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    • 3. 发明授权
    • Super low melt toner having small molecule plasticizers
    • 具有小分子增塑剂的超低熔点调色剂
    • US09069272B2
    • 2015-06-30
    • US14077024
    • 2013-11-11
    • XEROX CORPORATION
    • Jordan H. WosnickKe ZhouValerie M. FarrugiaKentaro MorimitsuEdward G. Zwartz
    • G03G9/097G03G9/08G03G9/087
    • G03G9/0821G03G9/0806G03G9/08755G03G9/08759G03G9/08782G03G9/08797G03G9/09733
    • An emulsion aggregation (EA) toner includes an amorphous polymeric resin, optionally a colorant, and a small molecule crystalline organic compound having molecular weight less than 1,000 g/mol and melting point less than the fusing temperature of the EA toner, wherein a mixture of the resin and the small molecule compound is characterized by a reduction in glass transition temperature from that of the resin and by the lack of a significant solid to liquid phase transition peak for the small molecule compound as determined by differential scanning calorimetry, the enthalpy of fusion for the small molecule compound in the mixture being measured to be less than 10% of the enthalpy of fusion of the compound in pure form. Furthermore, the EA toner may be configured to have a crease fix minimum fusing temperature (MFT) less than or equal to the crease fix MFT of a benchmark ultra-low-melt emulsion aggregation toner.
    • 乳液聚集(EA)调色剂包括无定形聚合物树脂,任选的着色剂和分子量小于1,000g / mol且熔点低于EA调色剂的熔融温度的小分子结晶有机化合物,其中混合物 树脂和小分子化合物的特征在于玻璃化转变温度从树脂的降低以及通过差示扫描量热法测定的小分子化合物的显着固体与液相转变峰的缺乏,熔融焓 因为被测量的混合物中的小分子化合物的含量小于纯化合物的熔融焓的10%。 此外,EA调色剂可以被配置为具有小于或等于基准超低熔点乳液聚集调色剂的折痕固定MFT的折痕固定最小定影温度(MFT)。
    • 4. 发明授权
    • Super low melt toner having crystalline imides
    • 具有结晶酰亚胺的超低熔点调色剂
    • US09034546B1
    • 2015-05-19
    • US14076712
    • 2013-11-11
    • Xerox Corporation
    • Jordan H. WosnickKe ZhouKentaro MorimitsuMichael S. HawkinsEdward G. ZwartzValerie M. Farrugia
    • G03G9/08G03G9/097
    • G03G9/09741G03G9/0804G03G9/08795G03G9/08797G03G9/09775
    • A toner includes a polymeric resin, optionally a colorant, and a small molecule crystalline imide having a molecular weight less than 1,000 g/mol. The polymeric resin may be an amorphous resin and a mixture of the amorphous resin and the crystalline imide may be characterized by a reduction in glass transition temperature from that of the resin and by the lack of a melting point for the crystalline imide as determined by differential scanning calorimetry, the enthalpy of fusion for the crystalline imide in the mixture being measured to be less than 10% of the enthalpy of fusion of the crystalline imide in pure form. Furthermore, the toner may be configured to have a crease fix minimum fusing temperature (MFT) less than or equal to the crease fix MFT of a benchmark ultra-low-melt emulsion aggregation toner. Suitable crystalline imides may include N-alkyl and N-aryl imides, such as N-benzylphthalimide.
    • 调色剂包括聚合物树脂,任选的着色剂和分子量小于1,000g / mol的小分子结晶酰亚胺。 聚合物树脂可以是无定形树脂,并且无定形树脂和结晶酰亚胺的混合物的特征在于玻璃化转变温度从树脂的温度降低,并且结晶酰亚胺的熔点缺乏由差分测定 扫描量热法测定混合物中结晶酰亚胺的熔融焓低于纯形式的结晶酰亚胺熔融焓的10%。 此外,调色剂可以被配置为具有小于或等于基准超低熔点乳液聚集调色剂的折痕固定MFT的折痕固定最小定影温度(MFT)。 合适的结晶酰亚胺可以包括N-烷基和N-芳基酰亚胺,例如N-苄基邻苯二甲酰亚胺。
    • 10. 发明授权
    • Super low melt toner having crystalline aromatic monoesters
    • 具有结晶芳族单酯的超低熔点调色剂
    • US09557665B2
    • 2017-01-31
    • US14965299
    • 2015-12-10
    • XEROX CORPORATION
    • Ke ZhouJordan H. WosnickKentaro MorimitsuEdward G. ZwartzValerie M. Farrugia
    • G03G9/087G03G9/097G03G9/093G03G9/08
    • G03G9/0804G03G9/0821G03G9/08755G03G9/08797G03G9/09378G03G9/09392G03G9/09733
    • A toner includes a polymeric resin, a colorant, and a small molecule crystalline aromatic monoester having a molecular weight less than 1,000 g/mol. The polymeric resin may be an amorphous resin and a mixture of the amorphous resin and the crystalline aromatic monoester may be characterized by a reduction in glass transition temperature from that of the resin and by the lack of a melting point for the crystalline aromatic monoester as determined by differential scanning calorimetry, the enthalpy of fusion for the crystalline aromatic monoester in the mixture being measured to be less than 10% of the enthalpy of fusion of the crystalline aromatic monoester in pure form. Furthermore, the toner may be configured to have a crease fix minimum fusing temperature (MFT) less than or equal to the crease fix MFT of a benchmark ultra-low-melt emulsion aggregation toner. Suitable crystalline aromatic monoesters may include 2-Naphthyl benzoate.
    • 调色剂包括聚合树脂,着色剂和分子量小于1,000g / mol的小分子结晶芳族单酯。 聚合物树脂可以是无定形树脂,并且无定形树脂和结晶芳族单酯的混合物的特征在于玻璃化转变温度从树脂的温度降低,并且由于结晶芳族单酯的熔点没有被确定 通过差示扫描量热法,测量混合物中结晶芳族单酯的熔化焓小于纯形式的结晶芳族单酯的熔化焓的10%。 此外,调色剂可以被配置为具有小于或等于基准超低熔点乳液聚集调色剂的折痕固定MFT的折痕固定最小定影温度(MFT)。 合适的结晶芳族单酯可包括苯甲酸2-萘酯。