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1. 发明授权

US06201043B1 Dispersion product for producting an electrophoretically precipitable dipping varnish 有权
标题翻译：用于产生电泳可沉淀浸渍清漆的分散产物
公开(公告)号：US06201043B1
公开(公告)日：2001-03-13
申请号：US09242146
申请日：1999-04-27
申请人： Wolfgang Bremser , Frank Strickmann , Günther Ott , Karl-Heinz Grosse-Brinkhaus
发明人： Wolfgang Bremser , Frank Strickmann , Günther Ott , Karl-Heinz Grosse-Brinkhaus
IPC分类号： C08K320
CPC分类号： C09D151/08 , C08F283/10 , C09D5/4473
摘要： The invention relates to aqueous dispersions. They are obtainable by polymerizing an ethylenically unsaturated monomer or a mixture of ethylenically unsaturated monmers [sic] in an aqueous solution of an at least partially protonated epoxide-amine adduct. It is characterized in that the epoxide-amine adduct is for its part obtainable by reacting (A) a glycidyl ether of a polyphenol that contains on statistical average at least one epoxide group in the molecule, or a mixture of such glycidyl ethers, (B) a polygycidyl [sic] ether of a polyol that contains on statistical average more than 1.0 epoxide groups in the molecule, or a mixture of such polyglycidyl ethers, and (C) a compound that contains a primary amino group in the molecule, or a mixture of such compounds, to give the epoxide-amine adduct, components (A) and (B) being employed in a ratio of equivalents of from 1.0:0.5 to 1.0:8.0 and from 0.3 to 0.7 mol of component (C) being employed per equivalent of epoxide groups of (A) and (B).
摘要翻译：本发明涉及水性分散体。它们可通过在至少部分质子化的环氧化物 - 胺加合物的水溶液中聚合烯属不饱和单体或烯属不饱和单体的混合物而获得。其特征在于环氧 - 胺加合物部分可通过使（A）分子中含有至少一个环氧基的统计平均数的多酚的缩水甘油醚或这种缩水甘油醚的混合物（B ）多元醇的聚环己烷基醚，其在分子中统计平均含有超过1.0个环氧基，或这些多缩水甘油醚的混合物，和（C）在分子中含有伯氨基的化合物，或这些化合物的混合物得到环氧化物 - 胺加合物，组分（A）和（B）以当量为1.0:0.5至1.0:8.0和0.3-0.7mol的组分（C）的使用量使用（A）和（B）的每当量的环氧基团。

2. 发明授权

US07867570B2 Method of producing a coating having metal coordinating and film-forming materials 有权
标题翻译：制备具有金属配位和成膜材料的涂层的方法
公开(公告)号：US07867570B2
公开(公告)日：2011-01-11
申请号：US11553213
申请日：2006-10-26
申请人： Timothy S. December , Sergio Gonzalez , Günther Ott , Karl-Heinz Grosse-Brinkhaus
发明人： Timothy S. December , Sergio Gonzalez , Günther Ott , Karl-Heinz Grosse-Brinkhaus
IPC分类号： B05D3/02
CPC分类号： C09D5/4419 , C09D5/4415
摘要： Film-forming materials include nonionic metal coordinating structures. Nonionic metal coordinating structures can coordinate metals, such as metal catalysts and metal substrates. Example film-forming materials can be the product of a poly-functional epoxide and a nucleophilic ligand having a nonionic metal coordinating structure, or the product of a poly-functional alcohol and an electrophilic ligand having a nonionic metal coordinating structure. Coating compositions can include the film-forming material and a crosslinker. The coating compositions can be used to coat a substrate, such as a metal substrate. Applied coating layers on substrates can be cured to form coating films.
摘要翻译：成膜材料包括非离子金属配位结构。非离子金属配位结构可以配合金属，如金属催化剂和金属基材。成膜材料的实例可以是具有非离子金属配位结构的多官能环氧化物和亲核配体的产物，或多官能醇和具有非离子金属配位结构的亲电子配体的产物。涂料组合物可以包括成膜材料和交联剂。涂料组合物可用于涂覆基底，例如金属基底。可以将基材上的涂布层固化形成涂膜。

