专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明授权

US10343153B2 Metathesis catalysts and reactions using the catalysts 有权
公开(公告)号：US10343153B2
公开(公告)日：2019-07-09
申请号：US14209313
申请日：2014-03-13
申请人： XiMo AG
发明人： Levente Ondi , Jeno Varga , Agota Bucsai , Florian Toth , Krisztian Lorincz , Csaba Hegedus , Emmanuel Robe , Georg Emil Frater
IPC分类号： C07C6/02 , B01J31/22 , B01J31/16 , B01J31/18 , C07C6/04 , C07F11/00 , B01J31/14 , C08G61/08 , C07C67/293 , C07C67/347
摘要： A method is provided of forming an olefin from a first olefin and a second olefin in a metathesis reaction, comprising reacting the first olefin with the second olefin in the presence of a compound that catalyzes the metathesis reaction such that the molar ratio of the compound to the first or the second olefin is from 1:500 or less, and the conversion of the first or the second olefin to the olefin is at least 30%.

2. 发明申请

US20190119311A1 COMPOUNDS AND THE USE THEREOF IN METATHESIS REACTIONS 审中-公开
公开(公告)号：US20190119311A1
公开(公告)日：2019-04-25
申请号：US16167250
申请日：2018-10-22
申请人： XiMo AG
发明人： Florian Toth , Georg Frater , Levente Ondi
IPC分类号： C07F11/00 , B01J31/22 , C07C67/475 , C07D321/00 , C07C6/04 , C07C67/333
摘要： The disclosure provides Group 6 complexes, which, in some embodiments, are useful for catalyzing olefin metathesis reactions. In some embodiments, the compounds are compounds of the following formula: wherein: M is a Group 6 metal atom; X is an oxygen atom, ═N—R5, ═N—N(R5)(R5′) or ═N—O—R5, R5 and R5′ independently being various substituents, such as aryl or heteroaryl, each optionally substituted; n is 0 or 1; Rz is a neutral ligand; R1 is hydrogen or an organic substituent; R2 is an aryl or heteroaryl group, each optionally substituted; R3 is an anionic ligand; and R4 is an anionic ligand, such as a pyrrolide, a pyrazolide, an imidazolide, an indolide, an azaindolide, or an indazolide, each optionally substituted.

3. 发明授权

US10106566B2 Compounds and the use thereof in metathesis reactions 有权
公开(公告)号：US10106566B2
公开(公告)日：2018-10-23
申请号：US15303089
申请日：2015-04-09
申请人： XiMo AG
发明人： Florian Toth , Georg Frater , Levente Ondi
IPC分类号： C07F11/00 , B01J31/12 , B01J31/22 , C07C67/475 , C07D321/00 , C07C67/333 , C07C6/04
摘要： The disclosure provides Group 6 complexes, which, in some embodiments, are useful for catalyzing olefin metathesis reactions. In some embodiments, the compounds are compounds of the following formula (I) wherein: M is a Group 6 metal atom; X is an oxygen atom, ═N—R5, ═N—N(R5)(R5′) or ═N—O—R5, R5 and R5′ independently being various substituents, such as aryl or heteroaryl, each optionally substituted; n is 0 or 1; Rz is a neutral ligand; R1 is hydrogen or an organic substituent; R2 is an aryl or heteroaryl group, each optionally substituted; R3 is an anionic ligand; and R4 is an anionic ligand, such as a pyrrolide, a pyrazolide, an imidazolide, an indolide, an azaindolide, or an indazolide, each optionally substituted.

