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1. 发明申请

US20120256117A1 CONDUCTIVE POLYMER SUSPENSION AND METHOD FOR PRODUCING THE SAME, CONDUCTIVE ORGANIC MATERIAL, AND ELECTROLYTIC CAPACITOR AND METHOD FOR PRODUCING THE SAME 有权
标题翻译：导电聚合物悬浮体及其制造方法，导电有机材料和电解电容器及其制造方法
公开(公告)号：US20120256117A1
公开(公告)日：2012-10-11
申请号：US13083001
申请日：2011-04-08
申请人： Yasuhisa SUGAWARA , Tomoki Nobuta , Naoki Takahashi , Yuji Yoshida , Satoshi Suzuki , Yasuhiro Tomioka
发明人： Yasuhisa SUGAWARA , Tomoki Nobuta , Naoki Takahashi , Yuji Yoshida , Satoshi Suzuki , Yasuhiro Tomioka
IPC分类号： H01B1/12 , B05D5/12 , H01G9/025
CPC分类号： H01G9/028 , H01B1/127
摘要： Provided are an electroconductive polymer suspension solution and a method for producing the same, which has excellent adhesion to a substrate and excellent liquid resistance and which can provide an organic material having high electroconductivity. An electroconductive polymer suspension solution of an exemplary embodiment of the invention contains an electroconductive polymer, at least one kind of a water-soluble polyhydric alcohol, and at least one kind of a water-soluble organic substance having two or more functional groups which can be polycondensed with the water-soluble polyhydric alcohol. The electroconductive polymer suspension solution can be produced by collecting an electroconductive polymer which is obtained by chemical oxidative polymerization of a monomer giving the electroconductive polymer by using an oxidant in a solvent containing an organic acid or a salt thereof as a dopant, by contacting the electroconductive polymer with an oxidant in an aqueous solvent containing a polyacid, and further by mixing at least one kind of a water-soluble polyhydric alcohol and at least one kind of a water-soluble organic substance having two or more functional groups which can be polycondensed with the water-soluble polyhydric alcohol.
摘要翻译：提供一种导电聚合物悬浮液及其制造方法，其具有优异的对基材的粘附性和优异的耐液性，并且可以提供具有高导电性的有机材料。本发明的一个示例性实施方案的导电聚合物悬浮液包含导电聚合物，至少一种水溶性多元醇和至少一种具有两个或更多个官能团的水溶性有机物质，其可以是与水溶性多元醇缩合。导电聚合物悬浮液可以通过收集导电聚合物来制备，导电聚合物通过使含氧有机酸或其盐作为掺杂剂的溶剂中的氧化剂通过化学氧化聚合得到导电聚合物而获得，聚合物与含有多酸的水性溶剂中的氧化剂反应，进一步通过混合至少一种水溶性多元醇和至少一种具有两个或更多个官能团的水溶性有机物质，所述官能团可以与水溶性多元醇。