3. 发明授权

US07759436B2 Film-former of resin with nonionic metal coordinating structure and crosslinker-reactive group 失效
标题翻译：具有非离子金属配位结构和交联剂反应性基团的树脂成膜剂
公开(公告)号：US07759436B2
公开(公告)日：2010-07-20
申请号：US11553185
申请日：2006-10-26
申请人： Timothy S. December , Sergio Gonzalez , Günther Ott , Karl-Heinz Grosse-Brinkhaus
发明人： Timothy S. December , Sergio Gonzalez , Günther Ott , Karl-Heinz Grosse-Brinkhaus
IPC分类号： C08K3/22 , C08L33/02 , C08L33/08 , C08L33/10 , C08L33/14 , C08L61/20 , C08L61/32 , C08L67/02 , C08L75/00 , C08L75/12 , C08L83/04 , C08L63/02 , C08L69/00 , C08K3/20
CPC分类号： C09D5/4465 , C08G18/4081 , C08G18/6233 , C08G18/6283 , C08G18/643 , C08G18/8064 , C08G59/182 , C08G2150/90
摘要： Film-forming materials include nonionic metal coordinating structures. Nonionic metal coordinating structures can coordinate metals, such as metal catalysts and metal substrates. Example film-forming materials can be the product of a poly-functional epoxide and a nucleophilic ligand having a nonionic metal coordinating structure, or the product of a poly-functional alcohol and an electrophilic ligand having a nonionic metal coordinating structure.
摘要翻译：成膜材料包括非离子金属配位结构。非离子金属配位结构可以配合金属，如金属催化剂和金属基材。成膜材料的实例可以是具有非离子金属配位结构的多官能环氧化物和亲核配体的产物，或多官能醇和具有非离子金属配位结构的亲电子配体的产物。

4. 发明授权

US07504444B2 Aqueous electrocoat materials, their use in processes for coating electrically conductive substrates, and the use of bismuth compounds in these aqueous electrocoat materials 有权
标题翻译：水性电涂层材料，它们在用于涂覆导电基材的方法中的用途，以及在这些水性电泳涂料中使用铋化合物
公开(公告)号：US07504444B2
公开(公告)日：2009-03-17
申请号：US11416909
申请日：2006-05-03
申请人： Karl-Heinz Grosse-Brinkhaus , Günther Ott , Hardy Reuter , Hans-Otto Köbbert
发明人： Karl-Heinz Grosse-Brinkhaus , Günther Ott , Hardy Reuter , Hans-Otto Köbbert
IPC分类号： C08K5/02 , C08K5/44 , C08K5/56
CPC分类号： C09D5/4492 , C08K5/56 , C09D5/025
摘要： Electrocoat material comprising bismuth compounds, comprising: (A) at least one self-crosslinking and/or externally crosslinking binder containing(potentially) cationic or anionic groups and reactive functional groups which (i) with themselves or with complementary reactive functional groups in the self-crosslinking binder, or (ii) in the case of the externally crosslinking binder, with complementary reactive functional groups present in crosslinking agents (B) are able to undergo thermal crosslinking reactions, (B) if desired, at least one crosslinking agent comprising the complementary reactive functional groups, and (C) at least one bismuth compound.
摘要翻译：包含铋化合物的电涂层材料包括：（A）至少一种自交联和/或外部交联的粘合剂，其含有（潜在地）阳离子或阴离子基团和反应性官能团，其（i）在自身中具有自身或互补的反应性官能团 - 交联粘合剂，或（ii）在外部交联粘合剂的情况下，存在于交联剂（B）中的互补的反应性官能团能够进行热交联反应，（B）如果需要，至少一种包含互补的反应性官能团，和（C）至少一种铋化合物。

5. 发明授权

US06274649B1 Aqueous binding agent dispersion for cationic electro-dipcoat paint 有权
标题翻译：用于阳离子电泳涂料的水性粘合剂分散体
公开(公告)号：US06274649B1
公开(公告)日：2001-08-14
申请号：US09367001
申请日：1999-09-02
申请人： Günther Ott , Hardy Reuter , Walter Jouck , Thierry Herning , Susanne Piontek , Ulrich Heimann , Karl-Heinz Grosse-Brinkhaus
发明人： Günther Ott , Hardy Reuter , Walter Jouck , Thierry Herning , Susanne Piontek , Ulrich Heimann , Karl-Heinz Grosse-Brinkhaus
IPC分类号： C08K320
CPC分类号： C08G59/184 , C08G59/182 , C09D5/4434
摘要： The present invention relates to an aqueous binder dispersion for cathodic electrodeposition coatings obtained A) by reacting I. a precursor prepared at temperatures of from 120 to 180° C. from a) a diepoxide compound or a mixture of diepoxide compounds and b) an aromatic or aliphatic compound hydroxyl, carboxyl, phenol and/or thiol groups, or a mixture of such compounds with reaction of the phenolic hydroxyl groups with epoxide groups, II. with at least one organic amine or a mixture of organic amines at a temperature between 60 and about 130° C. to give an epoxide/amine adduct; B) subsequently or simultaneously reacting at least one secondary hydroxyl group of the precursor with an unreacted epoxide group of the epoxide/amine adduct prepared in step A) at a temperatures of from about 110 to about 150° C.; C) adding a crosslinking agent at a temperature of less than about 150° C.; D) neutralizing the resulting binder from step A to C at a temperature of from about 90 to about 110° C.; and E) dispersing the neutralized binder obtained in step A to D in water.
摘要翻译：本发明涉及一种用于阴极电沉积涂料的水性粘合剂分散体，其通过使I。由二环氧化合物或二环氧化合物的混合物和b）芳族或脂族化合物羟基，羧基，苯酚和/或硫醇基团或这些化合物与反应的混合物制备的前体，其温度为120-180℃。的酚羟基与环氧基团，II。与至少一种有机胺或有机胺的混合物在60至约130℃之间的温度下反应，得到环氧化物/胺加合物; B）随后或同时使前体的至少一个仲羟基与未反应的环氧化物在步骤A）中制备的环氧化物/胺加合物基团在约110至约150℃的温度下; C）在小于约150℃的温度下加入交联剂; D）中和所得粘合剂在步骤A至C的温度为约90至约110℃; 和E）将步骤A中获得的中和的粘合剂分散到D中。