4. 发明授权

US11285466B2 Metathesis catalysts and reactions using the catalysts 有权
公开(公告)号：US11285466B2
公开(公告)日：2022-03-29
申请号：US16439512
申请日：2019-06-12
申请人： Ximo AG
发明人： Levente Ondi , Jeno Varga , Agota Bucsai , Florian Toth , Krisztian Lorincz , Csaba Hegedus , Emmanuel Robe , Georg Emil Frater
IPC分类号： B01J31/22 , B01J31/16 , B01J31/18 , B01J31/14 , C08G61/08 , C07C6/04 , C07F11/00 , C07C67/293 , C07C67/347
摘要： The invention relates to a method of forming an olefin from a first olefin and a second olefin in a metathesis reaction, comprising step (i): (i) reacting the first olefin with the second olefin in the presence of a compound that catalyzes said metathesis reaction such that the molar ratio of said compound to the first or the second olefin is from 1:500 or less, and the conversion of the first or the second olefin to said olefin is at least 50%, characterized in that as compound that catalyzes said metathesis reaction a compound of the following formula is used: wherein M is Mo or W; R1 is aryl, heteroaryl, alkyl, or heteroalkyl; optionally substituted; R2 and R3 can be the same or different and are hydrogen, alkyl, alkenyl, heteroalkyl, heteroalkenyl, aryl, or heteroaryl; optionally substituted; R5 is alkyl, alkoxy, heteroalkyl, aryl, heteroaryl, silylalkyl, silyloxy, optionally substituted; and R4 is a residue R6—X—, wherein X═O and R6 is aryl, optionally substituted; or X═S and R6 is aryl, optionally substituted; or X═O and R6 is (R7, R8, R9)Si; wherein R7, R8, R9 are alkyl or phenyl, optionally substituted; or X═O and R6 is (R10, R11, R12)C, wherein R10, R11, R12 are independently selected from phenyl, alkyl; optionally substituted; and to the catalysts used in the method.

5. 发明授权

US10744494B2 Immobilized metal alkylidene catalysts and use thereof in olefin metathesis 有权
公开(公告)号：US10744494B2
公开(公告)日：2020-08-18
申请号：US16062852
申请日：2016-12-23
申请人： XiMo AG
发明人： Christophe Coperet , Margherita Puccino , Victor Mougel , Michael Buchmeiser , Roman Schowner , Csaba Hegedus , Florian Toth
IPC分类号： B01J31/22 , C08G61/08 , C07F7/08 , C07F11/00 , C07C67/333 , C07D307/28 , C07C1/213 , C07C67/475 , C07C6/04 , B01J21/08
摘要： The invention relates to immobilized metal alkylidene catalysts. The catalysts are useful in olefin metathesis.

6. 发明授权

US09919299B2 Metathesis catalysts and reactions using the catalysts 有权
公开(公告)号：US09919299B2
公开(公告)日：2018-03-20
申请号：US14774404
申请日：2014-03-13
申请人： XiMo AG
发明人： Levente Ondi , Jeno Varga , Agota Bucsai , Florian Toth , Krisztian Lorincz , Csaba Hegedus , Emmanuel Robe , Georg Emil Frater
IPC分类号： B01J31/22 , C07C6/04 , B01J31/16 , B01J31/18 , C07F11/00 , B01J31/14 , C08G61/08 , C07C67/293 , C07C67/347
CPC分类号： B01J31/2265 , B01J31/143 , B01J31/1608 , B01J31/1805 , B01J31/181 , B01J31/2208 , B01J31/2226 , B01J31/223 , B01J2231/543 , B01J2531/0266 , B01J2531/0288 , B01J2531/64 , B01J2531/66 , B01J2540/20 , B01J2540/22 , B01J2540/225 , C07C6/04 , C07C67/293 , C07C67/347 , C07C2531/12 , C07C2531/22 , C07C2601/10 , C07F11/00 , C08G61/08 , C08G2261/418 , C07C11/02
摘要： The invention relates to a method of forming an olefin from a first olefin and a second olefin in a metathesis reaction, comprising step (i): (i) reacting the first olefin with the second olefin in the presence of a compound that catalyzes said metathesis reaction such that the molar ratio of said compound to the first or the second olefin is from 1:500 or less, and the conversion of the first or the second olefin to said olefin is at least 50%, characterized in that as compound that catalyzes said metathesis reaction a compound of formula (A) is used: wherein M is Mo or W; R1 is aryl, heteroaryl, alkyl, or heteroalkyl; optionally substituted; R2 and R3 can be the same or different and are hydrogen, alkyl, alkenyl, heteroalkyl, heteroalkenyl, aryl, or heteroaryl; optionally substituted; R5 is alkyl, alkoxy, heteroalkyl, aryl, heteroaryl, silylalkyl, silyloxy, optionally substituted; and R4 is a residue R6—X—, wherein X═O and R6 is aryl, optionally substituted; or X═S and R6 is aryl, optionally substituted; or X═O and R6 is (R7, R8, R9)Si; wherein R7, R8, R9 are alkyl or phenyl, optionally substituted; or X═O and R6 is (R10, R11, R12)C, wherein R10, R11, R12 are independently selected from phenyl, alkyl; optionally substituted; and to the catalysts used in the method.