2. 发明申请

US20110182002A1 CONDUCTIVE POLYMER SUSPENSION AND METHOD FOR PRODUCING THE SAME, CONDUCTIVE POLYMER MATERIAL, AND SOLID ELECTROLYTIC CAPACITOR AND METHOD FOR PRODUCING THE SAME 有权
标题翻译：导电聚合物悬浮液及其制造方法，导电聚合物材料和固体电解电容器及其制造方法
公开(公告)号：US20110182002A1
公开(公告)日：2011-07-28
申请号：US13013361
申请日：2011-01-25
申请人： Naoki TAKAHASHI , Tomoki NOBUTA , Yasuhisa SUGAWARA , Yuji YOSHIDA , Satoshi SUZUKI , Yasuhiro TOMIOKA
发明人： Naoki TAKAHASHI , Tomoki NOBUTA , Yasuhisa SUGAWARA , Yuji YOSHIDA , Satoshi SUZUKI , Yasuhiro TOMIOKA
IPC分类号： H01G4/06 , H01B1/12 , B05D5/12
CPC分类号： H01G9/0036 , C08G2261/3223 , C08G2261/794 , C08K5/24 , C08L25/18 , C08L65/00 , H01G9/028 , H01G9/15 , H01G11/48 , H01G11/56 , Y02E60/13
摘要： The present invention provides a conductive polymer suspension for providing a conductive polymer material having high conductivity and a method for producing the same, and particularly provides a solid electrolytic capacitor having low ESR and a method for producing the same. In an emulsion comprising a dopant of a low molecular organic acid or a salt thereof, obtained by emulsifying a monomer providing a conductive polymer, using a nonionic surfactant, in a water, the monomer is subjected to chemical oxidative polymerization, using an oxidant, to synthesize a conductive polymer. The obtained conductive polymer is purified, and then, the purified conductive polymer and an oxidant are mixed in an aqueous solvent containing a polyacid component to produce a conductive polymer suspension.
摘要翻译：本发明提供一种用于提供具有高导电性的导电聚合物材料的导电聚合物悬浮体及其制造方法，特别是提供一种具有低ESR的固体电解电容器及其制造方法。在包含低分子有机酸或其盐的掺杂剂的乳液中，通过使用非离子表面活性剂在水中乳化提供导电聚合物的单体获得，使用氧化剂对单体进行化学氧化聚合合成导电聚合物。纯化得到的导电性聚合物，然后将纯化的导电性聚合物和氧化剂混合在含有多元酸成分的水性溶剂中，制造导电性高分子悬浮液。

3. 发明申请

US20110122546A1 CONDUCTIVE POLYMER SUSPENSION AND METHOD FOR PRODUCING THE SAME, CONDUCTIVE POLYMER MATERIAL, ELECTROLYTIC CAPACITOR, AND SOLID ELECTROLYTIC CAPACITOR AND METHOD FOR PRODUCING THE SAME 审中-公开
标题翻译：导电聚合物悬浮体及其制造方法，导电聚合物材料，电解电容器和固体电解电容器及其制造方法
公开(公告)号：US20110122546A1
公开(公告)日：2011-05-26
申请号：US12951379
申请日：2010-11-22
申请人： Tomoki NOBUTA , Naoki TAKAHASHI , Yasuhisa SUGAWARA , Yuji YOSHIDA , Satoshi SUZUKI , Yasuhiro TOMIOKA
发明人： Tomoki NOBUTA , Naoki TAKAHASHI , Yasuhisa SUGAWARA , Yuji YOSHIDA , Satoshi SUZUKI , Yasuhiro TOMIOKA
IPC分类号： H01G9/15 , H01B1/12 , H01G9/022 , B05D5/12
CPC分类号： H01G9/15 , C08G2261/3223 , C08G2261/794 , C08K5/053 , C08L25/18 , C08L65/00 , H01G9/028 , H01G11/48 , H01G11/56 , Y02E60/13 , C08L2666/22 , C08L2666/06
摘要： Provided are a conductive polymer suspension for providing a conductive polymer material having a high conductivity and a method for producing the same, and in particular, a solid electrolytic capacitor having a low ESR and a method for producing the same. The conductive polymer suspension is produced as follows: a conductive polymer is synthesized by chemical oxidative polymerization of a monomer giving a conductive polymer by using an oxidant in a solvent containing a dopant consisting of polysulfonic acid or a salt thereof; the conductive polymer is purified; and the purified conductive polymer is mixed with an oxidant in an aqueous solvent containing a polyacid component.
摘要翻译：提供一种用于提供具有高导电性的导电聚合物材料的导电聚合物悬浮液及其制备方法，特别是具有低ESR的固体电解电容器及其制备方法。导电聚合物悬浮液如下制备：导电聚合物通过在含有由聚磺酸或其盐组成的掺杂剂的溶剂中使用氧化剂的单体得到导电聚合物的化学氧化聚合来合成; 导电聚合物被纯化; 并且将纯化的导电聚合物与含有多元酸成分的水性溶剂中的氧化剂混合。

