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1. 发明申请

US20100252431A1 ION-SELECTIVE ELECTRODE 失效
标题翻译：离子选择性电极
公开(公告)号：US20100252431A1
公开(公告)日：2010-10-07
申请号：US12744649
申请日：2008-12-17
申请人： Yuji Nishio , Yasukazu Iwamoto
发明人： Yuji Nishio , Yasukazu Iwamoto
IPC分类号： G01N27/26
CPC分类号： G01N27/36 , C03C3/111 , C03C4/18
摘要： Disclosed is an ion-selective electrode having excellent mechanical strength, excellent durability, low membrane resistance and good ion response accuracy. This ion-selective electrode comprises a response glass membrane which has ion selectivity and is made of an oxynitride glass containing Li.
摘要翻译：公开了具有优异的机械强度，优异的耐久性，低膜电阻和良好的离子响应精度的离子选择性电极。该离子选择电极包括具有离子选择性并由含有Li的氧氮化物玻璃制成的响应玻璃膜。

2. 发明申请

US20100259271A1 METHOD FOR MEASUREMENT OF CONTENT OF WATER OR ORGANIC ACID IN POLAR ORGANIC SOLVENT, AND APPARATUS FOR THE METHOD 失效
标题翻译：用于测量有机溶剂中水或有机酸含量的方法及方法
公开(公告)号：US20100259271A1
公开(公告)日：2010-10-14
申请号：US12743922
申请日：2008-12-26
申请人： Yuji Nishio , Yasukazu Iwamoto
发明人： Yuji Nishio , Yasukazu Iwamoto
IPC分类号： G01N27/02
CPC分类号： G01N27/414
摘要： Disclosed are a measurement method and a measurement apparatus both of which can measure the content of water or an organic acid in a polar organic solvent with high accuracy even when water or the organic acid is contained in the polar organic solvent at a low content. The content of water or an organic acid in a polar organic solvent can be measured by using, as a work electrode, an ISFET electrode in which a thin film comprising an oxide or nitride of a metal or metalloid element belonging to Groups 3 to 15 is formed on a gate.
摘要翻译：公开了一种测量方法和测量装置，即使在低含量的极性有机溶剂中含有水或有机酸的情况下，也可以高精度地测定极性有机溶剂中的水分或有机酸的含量。水或有机酸在极性有机溶剂中的含量可以通过使用作为工作电极的ISFET电极来测量，其中包含属于第3〜15族的金属或准金属元素的氧化物或氮化物的薄膜为形成在门口。

3. 发明授权

US08197651B2 Ion-selective electrode 失效
标题翻译：离子选择电极
公开(公告)号：US08197651B2
公开(公告)日：2012-06-12
申请号：US12744649
申请日：2008-12-17
申请人： Yuji Nishio , Yasukazu Iwamoto
发明人： Yuji Nishio , Yasukazu Iwamoto
IPC分类号： G01N27/333
CPC分类号： G01N27/36 , C03C3/111 , C03C4/18
摘要： Disclosed is an ion-selective electrode having excellent mechanical strength, excellent durability, low membrane resistance and good ion response accuracy. This ion-selective electrode comprises a response glass membrane which has ion selectivity and is made of an oxynitride glass containing Li.
摘要翻译：公开了具有优异的机械强度，优异的耐久性，低膜电阻和良好的离子响应精度的离子选择性电极。该离子选择电极包括具有离子选择性并由含有Li的氧氮化物玻璃制成的响应玻璃膜。

4. 发明授权

US08080315B2 Responsive glass membrane and glass electrode 有权
标题翻译：响应玻璃膜和玻璃电极
公开(公告)号：US08080315B2
公开(公告)日：2011-12-20
申请号：US12037751
申请日：2008-02-26
申请人： Yuji Nishio , Yasukazu Iwamoto , Tadanori Hashimoto
发明人： Yuji Nishio , Yasukazu Iwamoto , Tadanori Hashimoto
IPC分类号： B32B3/26 , B32B17/06
CPC分类号： G01N27/36 , Y10T428/24999
摘要： An ion-selective electrode has a responsive glass membrane with an exterior thin film containing titanium dioxide of an anatase type that is continuously formed as an integrated body. The thin film, of several hundred nm in numbers, is electrically connected by an amount of titanium dioxide that will form a continuity in the thin film structure. The thin film can be porous and contain at least one metal selected from cobalt, nickel, tungsten, copper, platinum, gold, silver and iron. Additionally, significantly larger titanium dioxide particles of 0.02 μm in diameter can be further mixed into the thin film.
摘要翻译：离子选择性电极具有响应性玻璃膜，其具有外部薄膜，该外部薄膜包含连续形成为整体的锐钛矿型二氧化钛。数百nm的薄膜通过一定量的二氧化钛电连接，这将形成薄膜结构的连续性。薄膜可以是多孔的并且含有选自钴，镍，钨，铜，铂，金，银和铁中的至少一种金属。另外，直径0.02μm的显着更大的二氧化钛颗粒可以进一步混入薄膜中。