7. 发明申请

US20140309466A1 METATHESIS CATALYSTS AND REACTIONS USING THE CATALYSTS 审中-公开
标题翻译：使用催化剂的METATHESIS催化剂和反应
公开(公告)号：US20140309466A1
公开(公告)日：2014-10-16
申请号：US14209313
申请日：2014-03-13
申请人： XiMo AG
发明人： Levente Ondi , Jeno Varga , Agota Bucsai , Florian Toth , Krisztian Lorincz , Csaba Hegedus , Emmanuel Robbe , Georg Emil Frater
IPC分类号： C07C6/04 , C07F11/00
CPC分类号： B01J31/2265 , B01J31/143 , B01J31/1608 , B01J31/1805 , B01J31/181 , B01J31/2208 , B01J31/2226 , B01J31/223 , B01J2231/543 , B01J2531/0266 , B01J2531/0288 , B01J2531/64 , B01J2531/66 , B01J2540/20 , B01J2540/22 , B01J2540/225 , C07C6/04 , C07C67/293 , C07C67/347 , C07C2531/12 , C07C2531/22 , C07C2601/10 , C07F11/00 , C08G61/08 , C08G2261/418 , C07C11/02
摘要： The invention relates to a method of forming an olefin from a first olefin and a second olefin in a metathesis reaction, comprising step (i): (i) reacting the first olefin with the second olefin in the presence of a compound that catalyzes said metathesis reaction such that the molar ratio of said compound to the first or the second olefin is from 1:500 or less, and the conversion of the first or the second olefin to said olefin is at least 50%, characterized in that as compound that catalyzes said metathesis reaction a compound of the following formula is used: wherein M is Mo or W; R1 is aryl, heteroaryl, alkyl, or heteroalkyl; optionally substituted; R2 and R3 can be the same or different and are hydrogen, alkyl, alkenyl, heteroalkyl, heteroalkenyl, aryl, or heteroaryl; optionally substituted; R5 is alkyl, alkoxy, heteroalkyl, aryl, heteroaryl, silylalkyl, silyloxy, optionally substituted; and R4 is a residue R6—X—, wherein X═O and R6 is aryl, optionally substituted; or X═S and R6 is aryl, optionally substituted; or X═O and R6 is (R7, R8, R9)Si; wherein R7, R8, R9 are alkyl or phenyl, optionally substituted; or X═O and R6 is (R10, R11, R12)C, wherein R10, R11, R12 are independently selected from phenyl, alkyl; optionally substituted; and to the catalysts used in the method.
摘要翻译：本发明涉及一种在复分解反应中由第一种烯烃和第二种烯烃形成烯烃的方法，包括步骤（i）：（i）在催化所述复分解的化合物存在下，使第一种烯烃与第二种烯烃反应使得所述化合物与第一或第二烯烃的摩尔比为1:500以下，第一或第二烯烃向所述烯烃的转化率为至少50％，其特征在于，作为催化剂的化合物所述复分解反应使用下式的化合物：其中M是Mo或W; R 1是芳基，杂芳基，烷基或杂烷基; 任选取代; R2和R3可以相同或不同，为氢，烷基，烯基，杂烷基，杂烯基，芳基或杂芳基; 任选取代; R5是烷基，烷氧基，杂烷基，芳基，杂芳基，甲硅烷基烷基，甲硅烷基氧基，任意取代的; R4为残基R6-X-，其中X = O和R6为芳基，任选取代; 或X = S和R 6为任选被取代的芳基; 或X = O，R6为（R7，R8，R9）Si; 其中R 7，R 8，R 9为烷基或苯基，任选取代; 或X = O，R 6为（R 10，R 11，R 12）C，其中R 10，R 11，R 12独立地选自苯基，烷基，任选取代; 以及该方法中使用的催化剂。

