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1. 发明授权

US06759187B1 Imaging element containing a blocked photographically useful compound 失效
公开(公告)号：US06759187B1
公开(公告)日：2004-07-06
申请号：US09614035
申请日：2000-07-11
申请人： Wojciech K. Slusarek , Xiqiang Yang , Mark E. Irving , David H. Levy , Jared B. Mooberry , James J. Seifert , James H. Reynolds , Lyn M. Irving
发明人： Wojciech K. Slusarek , Xiqiang Yang , Mark E. Irving , David H. Levy , Jared B. Mooberry , James J. Seifert , James H. Reynolds , Lyn M. Irving
IPC分类号： G03C134
CPC分类号： G03C1/49809 , G03C1/42 , G03C1/43 , G03C1/49827 , G03C1/49845 , G03C7/30511 , G03C7/30541 , G03C7/39236 , G03C7/4136 , Y10S430/156 , Y10S430/158 , Y10S430/159
摘要： This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of Structure I: wherein: the substituents are as defined in the application.

2. 发明授权

US06756192B1 Imaging element containing a blocked photographically useful compound 失效
标题翻译：成像元件含有封闭的有用的化合物
公开(公告)号：US06756192B1
公开(公告)日：2004-06-29
申请号：US09475703
申请日：1999-12-30
申请人： Wojciech K. Slusarek , Xiqiang Yang , Mark E. Irving , David H. Levy , Jared B. Mooberry , James J. Seifert , James H. Reynolds , Lyn M. Irving
发明人： Wojciech K. Slusarek , Xiqiang Yang , Mark E. Irving , David H. Levy , Jared B. Mooberry , James J. Seifert , James H. Reynolds , Lyn M. Irving
IPC分类号： G03C1498
CPC分类号： G03C1/49809 , G03C1/42 , G03C1/43 , G03C1/49827 , G03C1/49845 , G03C7/30511 , G03C7/30541 , G03C7/39236 , G03C7/4136 , Y10S430/156 , Y10S430/158 , Y10S430/159
摘要： This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of Structure I: wherein: the substituents are as defined in the application.
摘要翻译：本发明涉及一种成像元件，其包括具有结构I的化合物的成像层：其中：取代基如本申请中所定义。

3. 发明授权

US06537712B1 Color photothermographic elements comprising blocked developing agents 失效
标题翻译：包括阻挡显影剂的彩色光热敏成像元件
公开(公告)号：US06537712B1
公开(公告)日：2003-03-25
申请号：US09710348
申请日：2000-11-09
申请人： Wojciech K. Slusarek , Xiqiang Yang , Mark E. Irving , David H. Levy , Jared B. Mooberry , James J. Seifert , James H. Reynolds , Lyn M. Irving , Zbyslaw R. Owczarczyk , David K. Southby
发明人： Wojciech K. Slusarek , Xiqiang Yang , Mark E. Irving , David H. Levy , Jared B. Mooberry , James J. Seifert , James H. Reynolds , Lyn M. Irving , Zbyslaw R. Owczarczyk , David K. Southby
IPC分类号： G03C1498
CPC分类号： G03C1/49845 , G03C7/30541 , G03C8/408 , Y10S430/16
摘要： This invention relates to a color photothermographic element comprising an imaging layer having associated therewith a compound of Structure I: wherein DEV, LINK, TIME, n, T, t, C*, R12, D, p, X, q, W, and w are defined in the application. Such compounds have good reactivity as developing agents when thermally activated under preselected conditions. The invention is also directed to a method of developing a color photothermographic element, including dry development systems.
摘要翻译：本发明涉及一种彩色光热敏成像元件，其包括具有与其结合的结构I的化合物的成像层：其中DEV，LINK，TIME，n，T，t，C *，R12，D，p，X，q，W和 w在应用程序中定义。当在预选条件下热激活时，这些化合物作为显影剂具有良好的反应性。本发明还涉及一种开发彩色光热敏成像元件的方法，包括干式显影系统。