4. 发明申请

US20110233450A1 CONDUCTIVE POLYMER AND METHOD FOR PRODUCING THE SAME, CONDUCTIVE POLYMER DISPERSION, AND SOLID ELECTROLYTIC CAPACITOR AND METHOD FOR PRODUCING THE SAME 审中-公开
标题翻译：导电聚合物及其制造方法，导电聚合物分散体和固体电解电容器及其制造方法
公开(公告)号：US20110233450A1
公开(公告)日：2011-09-29
申请号：US13070011
申请日：2011-03-23
申请人： Tomoki NOBUTA , Yasuhisa SUGAWARA , Yuji YOSHIDA , Satoshi SUZUKI , Yasuhiro TOMIOKA
发明人： Tomoki NOBUTA , Yasuhisa SUGAWARA , Yuji YOSHIDA , Satoshi SUZUKI , Yasuhiro TOMIOKA
IPC分类号： H01G9/022 , H01B1/12
CPC分类号： H01G9/0036 , C08G2261/3223 , C08G2261/794 , C08L79/04 , H01G9/028 , H01G9/15 , H01G11/48 , H01G11/56 , Y02E60/13
摘要： The present exemplary embodiment provides a conductive polymer having high conductivity and a method for producing the same, and a conductive polymer dispersion, and further provides a solid electrolytic capacitor having low ESR and a method for producing the same. A conductive polymer is produced by a method including the steps of dissolving a sulfonic acid group-containing resin having a weight average molecular weight of 2,000 or more and 50,000 or less and a compound represented by the following formula (1) in a solvent; mixing at least one monomer selected from pyrrole, thiophene, and derivatives thereof in an obtained solution; subjecting the monomer to chemical oxidative polymerization, using a persulfate, to obtain a conductive polymer; and washing the conductive polymer to remove the compound represented by the formula (1) contained in the conductive polymer. CnHn+2(OH)n (1) wherein n represents an integer of 3 to 6.
摘要翻译：本示例性实施方案提供了具有高导电性的导电聚合物及其制备方法和导电聚合物分散体，并且还提供了具有低ESR的固体电解电容器及其制备方法。通过包括以下步骤的方法制备导电聚合物：将重均分子量为2,000以上且50,000以下的含磺酸基的树脂和由下式（1）表示的化合物溶解在溶剂中; 将所选溶液中选自吡咯，噻吩及其衍生物的至少一种单体混合; 使用过硫酸盐使单体进行化学氧化聚合，得到导电性聚合物; 并洗涤导电聚合物以除去导电聚合物中所含的由式（1）表示的化合物。 CnHn + 2（OH）n（1）其中n表示3至6的整数。

5. 发明申请

US20100033906A1 CONDUCTIVE POLYMER SUSPENSION AND METHOD FOR PRODUCING THE SAME, CONDUCTIVE POLYMER MATERIAL, ELECTROLYTIC CAPACITOR, AND SOLID ELECTROLYTIC CAPACITOR AND METHOD FOR PRODUCING THE SAME 有权
标题翻译：导电聚合物悬浮体及其制造方法，导电聚合物材料，电解电容器和固体电解电容器及其制造方法
公开(公告)号：US20100033906A1
公开(公告)日：2010-02-11
申请号：US12510531
申请日：2009-07-28
申请人： Tomoki NOBUTA , Ryuta KOBAYAKAWA , Naoki TAKAHASHI , Yasuhisa SUGAWARA , Satoshi SUZUKI , Toshihiko NISHIYAMA
发明人： Tomoki NOBUTA , Ryuta KOBAYAKAWA , Naoki TAKAHASHI , Yasuhisa SUGAWARA , Satoshi SUZUKI , Toshihiko NISHIYAMA
IPC分类号： H01G9/045 , H01B1/12 , H01G9/025 , B05D5/12 , H01G9/00
CPC分类号： H01B1/122 , C08L65/00 , H01B1/127 , H01G9/0036 , H01G9/028 , H01G9/15 , H01L51/0037 , C08L2666/06
摘要： The present invention provides a conductive polymer suspension for providing a conductive polymer material having a high conductivity and a method for producing the same, and in particular, a solid electrolytic capacitor having a low ESR and a method for producing the same. The conductive polymer suspension can be is produced by: synthesizing a conductive polymer by chemical oxidative polymerization of a monomer giving the conductive polymer by using an oxidant in an aqueous solvent containing a dopant consisting of a low-molecular organic acid or a salt thereof, or a polyacid having a weight average molecular weight of less than 2,000 or a salt thereof.
摘要翻译：本发明提供一种用于提供具有高导电性的导电聚合物材料和其制备方法的导电聚合物悬浮体，特别是具有低ESR的固体电解电容器及其制备方法。导电聚合物悬浮液可以通过以下方法制备：通过在含有由低分子有机酸或其盐组成的掺杂剂的水性溶剂中使用氧化剂，通过化学氧化聚合单体得到导电聚合物来合成导电聚合物，或重均分子量小于2,000的多元酸或其盐。

