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1. 发明授权

US5206297A Electrically conductive moulding compositions and fillers from polyheteroaromatic compounds and polymeric sulfates 失效
标题翻译：来自聚异氰酸酯化合物和聚合硫酸酯的电导电成型组合物和填料
公开(公告)号：US5206297A
公开(公告)日：1993-04-27
申请号：US665494
申请日：1991-03-06
申请人： Wolfgang Wernet , Friedrich Lohse , Jurgen Finter , Hartmut Bleier , Bruno Rotzinger , Thomas Vogel
发明人： Wolfgang Wernet , Friedrich Lohse , Jurgen Finter , Hartmut Bleier , Bruno Rotzinger , Thomas Vogel
IPC分类号： C08L79/08 , C08G59/14 , C08G61/12 , C08G65/48 , C08L81/06 , C08L101/00 , C08L101/02 , H01B1/12
CPC分类号： H01B1/128 , C08G59/1411 , C08G61/123 , C08G65/48 , C08L81/06 , H01B1/127
摘要： Moulding composition in the form of particles of a) at least one polyheteroaromatic compound or an aniline in the oxidised, polycationic form, especially polypyrrole, and b) at least one polyanion of a thermoplastic polymer having sulfated alcohol groups ##STR1## in recurring structural units. Mouldings obtained from the moulding compositions have a high electrical conductivity and good mechanical strength properties. The mouldings can be used as electrodes, electrically conductive fibers or components for electromagnetic screening. The pulverulent moulding compounds are also suitable as electrically conductive fillers for plastics.
摘要翻译： a）至少一种氧化的聚阳离子形式的聚异氰脲酸化合物或苯胺，特别是聚吡咯的颗粒形式的成型组合物，和b）具有重复结构单元中具有硫酸化醇基团的热塑性聚合物的至少一种聚阴离子。从成型组合物得到的模制品具有高导电性和良好的机械强度性能。模制品可以用作电极，导电纤维或用于电磁屏蔽的部件。粉状模塑料也适用于塑料用导电填料。

2. 发明授权

US5482655A Electrically conductive thermoplastic polymer formulations and the use thereof 失效
标题翻译：导电热塑性聚合物配方及其用途
公开(公告)号：US5482655A
公开(公告)日：1996-01-09
申请号：US075658
申请日：1993-06-11
申请人： Thomas Vogel , Jurgen Finter , Hartmut Bleier , Patrice Bujard
发明人： Thomas Vogel , Jurgen Finter , Hartmut Bleier , Patrice Bujard
IPC分类号： C08G61/10 , C08G61/12 , C08L41/00 , C08L65/00 , H01B1/12 , H01B1/00 , H01B1/06
CPC分类号： C08G61/126 , C08L65/00 , H01B1/127 , H01G11/48 , H01G11/56 , C08G2261/1424 , C08G2261/3223 , Y02E60/13
摘要： A formulation comprisinga) at least one polythiophene in oxidised polycationic form and containing structural repeating units of formula I ##STR1## wherein R.sub.1 and R.sub.2 are each independently of the other linear or branched C.sub.1 -C.sub.18 alkyl or C.sub.2 -C.sub.18 alkoxyalkyl; or are C.sub.3 -C.sub.8 cycloalkyl, phenyl or benzyl which are unsubstituted or substituted by C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkoxy or halogen; or R.sub.1 and R.sub.2, taken together, are linear C.sub.1 -C.sub.8 alkylene which is unsubstituted or substituted by C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkoxy, halogen, C.sub.3 -C.sub.8 cycloalkyl, phenyl, benzyl, C.sub.1 -C.sub.4 alkylphenyl, C.sub.1 -C.sub.4 alkoxyphenyl, halophenyl, C.sub.1 -C.sub.4 alkylbenzyl, C.sub.1 -C.sub.4 alkoxybenzyl or halobenzyl; andb) at least one polyanion of a film-forming thermoplastic polymer containing sulfated alcohol groups ##STR2## and/or sulfonatoalkylated alcohol groups ##STR3## in structural repeating units, wherein the group --(C.sub.n H.sub.2n)-- is linear or branched C.sub.2 -C.sub.12 alkylene which contains 2 to 5 carbon atoms in the carbon chain and is unsubstituted or substituted by C.sub.1 -C.sub.4 alkoxy. The formulation is an intrinsically electrically conductive themoformable material.
摘要翻译：一种制剂，其包含a）至少一种氧化聚阳离子形式的聚噻吩，并含有另一个直链或支链C 1 -C 18烷基或C 2 -C 18烷氧基烷基的结构式I重复单元; 或未取代或被C 1 -C 6烷基，C 1 -C 6烷氧基或卤素取代的C 3 -C 8环烷基，苯基或苄基; 或者R 1和R 2一起是未被取代或被C 1 -C 6烷基，C 1 -C 6烷氧基，卤素，C 3 -C 8环烷基，苯基，苄基，C 1 -C 4烷基苯基，C 1 -C 4烷氧基苯基，卤代苯基，C 1 -C 4烷基苄基，C 1 -C 4烷氧基苄基或卤代苄基; 和b）在结构重复单元中含有硫酸化醇基团和/或磺化烷基化醇基团的成膜热塑性聚合物的至少一种聚阴离子，其中 - （C n H 2n） - 为直链或支链C 2 -C 12亚烷基其在碳链中含有2至5个碳原子且未被取代或被C 1 -C 4烷氧基取代。制剂是本征导电的可变形材料。