5. 发明申请

US20080206547A1 RESPONSIVE GLASS MEMBRANE AND GLASS ELECTRODE 有权
标题翻译：响应玻璃膜和玻璃电极
公开(公告)号：US20080206547A1
公开(公告)日：2008-08-28
申请号：US12037751
申请日：2008-02-26
申请人： Yuji Nishio , Yasukazu Iwamoto , Tadanori Hashimoto
发明人： Yuji Nishio , Yasukazu Iwamoto , Tadanori Hashimoto
IPC分类号： B32B3/26 , B32B17/06
CPC分类号： G01N27/36 , Y10T428/24999
摘要： This invention intends to provide a responsive glass membrane and a glass electrode comprising the responsive glass membrane to which taint is hardly attached and easily detached without hindering a function of measuring the ionic concentration. A thin film containing titanium dioxide of an anatase type is formed on a surface of the responsive glass membrane and whole of the thin film is continuously formed to be an integrated body.
摘要翻译：本发明旨在提供一种响应性玻璃膜和玻璃电极，其包含难以附着和容易分离的响应性玻璃膜，而不会妨碍测量离子浓度的功能。在响应性玻璃膜的表面上形成含有锐钛矿型二氧化钛的薄膜，并且将整个薄膜连续地形成为一体。

6. 发明授权

US08436622B2 Method for measurement of content of water or organic acid in polar organic solvent, and apparatus for the method 失效
标题翻译：用于测量极性有机溶剂中水或有机酸含量的方法，以及该方法的装置
公开(公告)号：US08436622B2
公开(公告)日：2013-05-07
申请号：US12743922
申请日：2008-12-26
申请人： Yuji Nishio , Yasukazu Iwamoto
发明人： Yuji Nishio , Yasukazu Iwamoto
IPC分类号： G01N27/02 , G01N27/00
CPC分类号： G01N27/414
摘要： Disclosed are a measurement method and a measurement apparatus both of which can measure the content of water or an organic acid in a polar organic solvent with high accuracy even when water or the organic acid is contained in the polar organic solvent at a low content. The content of water or an organic acid in a polar organic solvent can be measured by using, as a work electrode, an ISFET electrode in which a thin film comprising an oxide or nitride of a metal or metalloid element belonging to Groups 3 to 15 is formed on a gate.
摘要翻译：公开了一种测量方法和测量装置，即使在低含量的极性有机溶剂中含有水或有机酸的情况下，也可以高精度地测定极性有机溶剂中的水分或有机酸的含量。水或有机酸在极性有机溶剂中的含量可以通过使用作为工作电极的ISFET电极来测量，其中包含属于第3〜15族的金属或准金属元素的氧化物或氮化物的薄膜为形成在门口。

7. 发明授权

US07976690B2 Method for production of responsive glass membrane for ion electrode, responsive glass membrane for ion electrode, and ion electrode 有权
标题翻译：用于离子电极的响应玻璃膜，用于离子电极的响应性玻璃膜和离子电极的制造方法
公开(公告)号：US07976690B2
公开(公告)日：2011-07-12
申请号：US12518630
申请日：2007-12-11
申请人： Yuji Nishio , Yasukazu Iwamoto , Tadanori Hashimoto
发明人： Yuji Nishio , Yasukazu Iwamoto , Tadanori Hashimoto
IPC分类号： G01N27/333 , G01N27/36 , C03B19/09 , C03B32/02 , B32B17/06
CPC分类号： G01N27/36 , C03B9/31 , C03C17/23 , C03C17/256 , C03C2217/212 , C03C2218/17
摘要： Disclosed is a sensitive glass film for a pH electrode, which is not deteriorated in its glass strength or pH-measuring function, which is hardly stained, and from which any stain can be removed easily. Also disclosed is a pH electrode having the sensitive glass film. A microparticle comprising rutile-type or brookite-type titanium dioxide or a microparticle comprising amorphous titanium dioxide is adhered directly on the glass film surface of a sensitive glass film for a pH electrode.
摘要翻译：公开了用于pH电极的敏感性玻璃膜，其玻璃强度或pH测量功能不劣化，其几乎不被染色，并且可以容易地除去任何污渍。还公开了具有敏感玻璃膜的pH电极。包含金红石型或板钛矿型二氧化钛的微粒或包含无定形二氧化钛的微粒直接粘附在用于pH电极的敏感玻璃膜的玻璃膜表面上。

