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    • 1. 发明申请
    • ORGANIC ELECTROLUMINESCENT DEVICE BASED ON PYRENE DERIVATIVES
    • 基于紫罗兰衍生物的有机电致发光器件
    • US20050031898A1
    • 2005-02-10
    • US10634755
    • 2003-08-06
    • Xiao-Chang LiYoshimasa OkamuraKazunori UenoMasashi TashiroHideki TashiroG.K. Prakash
    • Xiao-Chang LiYoshimasa OkamuraKazunori UenoMasashi TashiroHideki TashiroG.K. Prakash
    • C09K11/06H01L51/00H01L51/50H05B33/12H05B33/14
    • C09K11/06C09K2211/1011H01L51/0054H01L51/0058H01L51/006H01L51/0067H01L51/0094H01L51/5012H05B33/14Y10S428/917
    • A pyrene based compound and its use in an organic light emitting device (OLED) according to the following formula: In the above formula, Z1 represents a hydrogen atom, deuterium atom, oxygen atom, silicon atom, selenium atom, substituted or unsubstituted aryl group, substituted or unsubstituted heteroaryl group, substituted or unsubstituted aryl amine or a combination thereof, and Z2 represents a hydrogen or deuterium atom. One of Y1 and Y2 represents a hydrogen atom, deuterium atom, oxygen atom, silicon atom, selenium atom, a substituted or unsubstituted aryl group, substituted or unsubstituted heteroaryl group, substituted or unsubstituted aryl amine or a combination thereof, and the other of Y1 and Y2 represents a hydrogen or deuterium atom. X1 through X6 independently represent hydrogen atoms, deuterium atoms, alkyl groups or aryl groups, and at least one of X1 through X6 represents a bulky alkyl group or bulky aryl group. Also, at least one of X1 through X6, Y1, Y2, Z1, and Z2 represents a deuterium atom. The pyrene based compounds of this invention are useful in emissive layers, hole transport layers, or electron transport layers of an organic light emitting device (OLED). Within these layers, the pyrene based compound can serve directly to constitute the layers or as a host and/or dopant.
    • 芘基化合物及其在根据下式的有机发光器件(OLED)中的用途:在上式中,Z1表示氢原子,氘原子,氧原子,硅原子,硒原子,取代或未取代的芳基 取代或未取代的杂芳基,取代或未取代的芳基胺或其组合,Z 2表示氢或氘原子。 Y1和Y2之一表示氢原子,氘原子,氧原子,硅原子,硒原子,取代或未取代的芳基,取代或未取代的杂芳基,取代或未取代的芳基胺或其组合,Y1中的另一个 而Y2代表氢或氘原子。 X 1〜X 6独立地表示氢原子,氘原子,烷基或芳基,X 1〜X 6中的至少一个表示大体积的烷基或大体积的芳基。 此外,X1至X6,Y1,Y2,Z1和Z2中的至少一个表示氘原子。 本发明的芘基化合物可用于有机发光器件(OLED)的发射层,空穴传输层或电子传输层。 在这些层内,芘基化合物可以直接用于构成层或作为主体和/或掺杂剂。
    • 2. 发明授权
    • Organic electroluminescent device based on pyrene derivatives
    • 基于芘衍生物的有机电致发光器件
    • US06852429B1
    • 2005-02-08
    • US10634755
    • 2003-08-06
    • Xiao-Chang Charles LiYoshimasa OkamuraKazunori UenoMasashi TashiroHideki TashiroG. K. Surya Prakash
    • Xiao-Chang Charles LiYoshimasa OkamuraKazunori UenoMasashi TashiroHideki TashiroG. K. Surya Prakash
    • C09K11/06H01L51/00H01L51/50H05B33/12H05B33/14
    • C09K11/06C09K2211/1011H01L51/0054H01L51/0058H01L51/006H01L51/0067H01L51/0094H01L51/5012H05B33/14Y10S428/917
    • A pyrene based compound and its use in an organic light emitting device (OLED) according to the following formula: In the above formula, Z1 represents a hydrogen atom, deuterium atom, oxygen atom, silicon atom, selenium atom, substituted or unsubstituted aryl group, substituted or unsubstituted heteroaryl group, substituted or unsubstituted aryl amine or a combination thereof, and Z2 represents a hydrogen or deuterium atom. One of Y1 and Y2 represents a hydrogen atom, deuterium atom, oxygen atom, silicon atom, selenium atom, a substituted or unsubstituted aryl group, substituted or unsubstituted heteroaryl group, substituted or unsubstituted aryl amine or a combination thereof, and the other of Y1 and Y2 represents a hydrogen or deuterium atom. X1 through X6 independently represent hydrogen atoms, deuterium atoms, alkyl groups or aryl groups, and at least one of X1 through X6 represents a bulky alkyl group or bulky aryl group. Also, at least one of X1 through X6, Y1, Y2, Z1, and Z2 represents a deuterium atom. The pyrene based compounds of this invention are useful in emissive layers, hole transport layers, or electron transport layers of an organic light emitting device (OLED). Within these layers, the pyrene based compound can serve directly to constitute the layers or as a host and/or dopant.