4. 发明授权

US07112398B2 Imaging element containing a blocked photographically useful compound 失效
标题翻译：成像元件含有封闭的有用的化合物
公开(公告)号：US07112398B2
公开(公告)日：2006-09-26
申请号：US10755069
申请日：2004-01-09
申请人： Wojciech K. Slusarek , Xiqiang Yang , Mark E. Irving , David H. Levy , Jared B. Mooberry , James J. Seifert , James H. Reynolds , Lyn M. Irving
发明人： Wojciech K. Slusarek , Xiqiang Yang , Mark E. Irving , David H. Levy , Jared B. Mooberry , James J. Seifert , James H. Reynolds , Lyn M. Irving
IPC分类号： G03C5/16 , G03C11/00
CPC分类号： G03C7/30511 , G03C1/42 , G03C1/43 , G03C1/49809 , G03C1/49827 , G03C1/49845 , G03C7/30541 , G03C7/39236 , G03C7/4136 , Y10S430/156 , Y10S430/16 , Y10S430/165
摘要： This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of Structure I: wherein: the substituents are as defined in the application.
摘要翻译：本发明涉及一种成像元件，其包括具有结构I的化合物的成像层：其中：取代基如本申请中所定义。

5. 发明授权

US5457004A Photographic element containing a high dye-yield coupler with methine dye chromophore 失效
标题翻译：含有高染料收率成色剂与次甲基染料发色团的摄影元件
公开(公告)号：US5457004A
公开(公告)日：1995-10-10
申请号：US250744
申请日：1994-05-27
申请人： Jared B. Mooberry , James J. Seifert , David Hoke , Zheng Z. Wu , David T. Southby , Frank D. Coms
发明人： Jared B. Mooberry , James J. Seifert , David Hoke , Zheng Z. Wu , David T. Southby , Frank D. Coms
IPC分类号： G03C7/00 , G03C7/305 , G03C7/36 , G03C7/333
CPC分类号： G03C7/30547 , Y10S430/156
摘要： The invention provides a photographic element comprising a substrate bearing a photographic silver halide emulsion layer having associated therewith a high dye-yield coupler having the formula: ##STR1## wherein: COUP is a photographic coupler residue capable of coupling with oxidized color developer to form a first dye;T is a timing group;m is an integer from 0 to 2;L is a linking group selected from the group consisting of --OC(.dbd.O)--, --OC(.dbd.S)--, --SC(.dbd.O)--, --SC(.dbd.S)--, and --OC(.dbd.NSO.sub.2 R) where R is substituted or unsubstituted alkyl or aryl; andDYE is a releasable second dye or dye precursor having a particular formula including a methine dye chromophore.
摘要翻译：本发明提供了一种照相元件，其包含具有照相卤化银乳剂层的基底，其具有下列结构的高染料收率成色剂：其中：COUP是能够与氧化的显色剂偶联以形成第一染料; T是一个时间组; m为0〜2的整数; L是选自-OC（= O） - ， - OC（= S） - ， - SC（= O） - ， - SC（= S） - 和-OC（= NSO 2 R）其中R是取代或未取代的烷基或芳基; 并且DYE是具有特定配方的可释放的第二染料或染料前体，其包含次甲基染料发色团。

6. 发明授权

US06172260B2 Preparation of high dye-yield couplers and intermediates useful therein 失效
标题翻译：制备高染料收率的成色剂和其中有用的中间体
公开(公告)号：US06172260B2
公开(公告)日：2001-01-09
申请号：US09224476
申请日：1998-12-31
申请人： Chang-Kyu Kim , Jared B. Mooberry , David Hoke , James J. Seifert
发明人： Chang-Kyu Kim , Jared B. Mooberry , David Hoke , James J. Seifert
IPC分类号： C07C27104
CPC分类号： C07D263/56 , C07C271/04 , G03C7/3005 , G03C7/30576 , G03C7/333
摘要： Disclosed is a carbamyl chloride of an aminoarylcarbonyl compound having the structural formula I: wherein R is an alkyl, alkenyl, or aryl group; A is an aryl (including heteroaryl) ring group; each R′ is independently an alkyl group which may form a ring with Z or Z′; p is 0, 1, 2, or 3; each Z, Z′, and Y is independently hydrogen or a substituent; and n is 0, 1, or 2.
摘要翻译：公开了具有结构式I的氨基芳基羰基化合物的氨基甲酰氯：其中R是烷基，烯基或芳基; A是芳基（包括杂芳基）环基;每个R'独立地是可以形成环的烷基 Z或Z'; p为0,1,2或3; Z，Z'和Y各自独立地为氢或取代基; andn为0,1或2。