8. 发明申请

US20100051053A1 WASHING STORAGE SOLUTION FOR GLASS ELECTRODE AND THE LIKE 审中-公开
标题翻译：用于玻璃电极的洗涤储存溶液和类似物
公开(公告)号：US20100051053A1
公开(公告)日：2010-03-04
申请号：US12513160
申请日：2007-11-07
申请人： Yuji Nishio , Yasukazu Iwamoto
发明人： Yuji Nishio , Yasukazu Iwamoto
IPC分类号： C03C23/00
CPC分类号： G01N27/36 , G01N27/38
摘要： This invention provides a washing storage solution (22), which can substantially completely remove contaminants such as transition metals and alkali metals deposited on the surface of a glass electrode that comprises a glass comprising lithium and can restore performances as an electrode such as responsiveness and reproducibility in the measurement to an initial state or a state better than the initial state. The washing storage solution (22) is characterized by comprising at least one reducing reagent having a reduction behavior. Examples of reducing reagents include hydroxylammonium chloride, sodium hyposulfite, sodium hydrogen sulfite, sodium thiosulfate, sodium hypophosphite, ascorbic acid, and titanium oxide.
摘要翻译：本发明提供了一种洗涤储存溶液（22），其可以基本上完全去除沉积在包含锂的玻璃的玻璃电极的表面上的过渡金属和碱金属的污染物，并且可以恢复作为电极的性能，例如响应性和再现性在测量到初始状态或状态比初始状态好。洗涤储存溶液（22）的特征在于包含至少一种具有还原性能的还原剂。还原剂的实例包括羟基氯化铵，亚硫酸氢钠，亚硫酸氢钠，硫代硫酸钠，次磷酸钠，抗坏血酸和氧化钛。

9. 发明授权

US07547379B2 Responsive glass membrane for ion selective electrode and ion selective electrode 失效
标题翻译：用于离子选择电极和离子选择电极的响应玻璃膜
公开(公告)号：US07547379B2
公开(公告)日：2009-06-16
申请号：US12037745
申请日：2008-02-26
申请人： Yuji Nishio , Yasukazu Iwamoto , Tadanori Hashimoto
发明人： Yuji Nishio , Yasukazu Iwamoto , Tadanori Hashimoto
IPC分类号： G01N27/333 , G01N27/36
CPC分类号： G01N27/36 , C03C3/21 , C03C4/18
摘要： The present claimed invention intends to provide a responsive glass membrane for ion selective electrode glass and an ion selective electrode comprising the responsive glass membrane that produces a self-cleaning function when the ultraviolet rays are irradiated although no change is brought in a composition of a sample solution as being an object to be measured and that is low in electric resistance value and superior in responsivity under an ordinary measurement environment.The responsive glass membrane for ion selective electrode is made of the titanium-containing oxide glass that contains 20˜80 mol % of titanium dioxide and lithium oxide.
摘要翻译：本发明的目的在于提供一种用于离子选择性电极玻璃的响应玻璃膜和一种离子选择电极，其包括响应性玻璃膜，其在照射紫外线时产生自清洁功能，尽管样品组成没有变化溶液作为测量对象，并且在普通测量环境下的电阻值低和响应性优异。用于离子选择电极的响应性玻璃膜由含有20〜80摩尔％的二氧化钛和氧化锂的含钛氧化物玻璃制成。

10. 发明授权

US08262877B2 Glass electrode and sensitive glass for the glass electrode 有权
标题翻译：用于玻璃电极的玻璃电极和敏感玻璃
公开(公告)号：US08262877B2
公开(公告)日：2012-09-11
申请号：US12440234
申请日：2007-09-06
申请人： Yasukazu Iwamoto , Yuji Nishio
发明人： Yasukazu Iwamoto , Yuji Nishio
IPC分类号： G01N27/26 , C03C3/095 , C03C3/15
CPC分类号： G01N27/36 , C03C3/095 , C03C4/18
摘要： Disclosed is a sensitive glass for use in a pH-sensitive glass electrode, which comprises at least Me2O3 (Me represents a lanthanoid) and further comprises Y2O3 or Sc2O3 in an amount smaller than that of the Me2O3. Also disclosed is a sensitive glass for use in a cation-sensitive glass electrode, which comprises at least Y2O3 or Sc2O3.
摘要翻译：公开了一种用于pH敏感玻璃电极的敏感玻璃，其至少含有Me 2 O 3（Me表示镧系元素），并且还含有少于Me 2 O 3的量的Y 2 O 3或Sc 2 O 3。还公开了一种用于阳离子敏感性玻璃电极的敏感玻璃，其至少包括Y 2 O 3或Sc 2 O 3。

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