8. 发明申请

US20190001315A1 IMMOBILIZED METAL ALKYLIDENE CATALYSTS AND USE THEREOF IN OLEFIN METATHESIS 审中-公开
公开(公告)号：US20190001315A1
公开(公告)日：2019-01-03
申请号：US16062852
申请日：2016-12-23
申请人： XiMo AG
发明人： Christophe Coperet , Margherita Puccino , Victor Mougel , Michael Buchmeiser , Roman Schowner , Csaba Hegedus , Florian Toth
IPC分类号： B01J31/22 , B01J21/08 , C08G61/08
摘要： The invention relates to immobilized metal alkylidene catalysts. The catalysts are useful in olefin metathesis.

9. 发明申请

US20170037069A1 COMPOUNDS AND THE USE THEREOF IN METATHESIS REACTIONS 审中-公开
标题翻译：化合物及其在金属反应中的应用
公开(公告)号：US20170037069A1
公开(公告)日：2017-02-09
申请号：US15303089
申请日：2015-04-09
申请人： XiMo AG
发明人： Florian Toth , Georg Frater , Levente Ondi
IPC分类号： C07F11/00 , C07C6/04 , B01J31/22 , C07C67/475
CPC分类号： C07F11/00 , B01J31/2265 , B01J2231/543 , B01J2531/64 , B01J2531/66 , C07C6/04 , C07C67/333 , C07C67/475 , C07C2531/22 , C07C2601/10 , C07D321/00 , C07C69/74 , C07C69/593 , C07C11/02 , C07C15/12
摘要： The disclosure provides Group 6 complexes, which, in some embodiments, are useful for catalyzing olefin metathesis reactions. In some embodiments, the compounds are compounds of the following formula (I) wherein: M is a Group 6 metal atom; X is an oxygen atom, ═N—R5, ═N—N(R5)(R5′) or ═N—O—R5, R5 and R5′ independently being various substituents, such as aryl or heteroaryl, each optionally substituted; n is 0 or 1; Rz is a neutral ligand; R1 is hydrogen or an organic substituent; R2 is an aryl or heteroaryl group, each optionally substituted; R3 is an anionic ligand; and R4 is an anionic ligand, such as a pyrrolide, a pyrazolide, an imidazolide, an indolide, an azaindolide, or an indazolide, each optionally substituted.
摘要翻译：本公开提供了第6组配合物，其在一些实施方案中可用于催化烯烃复分解反应。在一些实施方案中，化合物是下式（I）的化合物，其中：M是第6族金属原子; X是氧原子，= N-R5，= N-N（R5）（R5'）或= N-0-R5，R5和R5独立地是各种取代基，例如芳基或杂芳基，各自任选被取代; n为0或1; Rz是中性配体; R1是氢或有机取代基; R2是芳基或杂芳基，各自任选被取代; R3是阴离子配体; 并且R 4是阴离子配体，例如吡咯烷，吡唑啉，咪唑啉，吲哚啉，氮杂吲哚，或吲唑啉，各自任选被取代。

