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    • 6. 发明申请
    • Method for Generating Free Radical Capable Polymers Using Tin or Silicon Halide Compounds
    • 使用锡或硅化合物生成自由基聚合物的方法
    • US20080161495A1
    • 2008-07-03
    • US11618059
    • 2006-12-29
    • James E. HallDavid F. Lawson
    • James E. HallDavid F. Lawson
    • C08F8/00
    • C08F8/42
    • Provided is a method comprising reacting the anionic living end of a polymer with a compound selected from the group consisting of tin halides and silicon halides to produced a polymer with a homolytically cleavable group containing a Sn—C bond or a Si—C bond. An engineered plastic may then be produced by adding the polymer containing a homolytically cleavable group containing a Sn—C bond or a Si—C bond to a solvent comprising at least one vinyl monomer; (b) optionally adding at least one additional inert solvent; (c) optionally adding additives selected from the group consisting of extender oils, modifiers, and antioxidants; and (d) initiating polymerization of the at least one vinyl monomer by the use of an initiator and/or heat, wherein a free radical is produced from the polymer containing a homolytically cleavable group containing a Sn—C bond or a Si—C bond.
    • 提供了一种方法,其包括使聚合物的阴离子活性端与选自卤化锡和卤化硅的化合物反应,以制备具有含Sn-C键或Si-C键的均聚裂解基团的聚合物。 然后可以通过将含有含有Sn-C键或Si-C键的均聚裂解基团的聚合物加入到包含至少一种乙烯基单体的溶剂中来制备工程塑料; (b)任选地加入至少一种另外的惰性溶剂; (c)任选地添加选自由增量油,改性剂和抗氧化剂组成的组的添加剂; 和(d)通过使用引发剂和/或加热引发至少一种乙烯基单体的聚合,其中由含有Sn-C键或Si-C键的均聚裂解基团的聚合物产生自由基 。