6. 发明授权

US07772334B2 Crosslinker of reactive functional groups and nonionic metal coordinating structure-containing alkyl or aromatic compound 有权
标题翻译：反应性官能团和非离子金属配位结构的烷基或芳族化合物的交联剂
公开(公告)号：US07772334B2
公开(公告)日：2010-08-10
申请号：US11553195
申请日：2006-10-26
申请人： Timothy S. December , Sergio Gonzalez , Günther Ott , Karl-Heinz Grosse-Brinkhaus
发明人： Timothy S. December , Sergio Gonzalez , Günther Ott , Karl-Heinz Grosse-Brinkhaus
IPC分类号： C08L63/02 , C08L63/10
CPC分类号： C08J3/24 , C08G59/18 , C09D201/02
摘要： A crosslinker for polymerizing a film-forming material including an alkyl or aromatic compound comprising at least two functional groups reactive with a film-forming resin and at least one pendent group having a nonionic metal coordinating structure. Coating compositions can include a film-forming material and the crosslinker. The coating compositions can be used to coat a substrate, such as a metal substrate. Applied coating layers on substrates can be cured to form coating films.
摘要翻译：用于聚合包含至少两个与成膜树脂反应的官能团的烷基或芳族化合物的成膜材料和至少一个具有非离子金属配位结构的侧基的成膜材料的交联剂。涂料组合物可以包括成膜材料和交联剂。涂料组合物可用于涂覆基底，例如金属基底。可以将基材上的涂布层固化，形成涂膜。

7. 发明授权

US06398944B1 Method of removing acid formed during cathodic electrodip coating 失效
标题翻译：在阴极电涂层中除去酸形成的方法
公开(公告)号：US06398944B1
公开(公告)日：2002-06-04
申请号：US09043369
申请日：1998-05-19
申请人： Klaus Arlt , Udo Heil , Karl-Heinz Grosse-Brinkhaus
发明人： Klaus Arlt , Udo Heil , Karl-Heinz Grosse-Brinkhaus
IPC分类号： C25F702
CPC分类号： C25D13/22 , C25D21/18
摘要： A method of removing, by oxidation at the anode, the acid liberated in cathodic dip-coating in the course of the deposition of the coating film, using anodes coated with a layer of tin oxide or with a mixture of tin oxide with ruthenium or iridium oxides.
摘要翻译：通过在阳极处氧化在涂膜沉积过程中在阴极浸涂中释放的酸，使用涂有氧化锡层的氧化锡或氧化锡与钌或铱的混合物除去阳极的方法氧化物。

8. 发明授权

US07087146B2 Method for producing a multilayer coating and the use thereof 失效
标题翻译：多层涂层的制造方法及其用途
公开(公告)号：US07087146B2
公开(公告)日：2006-08-08
申请号：US10381534
申请日：2001-10-19
申请人： Karl-Heinz Grosse-Brinkhaus , Georg Wigger
发明人： Karl-Heinz Grosse-Brinkhaus , Georg Wigger
IPC分类号： C25D13/12
CPC分类号： B05D7/544
摘要： A process for producing a multicoat system on a substrate, in which a) an electrodeposition coating film is deposited on the substrate, b) the electrodeposition coating film is predried by heating to a predrying temperature for a predetermined period, c) a coat of a surfacer is applied to the electrodeposition coating film, and d) the electrodeposition coating film and the coat of the surfacer are baked together at elevated temperatures, and in which the predrying temperature in step b) is equal to the temperature (Tp) or lies above the temperature (Tp) at which the loss factor tan δ, which is the quotient formed from the loss modulus E″ and the storage modulus E′, of the unbaked electrodeposition coating material shows a maximum, and the use of the resulting multicoat system.
摘要翻译：一种在基板上制造多点印刷系统的方法，其中a）将电沉积涂膜沉积在基板上，b）电沉积涂膜通过加热到预烘烤温度预定的时间段，c）将表面涂布在电沉积涂膜上，d）将电沉积涂膜和表面涂层在高温下烘烤在一起，步骤b）中的预干燥温度等于温度（T p 或者位于温度（T p P p）之上，在该温度下，作为由损耗模量E“和储能模量E'形成的商的损耗因子tanδ，未烘烤的电沉积涂料显示最大值，并使用得到的多色系统。