10. 发明申请

US20160030936A1 METATHESIS CATALYSTS AND REACTIONS USING THE CATALYSTS 有权
标题翻译：使用催化剂的METATHESIS催化剂和反应
公开(公告)号：US20160030936A1
公开(公告)日：2016-02-04
申请号：US14774404
申请日：2014-03-13
申请人： XIMO AG
发明人： Levente Ondi , Jeno Varga , Agota Bucsai , Florian Toth , Krisztian Lorincz , Csaba Hegedus , Emmanuel Robe , Georg Emil Frater
IPC分类号： B01J31/22 , C07C6/04 , C07C67/293 , C07F11/00 , B01J31/18 , C07C67/347
CPC分类号： B01J31/2265 , B01J31/143 , B01J31/1608 , B01J31/1805 , B01J31/181 , B01J31/2208 , B01J31/2226 , B01J31/223 , B01J2231/543 , B01J2531/0266 , B01J2531/0288 , B01J2531/64 , B01J2531/66 , B01J2540/20 , B01J2540/22 , B01J2540/225 , C07C6/04 , C07C67/293 , C07C67/347 , C07C2531/12 , C07C2531/22 , C07C2601/10 , C07F11/00 , C08G61/08 , C08G2261/418 , C07C11/02
摘要： The invention relates to a method of forming an olefin from a first olefin and a second olefin in a metathesis reaction, comprising step (i): (i) reacting the first olefin with the second olefin in the presence of a compound that catalyzes said metathesis reaction such that the molar ratio of said compound to the first or the second olefin is from 1:500 or less, and the conversion of the first or the second olefin to said olefin is at least 50%, characterized in that as compound that catalyzes said metathesis reaction a compound of formula (A) is used: wherein M is Mo or W; R1 is aryl, heteroaryl, alkyl, or heteroalkyl; optionally substituted; R2 and R3 can be the same or different and are hydrogen, alkyl, alkenyl, heteroalkyl, heteroalkenyl, aryl, or heteroaryl; optionally substituted; R5 is alkyl, alkoxy, heteroalkyl, aryl, heteroaryl, silylalkyl, silyloxy, optionally substituted; and R4 is a residue R6—X—, wherein X═O and R6 is aryl, optionally substituted; or X═S and R6 is aryl, optionally substituted; or X═O and R6 is (R7, R8, R9)Si; wherein R7, R8, R9 are alkyl or phenyl, optionally substituted; or X═O and R6 is (R10, R11, R12)C, wherein R10, R11, R12 are independently selected from phenyl, alkyl; optionally substituted; and to the catalysts used in the method.
摘要翻译：本发明涉及一种在复分解反应中由第一种烯烃和第二种烯烃形成烯烃的方法，包括步骤（i）：（i）在催化所述复分解的化合物存在下，使第一种烯烃与第二种烯烃反应使得所述化合物与第一或第二烯烃的摩尔比为1:500以下，第一或第二烯烃向所述烯烃的转化率为至少50％，其特征在于，作为催化剂的化合物所述复分解反应使用式（A）化合物：其中M是Mo或W; R 1是芳基，杂芳基，烷基或杂烷基; 任选取代; R2和R3可以相同或不同，为氢，烷基，烯基，杂烷基，杂烯基，芳基或杂芳基; 任选取代; R5是烷基，烷氧基，杂烷基，芳基，杂芳基，甲硅烷基烷基，甲硅烷基氧基，任意取代的; R4为残基R6-X-，其中X = O和R6为芳基，任选取代; 或X = S和R 6为任选被取代的芳基; 或X = O，R6为（R7，R8，R9）Si; 其中R 7，R 8，R 9为烷基或苯基，任选取代; 或X = O，R 6为（R 10，R 11，R 12）C，其中R 10，R 11，R 12独立地选自苯基，烷基，任选取代; 以及该方法中使用的催化剂。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式