3. 发明授权

US6004724A Oxime sulfonates and the use thereof as latent sulfonic acids 失效
标题翻译：肟磺酸盐及其作为潜在磺酸的用途
公开(公告)号：US6004724A
公开(公告)日：1999-12-21
申请号：US104676
申请日：1998-06-25
申请人： Hitoshi Yamato , Hartmut Bleier , Jean-Luc Birbaum , Martin Kunz , Kurt Dietliker , Christoph De Leo , Toshikage Asakura
发明人： Hitoshi Yamato , Hartmut Bleier , Jean-Luc Birbaum , Martin Kunz , Kurt Dietliker , Christoph De Leo , Toshikage Asakura
IPC分类号： C07C309/65 , C07C309/66 , C07C309/73 , C07C323/63 , C07C381/00 , C07D207/44 , C07D213/90 , C07D333/34 , C07D333/36 , C07D333/44 , G03F7/004 , G03C1/725 , C07C249/04 , C07C251/32 , G03C1/72
CPC分类号： C07D207/44 , C07C309/65 , C07C309/66 , C07C309/73 , C07C323/63 , C07C381/00 , C07D213/90 , C07D333/44 , G03F7/0045 , Y10S430/114 , Y10S430/117 , Y10S430/12 , Y10S430/122
摘要： New oximsulfonate compounds of the formulae I or II, ##STR1## wherein m is 0 or 1; x is 1 or 2; R.sub.1 is, for example phenyl, which is unsubstituted or substituted or R.sub.1 is a heteroaryl radical that is unsubstituted or substituted, or, if m is 0, R.sub.1 additionally is C.sub.2 -C.sub.6 alkoxycarbonyl, phenoxycarbonyl or CN; R'.sub.1 is for example C.sub.2 -C.sub.12 alkylene, phenylene; R.sub.2 has for example one of the meanings of R.sub.1 ; n is 1 or 2; R.sub.3 is for example C.sub.1 -C.sub.18 alkyl, R'.sub.3 when x is 1, has one of the meanings given for R.sub.3, or R'.sub.3 in the formula IV and when x is 2 in the formula 1, is for example C.sub.2 -C.sub.12 alkylene, phenylene; R.sub.4 and R.sub.5 are independently of each other for example hydrogen, halogen, C.sub.1 -C.sub.6 alkyl; R.sub.6 is for example hydrogen, phenyl; R.sub.7 and R.sub.8 are independently of each other for example hydrogen or C.sub.1 -C.sub.12 -alkyl; R.sub.9 is for example C.sub.1 -C.sub.12 alkyl; A is S, O, NR.sub.6, or a group of formula A1, A2, A3 or A4 ##STR2## R.sub.10 and R.sub.11 independently of each other have one of the meanings given for R.sub.4 ; R.sub.12, R.sub.13, R.sub.14 and R.sub.15 independently of one another are for example hydrogen, C.sub.1 -C.sub.4 alkyl; Z is CR.sub.11 or N; Z.sub.1 is --CH.sub.2 --, S, O or NR.sub.6, are useful as latent sulfonic acids, especially in photoresist applications.
摘要翻译：式I或II的新的磺酸磺酸酯化合物，其中m为0或1; x为1或2; R1是例如未取代或取代的苯基，或R1是未取代或取代的杂芳基，或者如果m是0，则R1另外是C 2 -C 6烷氧基羰基，苯氧基羰基或CN; R'1例如为C 2 -C 12亚烷基，亚苯基; R2具有例如R1的含义之一; n为1或2; R3为例如C1-C18烷基，当x为1时为R'3，具有R3给出的含义之一，或式Ⅳ中的R'3，当式Ⅺ中x为2时，为例如C 2 -C 12亚烷基，亚苯基; R4和R5彼此独立，例如氢，卤素，C1-C6烷基; R6是例如氢，苯基; R 7和R 8彼此独立地为氢或C 1 -C 12 - 烷基; R 9为例如C 1 -C 12烷基; A是S，O，NR6或式A1，A2，A3或A4的基团，R10和R11彼此独立地具有对R4给出的含义之一; R 12，R 13，R 14和R 15彼此独立地是例如氢，C 1 -C 4烷基; Z为CR11或N; Z1是-CH2-，S，O或NR6，可用作潜在的磺酸，特别是在光刻胶应用中。

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