7. 发明授权

US6124503A Processes for making and using alkylaminoarylcarbonyl compounds 失效
标题翻译：制备和使用烷基氨基芳基羰基化合物的方法
公开(公告)号：US6124503A
公开(公告)日：2000-09-26
申请号：US223863
申请日：1998-12-31
申请人： Chang-Kyu Kim , Jared B. Mooberry , David Hoke , James J. Seifert
发明人： Chang-Kyu Kim , Jared B. Mooberry , David Hoke , James J. Seifert
IPC分类号： C07C221/00 , C07C223/06 , C07C211/03
CPC分类号： C07C221/00 , C07C2101/08
摘要： A method of making an alkylaminoarylcarbonyl compound having Formula I: ##STR1## wherein R is an alkyl group;A is an aryl (including heteroaryl) ring;each R' is independently an alkyl group which may form a ring with Z or Z';p is 0, 1, 2, or 3;each Z, Z', and Y is independently hydrogen or a substituent; andn is 0, 1, or 2;comprising:(a) blocking the carbonyl function of an aminoarylcarbonyl compound via condensation with an active methylene compound(b) alkylating this blocked amniocarbonyl compound via reductive alkylation with an alkyl or aryl (including heteroaryl) carbonyl compound, and(c) deblocking of the blocked alkylaminoarylcarbonyl compound via base hydrolysis to regenerate the carbonyl function and give the desired alkylaminocarbonyl compound.
摘要翻译：制备具有式I的烷基氨基芳基羰基化合物的方法：其中R是烷基; A是芳基（包括杂芳基）环; 每个R'独立地是可以与Z或Z'形成环的烷基; p为0,1,2或3; 每个Z，Z'和Y独立地是氢或取代基; 并且n为0,1或2; 包括：（a）通过与活性亚甲基化合物缩合来阻断氨基芳基羰基化合物的羰基官能团（b）通过用烷基或芳基（包括杂芳基）羰基化合物还原烷基化将该封端的氨基羰基化合物烷基化，和（c）通过碱水解封端的烷基氨基芳基羰基化合物以再生羰基官能团并得到所需的烷基氨基羰基化合物。

8. 发明授权

US5246820A Carbamic acid solubilized smearing couplers 失效
标题翻译：碳酸溶解性农药偶联剂
公开(公告)号：US5246820A
公开(公告)日：1993-09-21
申请号：US845290
申请日：1992-03-03
申请人： Jared B. Mooberry , James J. Seifert , Stephen P. Singer
发明人： Jared B. Mooberry , James J. Seifert , Stephen P. Singer
IPC分类号： G03C7/32
CPC分类号： G03C7/32 , Y10S430/159
摘要： A photographic element having improved granularity contains a dye-forming coupler containing a carbamic acid precursor capable of being converted into a carbamic acid group during processing, and wherein after processing the carbamic acid group decomposes, leaving the dye substantially non-diffusable.

9. 发明授权

US6132944A Photographic element containing high dye-yield couplers 有权
标题翻译：含有高染料收率成色剂的摄影元件
公开(公告)号：US6132944A
公开(公告)日：2000-10-17
申请号：US433256
申请日：1999-11-04
申请人： Jared B. Mooberry , Steven M. Bonser , Kevin P. Dockery , David Hoke , Chang-Kyu Kim , James J. Seifert , David T. Southby , Zheng Z. Wu
发明人： Jared B. Mooberry , Steven M. Bonser , Kevin P. Dockery , David Hoke , Chang-Kyu Kim , James J. Seifert , David T. Southby , Zheng Z. Wu
IPC分类号： G03C7/32 , C07C311/08 , G03C7/305 , G03C7/333 , G03C1/08 , G03C7/26
CPC分类号： G03C7/30547 , C07C311/08 , G03C7/333 , Y10S430/156 , Y10S430/159
摘要： Disclosed is a photographic element containing a light sensitive silver halide emulsion layer having associated therewith a coupler represented by Formula I: ##STR1## wherein COUP is a coupler parent group capable of reacting with an oxidized developer to form a first dye and is bonded at a coupling position to the group ##STR2## wherein X is a or NSO.sub.2 R; R is an alkyl or aryl group; and DYE is a releasable second dye that is after release the same color as the first dye and is linked to OC.dbd.X by a moiety of the DYE having Formula (IA): ##STR3## wherein R.sup.2 is a substituent; provided there is contained in the coupler of Formula I at least one group of Formula IB:--L.sub.m --Sol IBwherein L is a divalent linking group and m is 0 or 1; and Sol is a group containing an acidic hydrogen selected from the group consisting of --ArOH, --NHSO.sub.2 R.sup.1 and --SO.sub.2 NHR.sup.1, in which AR is an aromatic group and each R.sup.1 is a substitute; provided further that the pKa of an acidic hydrogen of Sol is less than 8.8.
摘要翻译：公开了一种含有光敏卤化银乳剂层的照相材料，其具有与式I相结合的成色剂：其中COUP是能够与氧化显影剂反应形成第一种染料并且在偶联位置处键合的成色剂母体基团其中X为或NSO 2 R的基团; R是烷基或芳基; 并且DYE是一种可释放的第二种染料，其在释放出与第一种染料相同的颜色后，通过具有式（IA）的DYE的部分与OC = X连接：其中R2是取代基; 条件是式I的成色剂中含有至少一个式IB的组：-Lm-SolIB，其中L是二价连接基团，m是0或1; 并且Sol是含有选自-ArOH，-NHSO 2 R 1和-SO 2 NHR的酸性氢的基团，其中AR是芳族基团，每个R 1是取代基; 进一步提供Sol的酸性氢的pKa小于8.8。