6. 发明申请

US20100297340A1 METHOD FOR PRODUCING SOLID ELECTROLYTIC CAPACITOR 审中-公开
标题翻译：生产固体电解电容器的方法
公开(公告)号：US20100297340A1
公开(公告)日：2010-11-25
申请号：US12780108
申请日：2010-05-14
申请人： Satoshi SUZUKI , Tomoki NOBUTA , Naoki TAKAHASHI , Yasuhisa SUGAWARA , Ryuta KOBAYAKAWA , Akiko OSHIMA
发明人： Satoshi SUZUKI , Tomoki NOBUTA , Naoki TAKAHASHI , Yasuhisa SUGAWARA , Ryuta KOBAYAKAWA , Akiko OSHIMA
IPC分类号： B05D5/12
CPC分类号： H01G9/0036 , H01G9/028 , H01G9/15
摘要： There is provided a method for producing a solid electrolytic capacitor having an improved capacitance appearance ratio by forming a conductive polymer layer in a few steps. A method for producing a solid electrolytic capacitor obtained by forming solid electrolyte layer 5 and cathode 6 on dielectric layer 2 formed on anode body 1, which is a porous body of a valve action metal, includes the step of forming precoat layer 3 by the steps of impregnating the porous body with polyacid, water washing, and drying.
摘要翻译：提供一种通过在几个步骤中形成导电聚合物层来制造具有改善的电容出现比的固体电解电容器的方法。通过在作为阀作用金属的多孔体的阳极体1上形成的电介质层2上形成固体电解质层5和阴极6而得到的固体电解电容器的制造方法包括以下工序：用多酸浸渍多孔体，水洗和干燥。

7. 发明申请

US20100033905A1 CONDUCTIVE POLYMER SUSPENSION AND METHOD FOR PRODUCING THE SAME, CONDUCTIVE POLYMER MATERIAL, ELECTROLYTIC CAPACITOR, AND SOLID ELECTROLYTIC CAPACITOR AND METHOD FOR PRODUCING THE SAME 有权
标题翻译：导电聚合物悬浮体及其制造方法，导电聚合物材料，电解电容器和固体电解电容器及其制造方法
公开(公告)号：US20100033905A1
公开(公告)日：2010-02-11
申请号：US12510592
申请日：2009-07-28
申请人： Ryuta KOBAYAKAWA , Tomoki NOBUTA , Naoki TAKAHASHI , Yasuhisa SUGAWARA , Satoshi SUZUKI , Toshihiko NISHIYAMA
发明人： Ryuta KOBAYAKAWA , Tomoki NOBUTA , Naoki TAKAHASHI , Yasuhisa SUGAWARA , Satoshi SUZUKI , Toshihiko NISHIYAMA
IPC分类号： H01G9/025 , H01B1/12 , B05D5/12 , H01G9/00
CPC分类号： C08J3/07 , C08G2261/1424 , C08G2261/3243 , C08G2261/51 , C08G2261/794 , C08J3/05 , C08J2365/00 , C08K5/09 , C08K5/098 , C08K5/42 , C08L25/18 , C08L65/00 , H01B1/127 , H01G9/028 , H01G11/48 , H01G11/56 , Y02E60/13 , C08L2666/06
摘要： The present invention provides a conductive polymer suspension for providing a conductive polymer material having a high conductivity and a method for producing the same, and in particular, a solid electrolytic capacitor having a low ESR and a method for producing the same. The conductive polymer suspension is produced by: synthesizing a conductive polymer by chemical oxidative polymerization of a monomer giving the conductive polymer by using an oxidant in a solvent containing a dopant consisting of a low-molecular organic acid or a salt thereof; purifying the conductive polymer; and mixing the purified conductive polymer and an oxidant in an aqueous solvent containing a polyacid component.
摘要翻译：本发明提供一种用于提供具有高导电性的导电聚合物材料和其制备方法的导电聚合物悬浮体，特别是具有低ESR的固体电解电容器及其制备方法。导电聚合物悬浮液通过以下方法制备：通过在含有由低分子有机酸或其盐组成的掺杂剂的溶剂中使用氧化剂，通过化学氧化聚合单体得到导电聚合物来合成导电聚合物; 纯化导电聚合物; 并将纯化的导电聚合物和氧化剂在含有多酸组分的水性溶剂中混合。

