.9, 0.1≦b≦0.9, 0≦c≦0.2, 0
    • 一种光波导,包括基板,基底上的下覆盖层,芯层和上覆盖层,下包层,芯层和上覆层中的至少一个由照相的固化产物形成 可固化的有机基聚硅氧烷组合物,其包含(A)具有以下平均组成式(1)的(甲基)丙烯酰氧基的有机聚硅氧烷:<?在线式描述=“在线式”末端=“铅” CH 2 CO 2(CH 2)n(CH 2)n(CH 2)n(CH 2) ) (4-abcd)/ 2(1)<?in-line-formula description =“In-line Formulas”end =“tail”?>其中R 1是氢或甲基 R 2是C 1 -C 8烷基或C 2 -C 8烷基或C 2 -C 8烷基, SUB>烯基,Ph是苯基,R 3是氢或未取代或烷氧基取代的C 1 -C 4烷基,下标 a,b,c和d是麻木的 满足:0.05 <= a <= 0.9,0.1 <= b <= 0.9,0 <= c <= 0.2,0
    • 6. 发明授权
    • Organopolysilmethylene-siloxane and a cured product thereof
    • 有机聚硅氧烷 - 硅氧烷及其固化物
    • US08497024B2
    • 2013-07-30
    • US12860682
    • 2010-08-20
    • Manabu UenoToshio ShiobaraTsutomu Kashiwagi
    • Manabu UenoToshio ShiobaraTsutomu Kashiwagi
    • B32B9/04
    • C08G77/50C08G77/16C08G77/18C08G77/24C08L83/14Y10T428/31663C08L83/00
    • Organopolysilmethylene-siloxane of the formula (1): wherein each R1 is, independently of one another, an unsubstituted or substituted monovalent hydrocarbon group having 1 to 10 carbon atoms other than an alkenyl group, an alkoxy group, a hydroxy group, and a halogen atom; each R2 is, independently of one another, an unsubstituted or substituted monovalent hydrocarbon group having 1 to 10 carbon atoms other than an alkenyl group, an alkoxy group, a hydroxy group, a halogen atom, and (R1)3SiCH2—, wherein each R3 is, independently of one another, a hydrogen atom and an alkyl group having 1 to 4 carbon atoms; k is an integer of 1 to 100; and n is an integer of 1 to 1000; said organopolysilmethylene-siloxane having, in a molecule, at least two out of alkoxy groups, hydroxy groups, and halogen atoms bonded to one or more silicon atoms.
    • 式(1)的有机聚硅氧烷 - 硅氧烷:其中每个R 1彼此独立地是除烯基,烷氧基,羟基和卤素以外的未取代或取代的碳原子数1〜10的一价烃基 原子; 每个R 2彼此独立地是除烯基,烷氧基,羟基,卤素原子和(R 1)3 SiCH 2 - 以外具有1至10个碳原子的未取代或取代的一价烃基,其中每个R 3 彼此独立地是氢原子和具有1至4个碳原子的烷基; k为1〜100的整数, n为1〜1000的整数。 所述有机聚硅氧烷 - 硅氧烷在分子中具有至少两个烷氧基,羟基和与一个或多个硅原子键合的卤素原子。
    • 9. 发明授权
    • Phosphor-filled curable silicone resin composition and cured product thereof
    • 荧光填充固化性有机硅树脂组合物及其固化物
    • US07705093B2
    • 2010-04-27
    • US11762445
    • 2007-06-13
    • Tsutomu KashiwagiToshio Shiobara
    • Tsutomu KashiwagiToshio Shiobara
    • C08G77/04
    • C08L83/04C08G77/12C08G77/20C08G77/70C08K3/32C08L83/00
    • A phosphor-containing addition-curable silicone resin composition is provided. The composition is capable of forming a cured product which exhibits excellent crack resistance and shock resistance, and minimal surface tackiness. The composition includes (A) an organopolysiloxane including R1SiO1.5 units (T units), R22SiO units (D units), and R3aR4bSiO(4-a-b)/2 units (wherein, R1, R2 and R3 represent a methyl group or the like, R4 represents a vinyl group or allyl group, a represents an integer from 0 to 2, b represents 1 or 2, and a+b is either 2 or 3), in which the number of repetitions of the D units is within a range from 5 to 300; (B) an Si—H-containing polysiloxane including T units, D units, and R3cHdSiO(4-c-d)/2 units (wherein, c represents an integer from 0 to 2, d represents 1 or 2, and c+d is either 2 or 3), in which the number of repetitions of the D units is within a range from 5 to 300, in sufficient quantity that the molar ratio of Si-bonded hydrogen atoms within (B), relative to vinyl groups or allyl groups within (A), is within a range from 0.1 to 4.0; (C) a catalyst; and (D) a phosphor.
    • 提供含磷光体的可加成固化的有机硅树脂组合物。 该组合物能够形成表现出优异的抗裂性和抗冲击性和最小表面粘性的固化产物。 该组合物包含(A)包含R1SiO1.5单元(T单元),R22SiO单元(D单元)和R3aR4bSiO(4-ab)/ 2单元的有机聚硅氧烷(其中,R1,R2和R3表示甲基等 ,R4表示乙烯基或烯丙基,a表示0〜2的整数,b表示1或2,a + b为2或3),D单元的重复数在 从5到300; (B)包含T单元,D单元和R3cHdSiO(4-cd)/ 2单元的Si-H的聚硅氧烷(其中,c表示0至2的整数,d表示1或2,c + d为 2或3),其中D单元的重复数在5至300的范围内,其量足以使(B)内的与Si键合的氢原子相对于乙烯基或烯丙基的摩尔比 (A)范围内,为0.1〜4.0; (C)催化剂; 和(D)荧光体。