10. 发明授权

US5447819A Photographic element containing high dye-yield couplers having improved reactivity 失效
标题翻译：含有高染料收率成色剂的摄影元件具有改善的反应性
公开(公告)号：US5447819A
公开(公告)日：1995-09-05
申请号：US250416
申请日：1994-05-27
申请人： Jared B. Mooberry , James J. Seifert , David Hoke , Zheng Z. Wu , David T. Southby , Frank D. Coms
发明人： Jared B. Mooberry , James J. Seifert , David Hoke , Zheng Z. Wu , David T. Southby , Frank D. Coms
IPC分类号： G03C7/00 , G03C7/30 , G03C7/305 , G03C7/36 , G03C7/333
CPC分类号： G03C7/30576 , G03C7/30547 , Y10S430/156
摘要： The invention provides a photographic element comprising a support bearing a photographic silver halide emulsion layer having associated therewith a high dye-yield coupler having the formula:COUP--(T).sub.m --L--DYEwhere COUP is the parent group of the coupler capable of reacting at the coupling position with oxidized color developer to form a first dye, T is one or more timing groups with m=1 or 2, L is a linking group selected from the group consisting of --OC(O)--, --OC(S)--, --SC(O)--, --SC(S)--, or --OC(.dbd.N SO.sub.2 R)--, where R is substituted or unsubstituted alkyl or aryl, and DYE is a second dye or precursor thereof, wherein there is present at least one T group that contains a substituent having the formula:--(LINK).sub.p --A--B--(C--D).sub.nwherein:LINK is an alkylene group capable of linking the above group to the group T, where p=0 or 1;A is a member selected from the group consisting of --NHCO--, --N(R')C(O)N(R--)--, --CONH--, --NR'SO.sub.2 --, --SO.sub.2 NR'--, and --OPO.sub.2 --, where R' is hydrogen or substituted or unsubstituted alkyl;B is a substituted or unsubstituted aromatic carbocyclic or heterocyclic group;C is a solubilizing group selected from --NHSO.sub.2 -- and --SO.sub.2 NH--;D is a substituted or unsubstituted alkyl, aryl, or heterocyclic ring; andn is from 1 to 3.The invention also provides a photographic coupler, a photographic silver halide emulsion, and a process for forming an image in a photographic element in accordance with the invention.
摘要翻译：本发明提供了一种照相元件，其包括带有照相卤化银乳剂层的载体，其具有下式的高染料收率成色剂：COUP-（T）mL-DYE，其中COUP是能够在与氧化的显色剂的偶联位置形成第一染料，T是m = 1或2的一个或多个时基，L是选自-OC（O） - ， - OC（S） - ， - SC（O） - ， - SC（S） - 或-OC（= N SO 2 R） - ，其中R是取代或未取代的烷基或芳基，DYE是第二种染料或其前体，含有具有下式的取代基的至少一个T基团： - （LINK）pAB-（CD）n其中：LINK是能够将上述基团连接到基团T的亚烷基，其中p = 0或1; A是选自-NHCO-，-N（R'）C（O）N（R） - ， - CONH - ， - NR'SO 2 - ， - SO 2 NR' - 和-OPO 2 - 其中R'是氢或取代或未取代的烷基; B是取代或未取代的芳族碳环或杂环基; C是选自-NHSO 2 - 和-SO 2 NH-的增溶基团; D是取代或未取代的烷基，芳基或杂环; 并且n为1至3.本发明还提供照相成色剂，照相卤化银乳剂，以及根据本发明在照相元件中形成图像的方法。

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