9. 发明授权

US06344501B1 Non-ionically stabilized transparent powder-coating dispersion 失效
标题翻译：非离子稳定的透明粉末涂料分散体
公开(公告)号：US06344501B1
公开(公告)日：2002-02-05
申请号：US09646947
申请日：2000-10-23
申请人： Claudia Sierakowski , Karl-Heinz Grosse-Brinkhaus , Egon Wegner , Thomas Frey , Jörg Niemann , Joachim Woltering
发明人： Claudia Sierakowski , Karl-Heinz Grosse-Brinkhaus , Egon Wegner , Thomas Frey , Jörg Niemann , Joachim Woltering
IPC分类号： C08K320
CPC分类号： C09D163/00 , C08L75/04 , C09D5/02 , C09D133/068 , C08L2666/14
摘要： The present invention relates to an aqueous powder clearcoat dispersion comprising a solid pulverulent component A and an aqueous component B, where component A is a transparent powder coating material comprising a) at least one epoxy binder containing from 25 to 45% by weight, preferably from 25 to 35% by weight, of glycidyl-containing monomers, with or without a fraction of vinylaromatic compounds, preferably styrene, b) at least one crosslinking agent, preferably straight-chain, aliphatic dicarboxylic acids and/or carboxy-functional polyesters, and c) if desired, catalysts, auxiliaries, additives typical for transparent powder coating materials, such as devolatilizers, leveling agents, UV absorbers, free-radical scavengers, and antioxidants, and component B is an aqueous dispersion comprising a) at least one nonionic thickener and b) if desired, catalysts, auxiliaries, defoamers, wetting agents, antioxidants, UV absorbers, free-radical scavengers, biocides, small amounts of solvent, leveling agents, neutralizing agents, preferably amines, and/or water retention agents, and c) a dispersant medium in the form of a nonionic polyurethane dispersion.
摘要翻译：本发明涉及包含固体粉状成分A和水性成分B的水性粉末透明涂料分散液，其中A是透明粉末涂料，其包含a）至少一种含25至45重量％，优选25至45重量％ 35重量％的含缩水甘油基的单体，具有或不含一部分乙烯基芳族化合物，优选苯乙烯，b）至少一种交联剂，优选直链的脂族二羧酸和/或羧基官能的聚酯，以及c）如果所需的催化剂，助剂，透明粉末涂料的典型添加剂如脱挥发分剂，流平剂，UV吸收剂，自由基清除剂和抗氧化剂，组分B是一种水分散体，其包含a）至少一种非离子型增稠剂，和b）如果需要，催化剂，助剂，消泡剂，润湿剂，抗氧化剂，紫外线吸收剂，自由基清除剂，杀生物剂，少量溶剂，水溶液中和剂，优选胺和/或保水剂，和c）非离子聚氨酯分散体形式的分散剂介质。

10. 发明授权

US08389653B2 Method of catalyzing a reaction to form a urethane coating and a complex for use in the method 有权
标题翻译：催化反应形成氨基甲酸酯涂层的方法和用于该方法的复合物
公开(公告)号：US08389653B2
公开(公告)日：2013-03-05
申请号：US11278030
申请日：2006-03-30
申请人： Timothy S. December , Cesar G. Ortiz , Hardy Reuter , Karl-Heinz Grosse-Brinkhaus , Guenter Ott
发明人： Timothy S. December , Cesar G. Ortiz , Hardy Reuter , Karl-Heinz Grosse-Brinkhaus , Guenter Ott
IPC分类号： C08F283/00
CPC分类号： C09D5/4484 , C08G18/4018 , C08G18/4283 , C08G2210/00 , C08G2230/00 , C09D5/4488
摘要： A urethane coating is formed by a reaction of a hydroxy-functional resin and a blocked isocyanate crosslinker. A method of catalyzing this reaction includes forming a polymeric ligand from the resin and/or the crosslinker. The method also includes incorporating a metal catalyst with the polymeric ligand to complex the metal catalyst with the polymeric ligand. The method further includes reacting resin and the crosslinker to form the urethane coating.
摘要翻译：通过羟基官能树脂和封端异氰酸酯交联剂的反应形成聚氨酯涂层。催化该反应的方法包括从树脂和/或交联剂形成聚合配体。该方法还包括将金属催化剂与聚合物配体结合以使金属催化剂与聚合物配体复合。该方法还包括使树脂和交联剂反应形成聚氨酯涂层。

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