8. 发明申请

US20090225499A1 CONDUCTIVE POLYMER AND SOLID ELECTROLYTIC CAPACITOR USING THE SAME 有权
标题翻译：导电聚合物和使用该固体电解电容器的固体电解电容器
公开(公告)号：US20090225499A1
公开(公告)日：2009-09-10
申请号：US12360238
申请日：2009-01-27
申请人： Naoki TAKAHASHI , Ryuta KOBAYAKAWA , Tomoki NOBUTA , Yasuhisa SUGAWARA , Satoshi SUZUKI
发明人： Naoki TAKAHASHI , Ryuta KOBAYAKAWA , Tomoki NOBUTA , Yasuhisa SUGAWARA , Satoshi SUZUKI
IPC分类号： H01G9/025 , C08G75/00
CPC分类号： H01G9/028 , C08G61/124 , C08G61/125 , C08G61/126 , H01G9/0036 , H01G11/48 , H01G11/52 , H01G11/56 , Y02E60/13 , Y10T29/41 , Y10T29/417
摘要： A conductive polymer having high conductivity and a solid electrolytic capacitor having low ESR are provided. A conductive polymer is synthesized using as a monomer a compound of a dimer to a decamer in which 3-alkyl five-membered heterocyclic rings are bonded at positions 2 and 5, being sterically controlled. Further, this conductive polymer is used as the solid electrolyte of a solid electrolytic capacitor.
摘要翻译：提供具有高导电性的导电聚合物和具有低ESR的固体电解电容器。使用空间控制的位置2和5上的三烷基五元杂环键合二聚物与十聚体的化合物作为单体合成导电聚合物。此外，该导电性聚合物用作固体电解电容器的固体电解质。

9. 发明申请

US20100065434A1 METHOD OF MANUFACTURING A SOLID ELECTROLYTIC CAPACITOR WITH A SUFFICIENTLY LOW IMPEDANCE IN A HIGH FREQUENCY RANGE 审中-公开
标题翻译：在高频范围内制造具有足够低阻抗的固体电解电容器的方法
公开(公告)号：US20100065434A1
公开(公告)日：2010-03-18
申请号：US12557612
申请日：2009-09-11
申请人： Yasuhisa SUGAWARA , Kazuyuki Katoh , Masako Ohya
发明人： Yasuhisa SUGAWARA , Kazuyuki Katoh , Masako Ohya
IPC分类号： C23C22/06
CPC分类号： H01G9/0036 , H01G9/028 , H01G9/15
摘要： In a method of manufacturing a solid electrolytic capacitor in which an electrolyte layer containing a conductive polymer is formed by chemical oxidative polymerization on a dielectric oxide film layer formed by anodizing surfaces of a valve metal, an ammonium peroxodisulfate solution adjusted to pH 6 to 8 is used as an oxidant in forming the conductive polymer layer.
摘要翻译：在通过在通过阳极氧化阀金属表面形成的电介质氧化膜层上进行化学氧化聚合而形成含有导电性聚合物的电解质层的固体电解电容器的制造方法中，调节至pH6〜8的过二硫酸铵溶液为在形成导电聚合物层时用作氧化剂。

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