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    • 2. 发明申请
    • Solar cell
    • 太阳能电池
    • US20060220059A1
    • 2006-10-05
    • US10552126
    • 2004-04-09
    • Takuya SatohTakayuki NegamiYasuhiro Hashimoto
    • Takuya SatohTakayuki NegamiYasuhiro Hashimoto
    • H01L31/00H01L29/732
    • H01L31/0749H01L31/0322Y02E10/541
    • A solar cell including a light-absorption layer of a compound semiconductor with a chalcopyrite crystal structure and having excellent characteristics such as conversion efficiency is provided. The solar cell includes a first electrode layer, a second electrode layer, a p-type semiconductor layer interposed between the first electrode layer and the second electrode layer, and an n-type semiconductor layer interposed between the p-type semiconductor layer and the second electrode layer. The p-type semiconductor layer includes a compound semiconductor containing a group Ib element, a group IIIb element and a group VI element and having a chalcopyrite structure. The bandgap of the p-type semiconductor layer increases from the n-type semiconductor layer side to the first electrode layer side monotonically. The bandgap of the p-type semiconductor layer on the main surface at the n-type semiconductor layer side is at least 1.08 eV, and the bandgap of the p-type semiconductor layer on the main surface at the first electrode layer side is at least 1.17 eV. In the p-type semiconductor layer, a first region at the n-type semiconductor layer side and a second region at the first electrode layer side are different from each other in bandgap increase rate in a direction of thickness of the p-type semiconductor layer.
    • 提供一种太阳能电池,其包括具有黄铜矿晶体结构的化合物半导体的光吸收层,并且具有优异的特性如转换效率。 太阳能电池包括第一电极层,第二电极层,介于第一电极层和第二电极层之间的p型半导体层,以及插入在p型半导体层和第二电极层之间的n型半导体层 电极层。 p型半导体层包括含有Ib族元素,IIIb族元素和VI族元素并具有黄铜矿结构的化合物半导体。 p型半导体层的带隙从n型半导体层侧单调增加到第一电极层侧。 n型半导体层侧的主面上的p型半导体层的带隙为1.08eV以上,第一电极层侧的主面上的p型半导体层的带隙为至少 1.17 eV 在p型半导体层中,在p型半导体层的厚度方向上的n型半导体层侧的第一区域和第一电极层侧的第二区域的带隙增加率彼此不同 。
    • 4. 发明申请
    • Compound semiconductor film, solar cell, and methods for producing those
    • 化合物半导体膜,太阳能电池及其制造方法
    • US20060261383A1
    • 2006-11-23
    • US10560801
    • 2004-11-30
    • Yasuhiro HashimotoTakuya SatohTakayuki Negami
    • Yasuhiro HashimotoTakuya SatohTakayuki Negami
    • H01L29/80
    • H01L31/02966H01L31/0322H01L31/0749H01L31/1832Y02E10/541Y02P70/521
    • A compound semiconductor film is formed with a compound containing: A. at least one element selected from zinc, tin, cadmium, indium, and gallium; B. at least one element selected from oxygen and sulfur; and C. an element of Group IIa. A solar cell is configured to include: a substrate (11); a conductive layer (12) formed on the substrate (11); a light-absorption layer (13) that is formed on the conductive layer (12) with a compound semiconductor containing an element of Group Ib, an element of Group IIIa, and an element of Group VIa; the above-described compound semiconductor film (14) formed on the light-absorption layer (13); and a transparent conductive layer (16) formed on the compound semiconductor film (14). Such a configuration provides a compound semiconductor film having a low electric resistivity. Further by employing the compound semiconductor film having a low electric resistivity as a buffer layer of a solar cell, the energy conversion efficiency of the solar cell is improved.
    • 化合物半导体膜由含有:A,选自锌,锡,镉,铟和镓中的至少一种元素的化合物形成; B.选自氧和硫中的至少一种元素; 和C.组IIa的一个要素。 太阳能电池被配置为包括:基板(11); 形成在所述基板(11)上的导电层(12); 在导电层(12)上形成有含有Ib族元素,IIIa族元素和VIa族元素的化合物半导体的光吸收层(13); 形成在光吸收层(13)上的上述化合物半导体膜(14)。 和形成在化合物半导体膜(14)上的透明导电层(16)。 这种结构提供具有低电阻率的化合物半导体膜。 此外,通过采用具有低电阻率的化合物半导体膜作为太阳能电池的缓冲层,能够提高太阳能电池的能量转换效率。