    • 芘基化合物及其在根据下式的有机发光器件(OLED)中的用途:在上式中,Z1表示氢原子,氘原子,氧原子,硅原子,硒原子,取代或未取代的芳基 取代或未取代的杂芳基,取代或未取代的芳基胺或其组合,Z 2表示氢或氘原子。 Y1和Y2之一表示氢原子,氘原子,氧原子,硅原子,硒原子,取代或未取代的芳基,取代或未取代的杂芳基,取代或未取代的芳基胺或其组合,Y1中的另一个 而Y2代表氢或氘原子。 X 1〜X 6独立地表示氢原子,氘原子,烷基或芳基,X 1〜X 6中的至少一个表示大体积的烷基或大体积的芳基。 此外,X1至X6,Y1,Y2,Z1和Z2中的至少一个表示氘原子。 本发明的芘基化合物可用于有机发光器件(OLED)的发射层,空穴传输层或电子传输层。 在这些层内,芘基化合物可以直接用于构成层或作为主体和/或掺杂剂。
    • 10. 发明授权
    • Image pickup system
    • 摄像系统
    • US07821529B2
    • 2010-10-26
    • US10670114
    • 2003-09-24
    • Akihiko MochidaKatsuyuki SaitoMakoto TsunakawaNoboru KusamuraKotaro OgasawaraHideki Tashiro
    • Akihiko MochidaKatsuyuki SaitoMakoto TsunakawaNoboru KusamuraKotaro OgasawaraHideki Tashiro
    • A62B1/04
    • H04N5/335A61B1/05H04N2005/2255
    • To provide an image pickup system having CCDs 25 driven at different frequencies respectively which can drive each CCD 25 with a predetermined frequency if a detachable camera head (or electronic endoscope) 28 is used and also can process a signal processing clock of a video processing circuit 29 with one type of clock. A drive signal of the predetermined frequency supplied to the CCD is produced via a generating circuit CXO 155 in the video processing circuit 29, a frequency dividing circuit 132 and a timing generator (T.G.) 131. A CCD signal outputted from the CCD 25 is inputted to a line memory 139 in a floating circuit 135. As a writing clock (WCK) of the line memory 139, the one which is divided in the frequency dividing circuit 132 to a frequency in accordance with the CCD 25 to be used is used, and as a reading clock (RCK), the one of one type of frequency is used without regard to the CCD 25 to be used. Hence, it is possible to perform the signal processing of a secondary circuit 136 of the line memory 139 and following ones always with a common generating clock.
    • 为了提供具有以不同频率驱动的CCD25的图像拾取系统,其可以使用可拆卸的相机头(或电子内窥镜)28来以预定频率驱动每个CCD 25,并且还可以处理视频处理电路的信号处理时钟 29与一种类型的时钟。 通过视频处理电路29,分频电路132和定时发生器(TG)131中的发生电路CX0 155产生提供给CCD的预定频率的驱动信号。输入从CCD 25输出的CCD信号 作为浮置电路135中的行存储器139.作为行存储器139的写入时钟(WCK),使用在分频电路132中划分为与要使用的CCD 25相对应的频率的存储器, 并且作为读取时钟(RCK),使用一种类型的频率中的一种,而不考虑要使用的CCD 25。 因此,可以对行存储器139的次级电路136进行信号处理,并且可以执行以下公式的公共生成时钟。